生物质资源产量大,但是利用效率不高,将其制备成高吸附性水凝胶不仅可消除环境污染,减少资源浪费,还可以有效地降低成本。综述了近年来天然生物质功能性水凝胶的制备原料及其制备方法,重点概述了水凝胶在重金属离子和染料吸附方面的应用,总结并展望了生物质凝胶的重点研究方向和未来发展前景。
There are large amounts of biomass resources produced in our country,but the utilization rate is low.These natural polymers can be synthesized into hydrogel materials with excellent adsorption properties.It can not only eliminate environmental pollution,reduce waste of resources,but also can reduce costs effectively.This arti-cle reviews the raw materials and preparation method of natural biomass hydrogels.Moreover,the application on re-moval of heavy metal ions and dye are discussed.Finally,research direction of the bio-hydrogels are summarized.
参考文献
[1] | Hoffman AS.Hydrogels for biomedical applications.[J].Advanced drug delivery reviews,20021(1):3-12. |
[2] | Qian-Qian Zhong;Qin-Yan Yue;Bao-Yu Gao.A novel amphoteric adsorbent derived from biomass materials: Synthesis and adsorption for Cu(II)/Cr(VI) in single and binary systems[J].Chemical engineering journal,2013:90-98. |
[3] | 周建华;王林本;孙根行.有机/无机纳米复合水凝胶的制备与应用[J].材料导报,2014(13):1-8. |
[4] | Ibrahim SM;El Salmawi KM;Zahran AH.Synthesis of crosslinked superabsorbent carboxymethyl cellulose/acrylamide hydrogels through electron-beam irradiation[J].Journal of Applied Polymer Science,20073(3):2003-2008. |
[5] | Murthy PSK;Mohan YM;Varaprasad K;Sreedhar B;Raju KM.First successful design of semi-IPN hydrogel-silver nanocomposites: A facile approach for antibacterial application[J].Journal of Colloid and Interface Science,20082(2):217-224. |
[6] | Jinku Kim;Kee-Won Lee;Theresa E.Hefferan.Synthesis and Evaluation of Novel Biodegradable Hydrogels Based on Poly(ethylene glycol)and Sebacic Acid as Tissue Engineering Scaffolds[J].Biomacromolecules,20081(1):149-157. |
[7] | Diana Ciolacu;Ana Maria Oprea;Narcis Anghel;Georgeta Cazacu;Maria Cazacu.New cellulose-lignin hydrogels and their application in controlled release of polyphenols[J].Materials science & engineering, C. Biomimetic and supramolecular systems,20123(3):452-463. |
[8] | Stephanie Laurichesse;Luc Averous.Chemical modification of lignins: Towards biobased polymers[J].Progress in Polymer Science,20147(7):1266-1290. |
[9] | Zhu, JY;Pan, XJ.Woody biomass pretreatment for cellulosic ethanol production: Technology and energy consumption evaluation[J].Bioresource Technology: Biomass, Bioenergy, Biowastes, Conversion Technologies, Biotransformations, Production Technologies,201013(13):4992-5002. |
[10] | Guilherme MR;Reis AV;Paulino AT;Fajardo AR;Muniz EC;Tambourgi EB.Superabsorbent hydrogrel based on modified polysaccharide for removal of Pb2+ and Cu2+ from water with excellent performance[J].Journal of Applied Polymer Science,20075(5):2903-2909. |
[11] | Dong Ruan;Lina Zhang;Jinping Zhou;Huiming Jin;Hui Chen.Structure and Properties of Novel Fibers Spun from Cellulose in NaOH/Thiourea Aqueous Solution[J].Macromolecular bioscience,200412(12):1105-1112. |
[12] | Huajin Jin;Chunxi Zha;Lixia Gu.Direct dissolution of cellulose in NaOH/thiourea/urea aqueous solution[J].Carbohydrate research,20076(6):851-858. |
[13] | Striouk S.;Wolf BA..Fractional dissolution of "solid" unsubstituted cellulose[J].Macromolecular chemistry and physics,200015(15):1946-1949. |
[14] | Frank Hermanutz;Frank Gahr;Eric Uerdingen;Frank Meister;Birgit Kosan.New Developments in Dissolving and Processing of Cellulose in Ionic Liquids[J].Macromolecular symposia,2008:23-27. |
[15] | Su JC;Liu SQ;Joshi SC;Lam YC.Effect of SDS on the gelation of hydroxypropylmethylcellulose hydrogels[J].Journal of thermal analysis and calorimetry,20082(2):495-501. |
