{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"通过时温等效原理,研究了一种快速评价HIPS材料后收缩性能的方法。结果表明：影响HIPS材料后收缩行为最关键因素是其不同尺度<span style=\"color:red\">链</span><span style=\"color:red\">段</span>的<span style=\"color:red\">松弛</span>行为；高温热处理条件下,HIPS材料以主<span style=\"color:red\">链</span><span style=\"color:red\">松弛</span>为主,而低温条件下以小尺寸<span style=\"color:red\">链</span><span style=\"color:red\">段</span>运动的次级<span style=\"color:red\">松弛</span>为主,从而导致高温热处理的后收缩行为与室温不相符；通过降低热处理温度,在40℃~45℃热处理温度下放置168 h能够较好地模拟HIPS在室温下放置一个月的后收缩尺寸。","authors":[{"authorName":"陈平绪","id":"9d9ee3a4-6bf6-4fb8-a845-5a08ad363e0a","originalAuthorName":"陈平绪"},{"authorName":"李玉虎","id":"af4e8cd8-44d8-4bf1-8278-23782963ad73","originalAuthorName":"李玉虎"},{"authorName":"程庆","id":"09b153a0-0ca2-48cf-8a98-84c33b10187f","originalAuthorName":"程庆"},{"authorName":"王林","id":"9213ebeb-2394-44e0-8217-f6a1a6604e36","originalAuthorName":"王林"},{"authorName":"叶南飚","id":"4aec76aa-3643-4788-84ea-ef98f13ae38b","originalAuthorName":"叶南飚"},{"authorName":"曾幸荣","id":"92027b3a-df7a-47ac-ab09-a60a1b990159","originalAuthorName":"曾幸荣"}],"doi":"","fpage":"29","id":"b81f88f4-d11f-4845-80c6-3d18af91f50c","issue":"4","journal":{"abbrevTitle":"HCCLLHYYY","coverImgSrc":"journal/img/cover/HCCLLHYYY.jpg","id":"42","issnPpub":"1671-5381","publisherId":"HCCLLHYYY","title":"合成材料老化与应用"},"keywords":[{"id":"b0cb44ba-bb8b-4958-a7ea-542b4b47738e","keyword":"HIPS","originalKeyword":"HIPS"},{"id":"4188c9fd-566f-4f8a-aa75-3b75590f3342","keyword":"后收缩","originalKeyword":"后收缩"},{"id":"57f00286-965c-4ea8-8d24-d7ac64eb0ce7","keyword":"<span style=\"color:red\">链</span><span style=\"color:red\">段</span><span style=\"color:red\">松弛</span>","originalKeyword":"链段松弛"}],"language":"zh","publisherId":"hccllhyyy201504007","title":"一种快速评价HIPS材料后收缩性能的方法","volume":"","year":"2015"},{"abstractinfo":"通过熔融后冰水淬火和热处理方法制备了δ'晶型和α晶型的尼龙11薄膜试样.在42Hz～5MHz频率范围测得了室温至150℃的介电<span style=\"color:red\">松弛</span>频率谱,研究了二种晶型的尼龙11在室温以上的分子<span style=\"color:red\">链</span>运动.结果发现,尼龙11在δ'→α晶型转变之后,由HavriliakNegami经验公式拟合得到的分子<span style=\"color:red\">链</span><span style=\"color:red\">段</span>和局域运动的<span style=\"color:red\">松弛</span>强度都减小,<span style=\"color:red\">松弛</span>时间则增大,表明退火之后尼龙11的分子<span style=\"color:red\">链</span>运动受到了抑制.","authors":[{"authorName":"朱俊","id":"b26dcfb0-9286-4e64-b285-98935ae91565","originalAuthorName":"朱俊"},{"authorName":"张兴元","id":"f6e7cde7-7dda-4ffb-8d58-a3e7a378785b","originalAuthorName":"张兴元"}],"doi":"","fpage":"953","id":"0284f075-5e7d-4346-a9e4-c17ca1d0bd7e","issue":"z1","journal":{"abbrevTitle":"GNCL","coverImgSrc":"journal/img/cover/GNCL.jpg","id":"33","issnPpub":"1001-9731","publisherId":"GNCL","title":"功能材料"},"keywords":[{"id":"659311c7-aa67-41f0-ab2a-6323bfc0ad0f","keyword":"尼龙11","originalKeyword":"尼龙11"},{"id":"7df35b8b-e8b2-4cf1-a0f0-71ffe4708267","keyword":"晶型转变","originalKeyword":"晶型转变"},{"id":"d47dec71-d50d-4856-a4bc-a0c9d8355abb","keyword":"介电<span