基于钌金属的烯烃复分解反应现今已成为一种至关重要且快速有效的催化反应类型，在聚合领域以及现代有机合成的应用方面起着改革性的推进作用。作为烯烃复分解反应催化剂的一种，钌茚基催化剂在该领域得到成功应用。结合近年来钌茚基催化剂在烯烃复分解反应中的合成研究进展，简述了其发展过程，介绍了该领域创新性的研究成果，重点论述了一些新型钌茚基催化剂的合成方法，并且探讨了辅助配体的结构对催化剂稳定性和活性的影响，最后对其发展方向以及应用前景进行了展望。
Olefin metathesis based on ruthenium has already become an important and effective catalytic reaction and has revolutionized a variety of applications not only in polymer science but also in modern organic synthesis.Ru-thenium indenylidene catalysts,a family of ruthenium olefin metathesis catalysts,have played a pivotal role in the suc-cess story of this technology.In this review,the recent synthesis research progress on ruthenium indenylidene cata-lysts is discussed.Firstly,the development of ruthenium indenylidene catalysts is introduced followed by an overview of the innovative work on the design of ruthenium indenylidene catalysts till today.Moreover,the synthesis of some novel important ruthenium indenylidene catalysts is highlighted.In addition,the relation between the structure of an-cillary ligands and the stability as well as activity of catalysts is discussed.Finally,the development directions and ap-plication prospects of ruthenium indenylidene catalysts are proposed.
参考文献
| [1] | Steven G.Aitken;Andrew D.Abell.Olefin Metathesis:Catalyst Development,Microwave Catalysis,and Domino Applications[J].Australian Journal of Chemistry: A Journal for the Publication of Original Research in All Branches of Chemistry,20051(1):3-13. |
| [2] | Wu Z.;Grubbs RH.;Ziller JW.;Nguyen ST..REACTIONS OF RUTHENIUM CARBENES OF THE TYPE (PPH(3))(2)(X)(2)RU=CH-CH=CPH(2) (X=CL AND CF3COO) WITH STRAINED ACYCLIC OLEFINS AND FUNCTIONALIZED OLEFINS[J].Journal of the American Chemical Society,199520(20):5503-5511. |
| [3] | Schwab P;Grubbs RH;Ziller JW.SYNTHESIS AND APPLICATIONS OF RUCL2(=CHR')(PR(3))(2) - THE INFLUENCE OF THE ALKYLIDENE MOIETY ON METATHESIS ACTIVITY[J].Journal of the American Chemical Society,19961(1):100-110. |
| [4] | Boeda F;Clavier H;Nolan SP.Ruthenium-indenylidene complexes: powerful tools for metathesis transformations[J].Chemical communications,200824(24):2726-2740. |
| [5] | Ding Fu;Sun Yaguang;Monsaert Stijn;Drozdzak Renata;Dragutan Ileana;Dragutan Valerian;Verpoort Francis.Ruthenium Complexes Containing Bidentate Schiff Base Ligands as Precursors of Homogeneous and Immobilized Catalysts[J].Current Organic Synthesis,20084(4):291-304. |
| [6] | Ofele, K;Tosh, E;Taubmann, C;Herrmann, WA.Carbocyclic Carbene Metal Complexes[J].Chemical Reviews,20098(8):3408-3444. |
| [7] | Lozano-Vila, A.M.;Monsaert, S.;Bajek, A.;Verpoort, F..Ruthenium-based olefin metathesis catalysts derived from alkynes[J].Chemical Reviews,20108(8):4865-4909. |
| [8] | Yu, Baoyi;Xie, Yu;Hamad, Fatma B.;Leus, Karen;Lyapkov, Alex A.;Van Hecke, Kristof;Verpoort, Francis.Synthesis and characterization of non-chelating ruthenium-indenylidene olefin metathesis catalysts derived from substituted 1,1-diphenyl-2-propyn-1-ols[J].New Journal of Chemistry,20153(3):1858-1867. |
| [9] | Furstner A.;Thiel OR..Formal total synthesis of (-)-balanol: Concise approach to the hexahydroazepine segment based on RCM[J].The Journal of Organic Chemistry,20006(6):1738-1742. |
| [10] | Clavier H;Nolan SP.N-heterocyclic carbene and phosphine ruthenium indenylidene precatalysts: A comparative study in Olefin metathesis[J].Chemistry: A European journal,200728(28):8029-8036. |
| [11] | Charles E. Diesendruck;Eyal Tzur;N. Gabriel Lemcoff.The Versatile Alkylidene Moiety in Ruthenium Olefin Metathesis Catalysts[J].European journal of inorganic chemistry,200928(28):4185-4203. |
| [12] | Clavier, Herve;Urbina-Blanco, Cesar A.;Nolan, Steven P..Indenylidene Ruthenium Complex Bearing a Sterically Demanding NHC Ligand: An Efficient Catalyst for Olefin Metathesis at Room Temperature[J].Organometallics,20099(9):2848-2854. |
| [13] | Xavier Sauvage;Albert Demonceau;Lionel Delaude.Imidazol(in)ium-2-carboxylates as N-Heterocyclic Carbene Precursors for the Synthesis of Second Generation Ruthenium Metathesis Catalysts[J].Advanced synthesis & catalysis,200911/12(11/12):2031-2038. |