[16] | Xiao, C.;Gao, F.;Gao, Y..Controlled preparation of physically crosslinked chitosan-g-poly(vinyl alcohol) hydrogel[J].Journal of Applied Polymer Science,20105(5):2946-2950. |
[17] | Yang ZG;Ding JD.A thermosensitive and biodegradable physical gel with chemically crosslinked nanogels as the building block[J].Macromolecular rapid communications: Publishing the newsletters of the European Polymer Federation,20089(9):751-756. |
[18] | Margaretha Soderqvist Lindblad;Ann-Christine Albertsson;Elisabetta Ranucci;Michele Laus;Elena Giani.Biodegradable Polymers from Renewable Sources:Rheological Characterization of Hemicellulose-Based Hydrogels[J].Biomacromolecules,20052(2):684-690. |
[19] | Todd R. Hoare;Daniel S. Kohane.Hydrogels in drug delivery: Progress and challenges[J].Polymer,20088(8):1993-2007. |
[20] | E.Marsano;E.Bianchi;A.Viscardi.Stimuli responsive gels based on interpenetrating network of hydroxy propylcellulose and poly(N-isopropylacrylamide)[J].Polymer: The International Journal for the Science and Technology of Polymers,20041(1):157-163. |
[21] | Sannino A.;Maffezzoli A.;Nicolais L..Introduction of molecular spacers between the crosslinks of a cellulose-based superabsorbent hydrogel: Effects on the equilibrium sorption properties[J].Journal of Applied Polymer Science,20031(1):168-174. |
[22] | Chang CY;Lue A;Zhang L.Effects of crosslinking methods on structure and properties of cellulose/PVA hydrogels[J].Macromolecular chemistry and physics,200812(12):1266-1273. |
[23] | Ann-Christine Albertsson;Jens Voepel;Ulrica Edlund.Design of Renewable Hydrogel Release Systems from Fiberboard Mill Wastewater[J].Biomacromolecules,20105(5):1406-1411. |
[24] | Nishida M.;Uraki Y.;Sano Y..Lignin gel with unique swelling property[J].Bioresource Technology: Biomass, Bioenergy, Biowastes, Conversion Technologies, Biotransformations, Production Technologies,20031(1):81-83. |
[25] | IRINA ELENA RASCHIP;CORNELIA VASILE;DIANA CIOLACU.Semi-interpenetrating Polymer Networks Containing Polysaccharides. I Xanthan/Lignin Networks[J].High performance polymers,20075/6(5/6):603-620. |
[26] | Chenite A iosyntech.com;Chaput C;Wang D;Combes C;Buschmann MD;Hoemann CD;Leroux JC;Atkinson BL;Binette F;Selmani A.Novel injectable neutral solutions of chitosan form biodegradable gels in situ.[J].Biomaterials,200021(21):2155-2161. |
[27] | Jagjit R.Khurma;Ashveen V.Nand.Temperature and pH sensitive hydrogels composed of chitosan and poly(ethylene glycol)[J].Polymer bulletin,20086(6):805-812. |
[28] | Wang, W.-B.;Huang, D.-J.;Kang, Y.-R.;Wang, A.-Q..One-step in situ fabrication of a granular semi-IPN hydrogel based on chitosan and gelatin for fast and efficient adsorption of Cu~(2+) ion[J].Colloids and Surfaces, B. Biointerfaces,2013:51-59. |
[29] | Athawale VD.;Lele V..Recent trends in hydrogels based on starch-graft-acrylic acid: A review [Review][J].Starch: International Journal for the Investigation, Processing and Use of Carbohydrates and their Derivatives: Internationale Zeitschrift fur die Erforschung, Verarbeitung und Verwendung von Kohlenhydraten und deren Derivaten,20011(1):7-13. |
[30] | 杨小玲;张卫红.Cu2+吸附用Fe3O4/淀粉接枝聚丙烯酸磁性微球的制备[J].中国胶粘剂,2012(11):10-14. |
[31] | 庄辰;陶芙蓉;于润慧;崔月芝.明胶/胶原改性的研究进展[J].化学通报(印刷版),2015(3):202-207. |
[32] | 竺亚斌;浦炳寅.耐盐性高吸水树脂的合成及性能研究[J].高分子材料科学与工程,1999(6):169-170. |
[33] | 乌兰;柳明珠.玉米淀粉接枝丙烯酸制备高吸水性树脂[J].高分子材料科学与工程,2006(1):250-253. |
[34] | Hasine Kasgoz;Saadet Ozgumus;Murat Orbay.Modified polyacrylamide hydrogels and their application in removal of heavy metal ions[J].Polymer: The International Journal for the Science and Technology of Polymers,20036(6):1785-1793. |