style=\"color:red\">松弛</span>","originalKeyword":"介电松弛"},{"id":"24eaff89-675f-4534-b7d6-5374bd91f090","keyword":"分子<span style=\"color:red\">链</span>运动","originalKeyword":"分子链运动"}],"language":"zh","publisherId":"gncl2004z1266","title":"尼龙11室温以上分子<span style=\"color:red\">链</span>运动的介电<span style=\"color:red\">松弛</span>研究","volume":"35","year":"2004"},{"abstractinfo":"用在不同温度下热处理的方法制备了具有不同结晶度的尼龙1010试样,通过测量热释电流研究了试样的分子<span style=\"color:red\">链</span><span style=\"color:red\">段</span>运动与电荷存储输运特性.热释电流谱上显示两个电流峰,通过研究峰电流与极化场强的关系发现,62℃左右的α峰为偶极<span style=\"color:red\">松弛</span>峰,109℃左右的ρ峰为空间电荷峰.随着结晶度从0.05%增加到46.3%,尼龙1010的偶极<span style=\"color:red\">松弛</span>活化能由0.98增加到1.18eV,显示分子<span style=\"color:red\">链</span><span style=\"color:red\">段</span>运动变得困难;陷阱深度则变浅,由1.36降低到1.13eV,表明适当的结晶度可提高对载流子的俘获能力,改变材料中电荷的存储与输运特性.","authors":[{"authorName":"陆红波","id":"785c8481-2bd9-4a0d-bf7a-b694bb698422","originalAuthorName":"陆红波"},{"authorName":"张兴元","id":"2e1005c6-611b-4f25-94db-a2cade858552","originalAuthorName":"张兴元"}],"doi":"","fpage":"1810","id":"e615adbe-c1fe-488f-9a29-4a8d9029d344","issue":"z1","journal":{"abbrevTitle":"GNCL","coverImgSrc":"journal/img/cover/GNCL.jpg","id":"33","issnPpub":"1001-9731","publisherId":"GNCL","title":"功能材料"},"keywords":[{"id":"eba0fe24-bcd7-4899-9bd8-80e9f5b5944a","keyword":"尼龙1010","originalKeyword":"尼龙1010"},{"id":"aa768d10-3dfd-44b4-b593-965e042a6e9b","keyword":"结晶","originalKeyword":"结晶"},{"id":"e044ac2f-0ab7-433e-bd9f-f88150d45cb1","keyword":"热释电流","originalKeyword":"热释电流"},{"id":"58b2724e-4700-4dcb-83ee-4c8afb548d48","keyword":"偶极<span style=\"color:red\">松弛</span>","originalKeyword":"偶极松弛"},{"id":"145b4cc4-1eb1-453b-9b7e-2dc78c29238e","keyword":"陷阱","originalKeyword":"陷阱"}],"language":"zh","publisherId":"gncl2004z1504","title":"不同结晶度尼龙1010的分子<span style=\"color:red\">链</span><span style=\"color:red\">段</span>运动与电荷存储输运","volume":"35","year":"2004"},{"abstractinfo":"为提高PBS基脂肪族聚酯的综合性能,通过ε-己内酯的开环聚合制备了端羟基的聚己内酯(PCL-OH),再通过熔融缩聚法制备了端羟基的聚(丁二酸丁二醇酯对苯二甲酸丁二醇酯)无规共聚物(PBST-OH),用氢化MDI(H12MDI)作为扩<span style=\"color:red\">链</span>剂,制得了可生物降解的聚酯聚氧酯(PPCLBST).采用核磁共振谱和红外光谱确定了PPCLBST的结构和组成,利用差示扫描量热仪和热重分析仪表征了PPCLBST的热性能和结晶性能,采用吸水率测试表征了其亲水性能.结果表明:PPCLBST的结晶主要由PBST-OH<span style=\"color:red\">段</span>产生,而PCL-OH<span style=\"color:red\">段</span>无法结晶,随PCL-OH<span style=\"color:red\">链</span><span style=\"color:red\">段</span>含量的升高.