基于邻苯二甲酸酯在浓硫酸下荧光增强的原理构建了一种测定邻苯二甲酸酯总量的荧光分析新方法.体系的荧光强度与邻苯二甲酸酯的浓度在5.00 ～600μg/L的范围内呈线性关系,方法的检出限为0.57 μg/L,回收率在91.6％ ～ 105.1％之间.该方法简单、快速、灵敏度高、线性范围宽.用于塑料水杯和聚氯乙烯水管中邻苯二甲酸酯总量的测定,结果令人满意.
参考文献
| [1] | Mahmoud M A,José R U,Raúl O P,et al.Environmental Impact of Phthalic Acid Esters and Their Removal from Water and Sediments by Different Technologies-A Review[J].J Environ Manage,2012,109(10):164-178.,2012. |
| [2] | Howdeshell K L,Wilson V S,Furr J,et al.A Mixture of Five Phthalate Esters Inhibits Fetal Testicular Testosterone Production in the Spraguee Dawley Rat in a Cumulative,Dose-additive Manner[J].Toxicol Sci,2008,105(6):153-165.,2008. |
| [3] | Liu X W,Shi J H,Bo T,et al.Occurrence of Phthalic Acid Esters in Source Waters:A Nationwide Survey in China During the Period of 2009-2012[J].Environ Pollut,2014,184(l):262-270.,2014. |
| [4] | Zheng X X,Zhang B T,Teng Y G.Distribution of Phthalate Acid Esters in Lakes of Beijing and Its Relationship with Anthropogenic Activities[J].Sci Total Environ,2014,476/477(4):107-113.,2014. |
| [5] | Zhang L F,Dong L,Ren L J,et al.Concentration and Source Identification of Polycyclic Aromatic Hydrocarbons and Phthalic Acid Esters in the Surface Water of the Yangtze River Delta,China[J].J Environ Sci,2012,24(2):335-342.,2012. |
| [6] | YANG Wenhong,YE Changmiog.Simultaneous Determination of Phthalic acid and Dimethyl Phthalate by Dual-wavelength Spectrophotometry[J].Environ Chem,1995,14(2):145-150(in Chinese).颜文红,叶常明.分光光度法同时测定水中邻苯二甲酸和邻苯二甲酸二甲酯[J].环境化学,1995,14(2):145-150.,1995. |
| [7] | 黄晓东,陶然,徐强.紫外分光光度法测定饮用纯净水中邻苯二甲酸二己酯含量[J].食品科学,2012(16):237-240. |
| [8] | Li X J,Zeng Z R,Chen Y,et al.Determination of Phthalate Acid Esters Plasticizers in Plastic by Ultrasonic Solvent Extraction Combined with Solid-phase Microextraction Using Calix【4】arene Fiber[J].Talanta,2004,63 (4):1013-1019.,2004. |
| [9] | Gabriela P,Katerina H,Jan P,et al.Development of a Solid-phase Microextraction Method for the Determination of Phthalic Acid Esters in Water[J].Anal Chim Acta,2002,457(2):211-223.,2002. |
| [10] | 肖尚友,王杰峰,夏之宁,穆小静.原柱富集-高效液相色谱法测定水体中痕量邻苯二甲酸二甲酯[J].分析化学,2009(08):1193-1196. |
| [11] | 杜新贞,曹旭,王雪梅,陈慧.介孔材料固相微萃取-高效液相色谱联用测定水样中邻苯二甲酸二乙酯[J].西北师范大学学报（自然科学版）,2009(04):56-59. |
| [12] | Xu D M,Deng X J,Fang E H,et al.Determination of 23 Phthalic Acid Esters in Food by Liquid Chromatography Tandem Mass Spectrometry[J].J Chromatogr A,2014,1324 (1):49-56.,2014. |
| [13] | Akos K,Lajos N,Miklos Z,et al.Fast Identification of Phthalic Acid Esters in Poly (vinyl chloride) Samples by Direct Analysis in Real Time (DART) Tandem Mass Spectrometry[J].Int J Mass Spectrom,2011,303 (2/3):225-228.,2011. |
| [14] | 张明翠,庄惠生.酸性条件下荧光光度法测定水中邻苯二甲酸二丁酯[J].分析测试学报,2006(05):113-115. |
| [15] | LANG Qing,ZHANG Mingcui,WANG Qionge,et al.Fluorophotometric Determination of Dibutyl Phthalate in Water[J].Phys Test Chem Anal Part B:Chem Anal,2006,42(4):243-244,251 (in Chinese).郎庆,张明翠,王琼娥,等.荧光光度法测定水中邻苯二甲酸二甲酯的研究[J].理化检验-化学分册,2006,42(4):243-244,251.,2006. |
| [16] | 李满秀,王华燕.荧光法测定环境样品中的邻苯二甲酸酯[J].分析化学,2005(09):1315-1317. |
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