钴岛膜上对巯基苯甲酸的表面增强红外吸收光谱

应用化学, 2015, 32(2): 221-224. doi: 10.11944/j.issn.1000-0518.2015.02.140177

钴岛膜上对巯基苯甲酸的表面增强红外吸收光谱

闫月荣 ^1, , 高成庄 ^2, , 张艳青 ^3, , 褚文娅 ^4, , 李双双 ^5, , 赵伟 ^6, , 周群 ^7, , 李晓伟 ^8,

1.苏州大学物理与光电·能源学部江苏苏州215006;焦作师范高等专科学校理工学院河南焦作454000

2.焦作师范高等专科学校理工学院河南焦作454000

3.苏州大学物理与光电·能源学部江苏苏州215006

4.苏州大学材料与化学化工学部江苏苏州215123

5.苏州大学材料与化学化工学部江苏苏州215123

6.苏州大学材料与化学化工学部江苏苏州215123

7.苏州大学材料与化学化工学部江苏苏州215123

8.苏州大学物理与光电·能源学部江苏苏州215006

基金项目: supported by the Foundation and Frontier Project of the Science and Technology Hall of He'nan Province(112300410326) the Foundation and Frontier Project of the Science and Technology Bureau of Jiaozuo(No.208,211)河南省科技厅基础与前沿基金(112300410326) 焦作市科技局基础与前沿项目(208,211)

关键词：钴岛膜 , 对巯基苯甲酸 , 表面增强红外吸收光谱

Surface-enhanced Infrared Absorption Spectroscopy of the Para-mercaptobenzoic acid on the Cobalt-island Film

Keywords： cobalt-island films , para-mercaptobenzoic acid , surface-enhanced infrared absorption spectroscopy

通过置换反应在金属铝表面制备了表面没有任何保护剂且具有红外增强作用的钴岛膜,用SEM、XRD和表面增强红外光谱对其形貌和性质进行表征.结果表明,铝片上沉积出的钴呈岛状结构,钴岛膜由二次钴粒子和一次钴粒子通过密堆积的方式构成;首次发现具有这种特殊结构的钴对吸附于其表面的有机分子的红外吸收光谱有较大的增强作用,用此钴岛膜对1 mmol/L的对巯基苯甲酸的红外光谱研究时得到很好的红外增强信号,使得表面增强红外光谱可以用于痕量分析、检测.

参考文献

[1]	Osawa M.Dynamic Processes in Electrochemical Reactions Studied by Surface-enhanced Infrared Absorption Spectroscopy(SEIRAS)[J].Bulletin of the Chemical Society of Japan,199770(12):2861-2880.
[2]	Osawa M;Ikeda M.Surface-enhanced Infrared Absorption of p-Nitrobenzoic Acid Deposited on Silver Island Films:Contributions of Electromagnetic and Chemical Mechanisms[J].Journal of Physical Chemistry,199195(24):9914-9919.
[3]	BY RICARDO F. AROCA;DANIEL J. ROSS MATERIALS;SURFACE SCIENCE GROUP.Surface-Enhanced Infrared Spectroscopy[J].Applied Spectroscopy: Society for Applied Spectroscopy,200411(11):324A-338A.
[4]	Hartstein A;Kialey J R;Tsang J C.Enhancement of the Infrared Absorption from Molecular Monolayers with Thin Metal Overlayers[J].Physical Review Letters,198045(3):201-204.
[5]	Osawa M;Ataka K I;Yoshii K.Surface-enhanced Infrared Spectroscopy:the Origin of the Absorption Enhancement and Band Selection Rule in the Infrared Spectra of Molecules Adsorbed on Fine Metal Particles[J].Applied Spectroscopy,199347(9):1497-1502.
[6]	Dominik Enders;Tadaaki Nagao;Annemarie Pucci.Surface-enhanced ATR-IR spectroscopy with interface-grown plasmonic gold-island films near the percolation threshold[J].Physical chemistry chemical physics: PCCP,201111(11):4935-4941.
[7]	Kinugasa S;Tanbe K;Tamura T .Spectral Database for Organic Compounds[DB/OL].http://riodb01.ibase.aist.go.jp/sdbs/cgi-bin/cre_index.cgi? lang =eng,2014-06-03.
[8]	Merklin G T;Griffiths P R.Effect of Microscopic Surface Roughness in Surface-enhanced Infrared Absorption Spectrometry[J].Journal of Physical Chemistry B,1997101(30):5810-5813.
[9]	Wells M;Dermody D L;Yang H C.Interactions between Organized,Surface-confined Monolayers and Vapor-phase Probe Molecules.9.Structure/Reactivity Relationship between Three Surface-confined Isomers of Mercaptobenzoic Acid and Vapor-phase Decylamine[J].LANGMUIR,199612(8):1989-1996.

上一张下一张

计量

下载量()
访问量()

作者相关

文章评分

您的评分：
1

0%
2

0%
3

0%
4

0%
5

0%

材料期刊网