其玻璃化温度下降,趋向于无定形态;PPCLBST的热降解分两步进行,第一<span style=\"color:red\">段</span>为PCL-OH<span style=\"color:red\">链</span><span style=\"color:red\">段</span>的分解,第二<span style=\"color:red\">段</span>为PBST-OH<span style=\"color:red\">链</span><span style=\"color:red\">段</span>的分解.由于同时含有硬<span style=\"color:red\">段</span>和软<span style=\"color:red\">段</span>,PPCLBST具有良好的热稳定性能,且比PBS有更为优良的亲水能力.","authors":[{"authorName":"郝瑞","id":"38f8fb6e-ee00-4204-80e9-81da08466f4a","originalAuthorName":"郝瑞"},{"authorName":"周艺峰","id":"b2bb71e3-68d4-4d56-a5e4-c7ca9ef6f82b","originalAuthorName":"周艺峰"},{"authorName":"聂王焰","id":"f7b77d73-154e-4884-96e2-548b89a0a627","originalAuthorName":"聂王焰"}],"doi":"","fpage":"58","id":"18e66218-bc9f-40ac-8c32-962d9c945670","issue":"6","journal":{"abbrevTitle":"CLKXYGY","coverImgSrc":"journal/img/cover/CLKXYGY.jpg","id":"14","issnPpub":"1005-0299","publisherId":"CLKXYGY","title":"材料科学与工艺"},"keywords":[{"id":"22f15ce1-f9cc-4222-ad88-df25064d2cd6","keyword":"聚ε-己内酯","originalKeyword":"聚ε-己内酯"},{"id":"10a0e15b-8a0f-4df5-bdbb-26a66edcade4","keyword":"扩<span style=\"color:red\">链</span>","originalKeyword":"扩链"},{"id":"ee35bc10-3a81-4c7a-9e73-20c020907b3c","keyword":"脂肪/芳香族聚酯","originalKeyword":"脂肪/芳香族聚酯"},{"id":"e8653b2a-385a-4db7-a1b1-56f4f8cf4779","keyword":"降解高分子","originalKeyword":"降解高分子"}],"language":"zh","publisherId":"clkxygy201106011","title":"含PCL和PBST<span style=\"color:red\">链</span><span style=\"color:red\">段</span>聚酯聚氨酯的合成与表征","volume":"19","year":"2011"},{"abstractinfo":"为了获得性能更优良的聚乳酸材料,以乳酸、ε-己内酯、丁二酸酐为原料,采用梯度升温法合成了聚乳酸嵌<span style=\"color:red\">段</span>共聚物,用IPDI对其扩<span style=\"color:red\">链</span>.采用乌氏黏度法、FT-IR、1H-NMR、TGA及XRD等手<span style=\"color:red\">段</span>对产物进行了表征.FT-IR和1H-NMR测试结果显示,预期的聚乳酸嵌<span style=\"color:red\">段</span>共聚物成功合成;几种聚合方法中,以先合成端羟基活性低聚物P(LA-CL),再加丁二酸酐与之共聚合成的产物P(LA-CL/SA)分子量最高,扩<span style=\"color:red\">链</span>后的产物分子量提高不多;P(LA-CL/SA)的热稳定性比PLA的低;XRD结果显示P(LA-CL/SA)为无定形峰,结晶度比PLA低.与PLA相比,改性后的聚乳酸嵌<span style=\"color:red\">段</span>共聚物分子量提高,更易降解,柔韧性增加.","authors":[{"authorName":"樊国栋","id":"11e8246a-c00c-45c6-a47e-f5292eda5dc1","originalAuthorName":"樊国栋"},{"authorName":"张春梅","id":"299713ec-a68a-4add-be94-ed3a9cf63077","originalAuthorName":"张春梅"},{"authorName":"李甜甜","id":"46cbe3d6-bbf8-4ea2-aebb-d1ffa9abcbff","originalAuthorName":"李甜甜"}],"doi":"","fpage":"70","id":"90741fde-a675-47da-ae1f-fc7e7294a1a0","issue":"6","journal":{"abbrevTitle":"CLKXYGY","coverImgSrc":"journal/img/cover/CLKXYGY.jpg","id":"14","issnPpub":"1005-0299","publisherId":"CLKXYGY","title":"材料科学与工艺"},"keywords":[{"id":"956b42d2-f278-4656-9a38-f4202c3c6153","keyword":"聚乳酸","originalKeyword":"聚乳酸"},{"id":"da4295ff-1d94-495c-b478-98eec845b6ec","keyword":"嵌<span