采用自组装技术,分别以β-环糊精和甲基丙烯酸为功能单体,反式白藜芦醇为模板分子,乙二醇二甲基丙烯酸酯为交联剂,制备了一种双功能单体印迹聚合物.并将其作为固相萃取材料萃取红酒和白酒酒样中的反式白藜芦醇.结果表明,与单功能印迹材料和非印迹材料相比,这种双功能单体印迹材料具有更高的吸附容量和选择性;结合高效液相色谱,建立了酒样中反式白藜芦醇浓度的检测方法.该方法的线性范围在0.003 ～2 mg/L,红酒的回收率在87.9％ ～ 93.2％,白酒的回收率在89.3％ ～91.2％,检测限为0.001 mg/L.
参考文献
| [1] | Tsang, Siu Wai;Zhang, Hongjie;Lin, Zesi;Mu, Huaixue;Bian, Zhao-Xiang.Anti-fibrotic effect of trans-resveratrol on pancreatic stellate cells[J].Biomedicine & pharmacotherapy =: Biomedecine & pharmacotherapie,2015:91-97. |
| [2] | Rastija V;Medic-Saric M.QSAR study of antioxidant activity of wine polyphenols.[J].European Journal of Medicinal Chemistry: Chimie Therapeutique,20091(1):400-408. |
| [3] | Li-Ping Pan, Si-Li Yu, Chang-Jian Chen, Hui Li, Yi-Liang Wu, Hai-Hang Li.Cloning a peanut resveratrol synthase gene and its expression in purple sweet potato.[J].Plant Cell Reports,20121(1):121-131. |
| [4] | El-Mowafy AM..Resveratrol activates membrane-bound guanylyl cyclase in coronary arterial smooth muscle: A novel signaling mechanism in support of coronary protection[J].Biochemical and Biophysical Research Communications,20025(5):1218-1224. |
| [5] | Ma, Fei;Li, Peiwu;Zhang, Qi;Yu, Li;Zhang, Liangxiao.Rapid determination of trans-resveratrol in vegetable oils using magnetic hydrophilic multi-walled carbon nanotubes as adsorbents followed by liquid chromatography-tandem mass spectrometry[J].Food Chemistry,2015Jul.1(Jul.1):259-266. |
| [6] | Zhang, Qianghua;Bian, Yanhong;Shi, Yingying;Zheng, Shangyong;Gu, Xu;Zhang, Danyan;Zhu, Xiufang;Wang, Xiaoli;Jiang, Dingyun;Xiong, Qingping.An economical and efficient technology for the extraction of resveratrol from peanut (Arachis hypogaea) sprouts by multi-stage countercurrent extraction[J].Food Chemistry,2015Jul.15(Jul.15):15-25. |
| [7] | Tiangang Luan;Gongke Li;Zhanxia Zhaing.Gas-phase postderivatization following solid-phase microextraction for rapid determination of trans-resveratrol in wine by gas chromatography-mass spectrometry[J].Analytica chimica acta,20001(1):19-25. |
| [8] | Careri M;Corradini C;Elviri L;Nicoletti I;Zagnoni I.Direct HPLC analysis of quercetin and trans-resveratrol in red wine, grape, and winemaking byproducts[J].Journal of Agricultural and Food Chemistry,200318(18):5226-5231. |
| [9] | Caro E;Marce RM;Borrull F;Cormack PAG;Sherrington DC.Application of molecularly imprinted polymers to solid-phase extraction of compounds from environmental and biological samples[J].TrAC: Trends in Analytical Chemistry,20062(2):143-154. |
| [10] | Ma, Yingxin;Xu, Suying;Wang, Shiguo;Wang, Leyu.Luminescent molecularly-imprinted polymer nanocomposites for sensitive detection[J].TrAC: Trends in Analytical Chemistry,2015:209-216. |
| [11] | Syu MJ;Deng JH;Nian YM;Chiu TC;Wu AH.Binding specificity of alpha-bilirubin-imprinted poly(methacrylic acid-co-ethylene glycol dimethylacrylate) toward alpha-bilirubin.[J].Biomaterials,200522(22):4684-4692. |
| [12] | Wei Zhang;Lei Qin;Xi-Wen He;Wen-You Li;Yu-Kui Zhang.Novel surface modified molecularly imprinted polymer using acryloyl-_-cyclodextrin and acrylamide as monomers for selective recognition of lysozyme in aqueous solution[J].Journal of chromatography, A: Including electrophoresis and other separation methods,200921(21):4560-4567. |
| [13] | Jose Manuel Lopez-Nicolas;Francisco Garcia-Carmona.Rapid, simple and sensitive determination of the apparent formation constants of trans-resveratrol complexes with natural cyclodextrins in aqueous medium using HPLC[J].Food Chemistry,20084(4):868-875. |
| [14] | Xavier Vitrac;Jean-Pierre Monti;Joseph Vercauteren;Gerard Deffieux;Jean-Michel Merillon.Direct liquid chromatographic analysis of resveratrol derivatives ad flavanonols in wines with absorbance and fluorescence detection[J].Analytica chimica acta,20021(1):103-110. |
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