[35] | W.L. Yan;Renbi Bai.Adsorption of lead and humic acid on chitosan hydrogel beads[J].Water research: A journal of the international water association,20054(4):688-698. |
[36] | Parajuli D;Adhikari CR;Kuriyama M;Kawakita H;Ohto K;Inoue K;Funaoka M.Selective recovery of gold by novel lignin-based adsorption gels[J].Industrial & Engineering Chemistry Research,20061(1):8-14. |
[37] | Li, N;Bai, RB.A novel amine-shielded surface cross-linking of chitosan hydrogel beads for enhanced metal adsorption performance[J].Industrial & Engineering Chemistry Research,200517(17):6692-6700. |
[38] | El-Din HMN;Taleb MFA;El-Naggar AWM.Metal sorption and swelling characters of acrylic acid and sodium alginate based hydrogels synthesized by gamma irradiation[J].Nuclear Instruments and Methods in Physics Research, Section B. Beam Interactions with Materials and Atoms,200811(11):2607-2613. |
[39] | Ghanshyam S.Chauhan;Baljit Singh;Sandeep Chauhan;Monica Verma;Swati Mahajan.Sorption of some metal ions on cellulosic-based hydrogels[J].Desalination: The International Journal on the Science and Technology of Desalting and Water Purification,20051/3(1/3):217-224. |
[40] | E.S. Abdel-Halim;Salem S. Al-Deyab.Preparation of poly(acrylic acid)/starch hydrogel and its application for cadmium ion removal from aqueous solutions[J].Reactive & functional polymers,2014Feb.(Feb.):1-8. |
[41] | Haixia Qiu;Zhaoxia Qiu;Jialing Wang;Ruobing Zhang;Fuyuan Zheng.Enhanced Swelling and Methylene Blue Adsorption of Polyacrylamide-Based Superabsorbents Using Alginate Modified Montmorillonite[J].Journal of Applied Polymer Science,20146(6):40013-1-40013-9. |
[42] | Yanru Shi;Zhenhua Xue;Ximing Wang.Removal of methylene blue from aqueous solution by sorption on lignocellulose-g-poly(acrylic acid)/ montmorillonite three-dimensional cross-linked polymeric network hydrogels[J].Polymer bulletin,20134(4):1163-1179. |
[43] | Dan Xu;San Hein;Leslie S. Loo.Modified Chitosan Hydrogels for the Removal of Acid Dyes at High pH: Modification and Regeneration[J].Industrial & Engineering Chemistry Research,201110(10):6343-6346. |
[44] | Guillermo J. Copello;Andrea M. Mebert;M. Raineri;Mariela P. Pesenti;Luis E. Diaz.Removal of dyes from water using chitosan hydrogel/SiO_2 and chitin hydrogel/SiO_2 hybrid materials obtained by the sol-gel method[J].Journal of hazardous materials,20111(1):932-939. |
[45] | Liu, J.;Su, Y.;Li, Q.;Yue, Q.;Gao, B..Preparation of wheat straw based superabsorbent resins and their applications as adsorbents for ammonium and phosphate removal[J].Bioresource Technology: Biomass, Bioenergy, Biowastes, Conversion Technologies, Biotransformations, Production Technologies,2013:32-39. |
[46] | Evaluation of ammonium removal using a chitosan-g-poly (acrylic acid)/rectorite hydrogel composite[J].Journal of hazardous materials,20091/3(1/3):671. |
[47] | Peter Kofinas;Dimitri R. Kioussis.Reactive phosphorus removal from aquaculture and poultry productions systems using polymeric hydrogels[J].Environmental Science & Technology: ES&T,20032(2):423-427. |
[48] | Hiroyuki Kono;Ikuo Oeda;Taichi Nakamura.The preparation, swelling characteristics, and albumin adsorption and release behaviors of a novel chitosan-based polyampholyte hydrogel[J].Reactive & functional polymers,20131(1):97-107. |
[49] | Bing Hui;Yi Zhang;Lin Ye.Preparation of PVA hydrogel beads and adsorption mechanism for advanced phosphate removal[J].Chemical engineering journal,2014:207-214. |
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