style=\"color:red\">段</span>共聚物","originalKeyword":"嵌段共聚物"},{"id":"08adbf05-98a5-4cd9-8e75-5f78966c2517","keyword":"异佛尔酮二异氰酸酯","originalKeyword":"异佛尔酮二异氰酸酯"},{"id":"38541cc6-95dd-49f2-8414-5d58b238e5f1","keyword":"端羟基共聚物","originalKeyword":"端羟基共聚物"},{"id":"9368d26f-90a9-478c-a1ff-7e4ce8ebd117","keyword":"梯度升温","originalKeyword":"梯度升温"}],"language":"zh","publisherId":"clkxygy201106013","title":"聚乳酸嵌<span style=\"color:red\">段</span>共聚物的制备及扩<span style=\"color:red\">链</span>研究","volume":"19","year":"2011"},{"abstractinfo":"综述了由聚氧乙烯<span style=\"color:red\">链</span><span style=\"color:red\">段</span>与聚二烯烃、聚异丁烯、聚乙烯基吡啶、聚丙烯腈、聚丙烯酰胺或聚丙烯酸<span style=\"color:red\">链</span><span style=\"color:red\">段</span>组成的各种嵌<span style=\"color:red\">段</span>共聚物及接枝共聚物的合成方法,并对其各种性能,包括两亲性质、络合碱金属离子性及微观相分离等进行了总结。","authors":[{"authorName":"谢洪泉","id":"340507ca-afb3-4124-9226-f3f32149c67f","originalAuthorName":"谢洪泉"}],"doi":"","fpage":"1","id":"6d66723f-6ce4-4de7-a85a-695198232500","issue":"1","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"c05aaff3-62e1-4030-88ac-2062b322d829","keyword":"嵌<span style=\"color:red\">段</span>共聚物","originalKeyword":"嵌段共聚物"},{"id":"a13c6224-0dda-4419-be7a-01f62183549d","keyword":"接枝共聚物","originalKeyword":"接枝共聚物"},{"id":"3b7374e4-4652-47b3-a9da-164857d66972","keyword":"多相聚合物","originalKeyword":"多相聚合物"},{"id":"d11fe965-9668-478b-8a7a-80ccf26928c6","keyword":"两亲聚合物","originalKeyword":"两亲聚合物"},{"id":"e0df9e83-49f8-4dc6-b725-dd1c5baf18e3","keyword":"聚氧乙烯","originalKeyword":"聚氧乙烯"}],"language":"zh","publisherId":"gfzclkxygc200101001","title":"含聚氧乙烯<span style=\"color:red\">链</span><span style=\"color:red\">段</span>的嵌<span style=\"color:red\">段</span>共聚物和接枝共聚物的合成及性能","volume":"17","year":"2001"},{"abstractinfo":"针对低成本有效去除环境中有害苯乙烯气体的需求,分别采用紫外(UV)和高能电子束(EB)辐照引发在聚丙烯(PP)非织造布上接枝丙烯酸十二酯,制备了能够快速吸附苯乙烯气体的功能非织造布.用衰减全反射傅里叶变换红外光谱、接触角和扫描电子显微镜对接枝前后非织造布的疏水烷基<span style=\"color:red\">链</span><span style=\"color:red\">段</span>分布和形貌进行了表征,重点研究了在不同吸附温度和气体流速条件下疏水烷基<span style=\"color:red\">链</span><span style=\"color:red\">段</span>分布对苯乙烯气体吸附效果的影响规律.结果表明,UV引发疏水烷基<span style=\"color:red\">链</span><span style=\"color:red\">段</span>只分布在非织造布表层;EB引发疏水烷基<span style=\"color:red\">链</span><span style=\"color:red\">段</span>相对均匀地分布在非织造布表层和内层.当接枝率为132％左右时,对苯乙烯气体的吸附透过时间由PP非织造布的50 min分别增加到UV引发接枝的80 