欢迎登录材料期刊网

材料期刊网

高级检索

在有机胺的存在下,三苯基氯化锡与邻苯二甲酸反应,得到了五配位阴离子型有机锡羧酸酯化合物,通过IR、1H NMR、元素分析等技术手段对反应产物结构进行了表征,确定了反应产物的结构.同时测定了反应产物对10种病菌的杀菌活性,结果表明,产物对芦笋茎枯、花生褐斑、水稻曲病菌和黄瓜黑星病菌的杀死率均为100%,对其它病菌具有中等强度的杀死率.

参考文献

[1] Gielen M;Davies A G;Pannell K.Tin Chemistry:Fundamentals,Frontiers,and Applications[M].Weinheim:John Wiley & Sons Inc,2008:413-417.
[2] Brown M N.In Tin-based Antitumor Drugs[M].Berlin:Springer-Verlag,1990:69-75.
[3] Tian LJ;Sun YX;Li HJ;Zheng XL;Cheng YZ;Liu XL;Qian BH.Synthesis, characterization and biological activity of triorganotin 2-phenyl-1,2,3-triazole-4-carboxylates[J].Journal of Inorganic Biochemistry: An Interdisciplinary Journal,20058(8):1646-1652.
[4] Antiproliferative And Anti-tumor Activity Of Organotin Compounds[J].Coordination chemistry reviews,20091/2(1/2):235-249.
[5] Demetrios Tzimopoulos;Ioannis Sanidas;Anastasia.-C. Varvogli;Agnieszka Czapik;Maria Gdaniec;Eleni Nikolakaki;Pericles D. Akrivos.On the bioreactivity of triorganotin aminobenzoates. Investigation of trialkyl and triarylyltin(IV) esters of 3-amino and 4-aminobenzoic acids[J].Journal of Inorganic Biochemistry: An Interdisciplinary Journal,20104(4):423-430.
[6] Shang, X.;Meng, X.;Alegria, E.C.B.A.;Li, Q.;Guedes Da Silva, M.F.C.;Kuznetsov, M.L.;Pombeiro, A.J.L..Syntheses, molecular structures, electrochemical behavior, theoretical study, and antitumor activities of organotin(IV) complexes containing 1-(4-chlorophenyl)-1-cyclopentanecarboxylato ligands[J].Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics,201117(17):8158-8167.
[7] Gielen M;Boualam M B;Tiekink E R T.Crystal Structure and in vitro Antitumour Activity of Dibutylbis (5-chloro-2-hydroxybenzoato) tin(Ⅳ)[J].Applied Organometallic Chemistry,19948(1):19-23.
[8] Atassi G.Antitumor and toxic Effects of Silicon,Germanium,Tin and Lead Compounds[J].Rev Si Ge Sn Pb Compd,19858(3):219-235.
[9] Gielen M;Biesemans M.Diorganotin Difluorobenzoates:Synthesis,Spectroscopic Characterization and in Vitro Antitumour Activity.X-ray Structure Determination of Bis[di-n-butyl(2,6-difluorobenzoato) tin]Oxide[J].J Flourine Chem,199364(3):279-291.
[10] Tao J X;Xiao W J;Yang Q C.Structural Chemistry of Organotin Ferrocenecarboxylic Esters Ⅱ.The Crystal Structure of Dibutyltin Ferrocenecarboxylate Oxide[J].Journal of Organometallic Chemistry,2001531(1):223-226.
[11] 钟桂云;刘清福;孙丽娟;谢庆兰.混合三烃基卤化锡二苯基环己基碘化锡和甲基二环己基氯化锡与巯基乙酸在有机胺存在下的反应产物及生物活性研究[J].有机化学,2011(5):728-732.
[12] 钟桂云;孙丽娟.离子型有机锡化合物的合成及其生物活性[J].应用化学,2011(4):387-393.
[13] Okawara R;Yasuda K.Occurrence of Dimeric Trimethyltin Hydroxide[J].Journal of Organometallic Chemistry,19641(3):356-359.
[14] Tiekink E R T.A Review of the Crystallographic Literature[J].Applied Organometallic Chemistry,19915(1):1-23.
[15] 钟桂云;孟宁;陈昌炽;孙丽娟;谢庆兰.五配位阴离子型有机锡化合物[HNR3][MeCy2ClSnO2CCH2CO2SnClCy2Me] 的合成及生物活性研究[J].内蒙古大学学报(自然科学版),2010(6):660-664.
[16] 钟桂云;刘芳;孙丽娟.新型离子型有机锡化合物的合成及[H2N(i-Pr)2][(Ph3Sn)3(O2CCH2CO2)2]·CH3CH2OH晶体结构研究[J].湘潭大学自然科学学报,2010(4):68-73.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%