通过带有不同长度的4-(4-氯烷氧基苯基)-2,2'∶6,2"-三联吡啶和N-甲基咪唑在甲苯中加热反应,制备了3种由烷氧基桥联的新型三联吡啶咪唑配体.研究了配体和过渡金属离子的配位反应.测定了三联吡啶咪唑铜配合物的单晶分子结构,在铜配合物中,Cu(Ⅱ)和两个三联吡啶单元形成扭曲八面体配位方式.Monoclinic,空间群P 21/c;a=1.7229(3) nm,b =1.5924(2) nm,c=2.1590(3) nm,α=90°,β=101.332(2)°,γ=90°,Mr=1298.09,V=5.8078(15) nm3,Dc=1.485 mg/m3,Z =4,F(000) =2684.
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