min和EB引发接枝的120min.","authors":[{"authorName":"路晖","id":"1b60743c-4a20-4d8a-a4c4-dc8234ac10c5","originalAuthorName":"路晖"},{"authorName":"张环","id":"c0b51bd6-a34f-4866-b941-cae5b2f12dc8","originalAuthorName":"张环"},{"authorName":"魏俊富","id":"87cb638d-ab42-40aa-9d6a-bbe518ba45f4","originalAuthorName":"魏俊富"},{"authorName":"李永花","id":"b4d73a61-faa7-4439-99ea-aae5db44f1e6","originalAuthorName":"李永花"},{"authorName":"赵孔银","id":"d9a978b4-cf36-4515-92a9-daac35f5a0c9","originalAuthorName":"赵孔银"},{"authorName":"孙思佳","id":"6ba2582b-f4ac-4951-9ac8-97a015fd64c6","originalAuthorName":"孙思佳"}],"doi":"","fpage":"159","id":"63618582-1852-41a3-a888-156bf4a6e3ae","issue":"9","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"569c9ae8-b7c7-453a-be69-a46386f3491e","keyword":"疏水烷基<span style=\"color:red\">链</span><span style=\"color:red\">段</span>分布","originalKeyword":"疏水烷基链段分布"},{"id":"4c5c91d5-c1fc-4bcc-95d1-ca5f24936a26","keyword":"聚丙烯非织造布","originalKeyword":"聚丙烯非织造布"},{"id":"501d987c-1d4e-4a3f-95fc-b20605f31675","keyword":"苯乙烯气体","originalKeyword":"苯乙烯气体"},{"id":"078fec1f-3cef-4106-b473-67ef4d72e186","keyword":"吸附","originalKeyword":"吸附"},{"id":"ca136b62-30f2-47a5-a3c4-df8bb5bcbe19","keyword":"接枝","originalKeyword":"接枝"}],"language":"zh","publisherId":"gfzclkxygc201409033","title":"非织造布上疏水<span style=\"color:red\">链</span><span style=\"color:red\">段</span>分布对苯乙烯气体吸附效果的影响","volume":"30","year":"2014"},{"abstractinfo":"通过热刺激电流、差示扫描量热和扫描电镜研究离子液体对聚酰胺610结构的变化以及热刺激电流所反映偶极取向<span style=\"color:red\">松弛</span>和空间电荷的受陷、退陷和陷阱能级变化.可知离子液体/聚酰胺610复合材料偶极<span style=\"color:red\">松弛</span>和空间电荷<span style=\"color:red\">松弛</span>峰形状、强度显著依赖于离子液体含量.离子液体增塑使得偶极<span style=\"color:red\">松弛</span>峰电流强度增大,活化能减弱.随着离子液体含量增大,非晶区和晶区陷阱俘获空间电荷能力增加.离子液体含量增大使得非晶区被俘获空间电荷的稳定性下降、晶区被俘获空间电荷的稳定性基本不变.","authors":[{"authorName":"徐佩","id":"c917a9ce-9521-4745-bce6-cb2ef21b14f5","originalAuthorName":"徐佩"},{"authorName":"郝倩","id":"f1a7f1d4-df63-4d69-acde-3ea26530b10a","originalAuthorName":"郝倩"},{"authorName":"桂豪冠","id":"e8533f44-5f09-4242-871f-15f268e1cb26","originalAuthorName":"桂豪冠"},{"authorName":"杨善中","id":"3162d36a-b126-4e7f-94d4-2ad59a839aea","originalAuthorName":"杨善中"},{"authorName":"丁运生","id":"668a8174-5a8f-4434-9be2-010be56e3996","originalAuthorName":"丁运生"}],"doi":"","fpage":"54","id":"93cdbca0-5e5f-400b-b113-696c530c3588","issue":"8","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"8478401e-5a92-4857-8f1c-f68ef48464da","keyword":"离子液体","originalKeyword":"离子液体"},{"id":"26f0ce30-8ae8-44fc-b4de-21f136495826","keyword":"聚酰胺610","originalKeyword":"聚酰胺610"},{"id":"f2299b3d-1905-4987-9eb9-2307303395e4","keyword":"空间电荷","originalKeyword":"空间电荷"},{"id":"c3a5fcf3-ec54-42a8-b9b4-ece2825852a3","keyword":"<span style=\"color:red\">链</span><span style=\"color:red\">段</span>运动","originalKeyword":"链段运动"}],"language":"zh","publisherId":"gfzclkxygc201408011","title":"离子液体对聚酰胺610分子<span style=\"color:red\">链</span><span style=\"color:red\">段</span>运动与电荷存储特性的影响","volume":"30","year":"2014"},{"abstractinfo":"通过原位聚合的方法合成了聚对苯二甲酸乙二醇酯(PET)/Ti3N4纳米复合材料.通过多功能内耗仪和动态力学分析仪(DMA)对该纳米复合材料的蠕变及动态力学性能进行了测试分析,结果表明,随纳米粒子含量的增加,复合材料的蠕变能力降低,内耗峰的峰高具有相同的变化趋势,当纳米Ti3 N4添加量增加至3％时,其蠕变能力和内耗峰高分别降低为纯PET的7.1％和11.9％.但复合材料的储能模量较纯PET高,因此该复合材料有望在工程材料领域得到应用.","authors":[{"authorName":"康升红","id":"e7ad801d-cb80-40f3-b452-5c1b2f306103","originalAuthorName":"康升红"},{"authorName":"郑康","id":"18e4e8c7-5a66-4d94-8078-6fd713aa266b","originalAuthorName":"郑康"},{"authorName":"费广涛","id":"22f1fc25-5bcf-4598-805d-5abe70ad6b95","originalAuthorName":"费广涛"},{"authorName":"田兴友","id":"b5146a45-cd71-433a-bca7-9767452f919d","originalAuthorName":"田兴友"}],"doi":"","fpage":"39","id":"a32eb847-b3fb-497f-bc3b-0dbdaa8a44ab","issue":"12","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"0ee79fc7-8560-4325-8634-650bdc432876","keyword":"聚对苯二甲酸乙二醇酯/Ti3N4纳米复合材料","originalKeyword":"聚对苯二甲酸乙二醇酯/Ti3N4纳米复合材料"},{"id":"c184bc65-a7b6-40ed-ad5b-07890b13622a","keyword":"<span style=\"color:red\">松弛</span>","originalKeyword":"松弛"},{"id":"86146b66-717a-48e6-9c47-2a65f3810501","keyword":"蠕变","originalKeyword":"蠕变"},{"id":"c6e228ed-72f5-4841-b0f8-f23fa20397f8","keyword":"结晶","originalKeyword":"结晶"}],"language":"zh","publisherId":"gfzclkxygc201312010","title":"聚对苯二甲酸乙二醇酯/Ti3N4纳米复合材料的<span style=\"color:red\">链</span><span style=\"color:red\">段</span><span style=\"color:red\">松弛</span>","volume":"29","year":"2013"},{"abstractinfo":"氨基树脂与磷酸酯组成的复配体系防火性能佳,但交联密度大,因此涂层的柔韧性、抗龟裂性差.为了改善体系柔韧性、抗龟裂性,将不同链长的聚乙二醇(PEG)与多聚磷酸(PPA)、多元醇合成聚磷酸酯,再与甲醚化的三聚氰胺甲醛树脂复配,制备了膨胀阻燃透明聚合物涂层.通过FT-IR、TG、硬度测试、柔韧性测试、SEM等手<span style=\"color:red\">段</span>,研究了PEG柔性链长对涂层柔韧性、抗龟裂性、阻燃性等的影响规律.结果表明:PEG<span style=\"color:red\">链</span><span style=\"color:red\">段</span>的引入能有效改善涂层的柔韧性,链长越长,柔韧性、抗龟裂性越佳,但链长过长,阻燃性降低.","authors":[{"authorName":"胡晓仙","id":"e72b7078-e7a7-4b93-bd9b-d1289aabd815","originalAuthorName":"胡晓仙"},{"authorName":"洪玲","id":"06bc3828-6019-475d-9685-d1a1c6b4ba48","originalAuthorName":"洪玲"}],"doi":"","fpage":"42","id":"16111071-0800-4818-ad8a-595ca5740e4f","issue":"9","journal":{"abbrevTitle":"TLGY","coverImgSrc":"journal/img/cover/TLGY.jpg","id":"61","issnPpub":"0253-4312","publisherId":"TLGY","title":"涂料工业   "},"keywords":[{"id":"e6bc0cfb-8039-4481-893a-3bfdf74c87fe","keyword":"透明涂层","originalKeyword":"透明涂层"},{"id":"9c58aebd-e1c3-4c81-a717-a7f91b883a22","keyword":"膨胀阻燃","originalKeyword":"膨胀阻燃"},{"id":"b02ff987-9db5-44fb-a057-f3fca87aa7c2","keyword":"聚乙二醇","originalKeyword":"聚乙二醇"},{"id":"7ad390f3-afb7-4c3e-ab5b-d1617da5f7f3","keyword":"柔韧性","originalKeyword":"柔韧性"}],"language":"zh","publisherId":"tlgy201309008","title":"聚乙二醇<span style=\"color:red\">链</span><span style=\"color:red\">段</span>对透明防火涂层柔韧性及阻燃性的影响","volume":"43","year":"2013"}],"totalpage":1560,"totalrecord":15598}