| [14] | Monsaert, S;Drozdzak, R;Dragutan, V;Dragutan, I;Verpoort, F.Indenylidene-ruthenium complexes bearing saturated N-heterocyclic carbenes: Synthesis and catalytic investigation in olefin metathesis reactions[J].European journal of inorganic chemistry,20083(3):432-440. |
| [15] | Monsaert S;De Canck E;Drozdzak R;Van Der Voort P;Verpoort F;Martins JC;Hendrickx PMS.Indenylidene Complexes of Ruthenium Bearing NHC Ligands - Structure Elucidation and Performance as Catalysts for Olefin Metathesis[J].European journal of organic chemistry,20095(5):655-665. |
| [16] | Urbina-Blanco, C.A.;Bantreil, X.;Wappel, J.;Schmid, T.E.;Slawin, A.M.Z.;Slugovc, C.;Cazin, C.S.J..Mixed N-heterocyclic carbene/phosphite ruthenium complexes: The effect of a bulkier NHC.[J].Organometallics,201321(21):6240-6247. |
| [17] | Gatti, M.;Vieille-Petit, L.;Luan, X.;Mariz, R.;Drinkel, E.;Linden, A.;Dorta, R..Impact of NHC ligand conformation and solvent concentration on the ruthenium-catalyzed ring-closing metathesis reaction[J].Journal of the American Chemical Society,200927(27):9498-9499. |
| [18] | Bantreil, X.;Schmid, T.E.;Randall, R.A.M.;Slawin, A.M.Z.;Cazin, C.S.J..Mixed N-heterocyclic carbene/phosphite ruthenium complexes: Towards a new generation of olefin metathesis catalysts[J].Chemical communications,201038(38):7115-7117. |
| [19] | Kuhn, KM;Bourg, JB;Chung, CK;Virgil, SC;Grubbs, RH.Effects of NHC-Backbone Substitution on Efficiency in Ruthenium-Based Olefin Metathesis[J].Journal of the American Chemical Society,200914(14):5313-5320. |
| [20] | Peeck, L.H.;Plenio, H..Synthesis and RCM activity of [(NHC)(NHC_(ewg))RuCl _2(3-phenylindenylid-1-ene)] complexes[J].Organometallics,201012(12):2761-2766. |
| [21] | Bantreil, X.;Randall, R.A.M.;Slawin, A.M.Z.;Nolan, S.P..Ruthenium complexes bearing two N-heterocyclic carbene ligands in low catalyst loading olefin metathesis reactions[J].Organometallics,201013(13):3007-3011. |
| [22] | Clavier H;Petersen JL;Nolan SP.A pyridine-containing ruthenium-indenylidene complex: Synthesis and activity in ring-closing metathesis[J].Journal of Organometallic Chemistry,200624/25(24/25):5444-5447. |
| [23] | Urbina-Blanco, C.A.;Leitgeb, A.;Slugovc, C.;Bantreil, X.;Clavier, H.;Slawin, A.M.Z.;Nolan, S.P..Olefin metathesis featuring ruthenium indenylidene complexes with a sterically demanding NHC ligand[J].Chemistry: A European journal,201118(18):5045-5053. |
| [24] | Hendrickx, PMS;Drozdzak, R;Verpoort, F;Martins, JC.Assignment and conformational investigation of asymmetric phenylindenylidene ruthenium complexes bearing N,O-bidentate ligands[J].Magnetic Resonance in Chemistry: MRC,20106(6):443-449. |
| [25] | Opstal T.;Verpoort F..Ruthenium indenylidene and vinylidene complexes bearing Schiff bases: Potential catalysts in enol-ester synthesis[J].Synlett,20026(6):935-941. |
| [26] | Hejl A;Day MW;Grubbs RH.Latent olefin metathesis catalysts featuring chelating alkylidenes[J].Organometallics,200626(26):6149-6154. |
| [27] | Keitz, BK;Grubbs, RH.A Tandem Approach to Photoactivated Olefin Metathesis: Combining a Photoacid Generator with an Acid Activated Catalyst[J].Journal of the American Chemical Society,20096(6):2038:1-2038:4. |
| [28] | Chang S.;Wang CM.;Henling LM.;Grubbs RH.;Jones L..Synthesis and characterization of new ruthenium-based olefin metathesis catalysts coordinated with bidentate Schiff-base ligands[J].Organometallics,199816(16):3460-3465. |
| [29] | Bart Allaert;Nicolai Dieltiens;Nele Ledoux.Synthesis and activity for ROMP of bidentate Schiff base substituted second generation Grubbs catalysts[J].Journal of molecular catalysis, A. Chemical,20061/2(1/2):221-226. |
| [30] | Bengi Ozgun Oztiirk;Emel Bucak;Solmaz Karabulut.In situ modification of the Grubbs first generation catalyst: A highly controllable metathesis catalyst bearing tridentate Schiff base ligands[J].Journal of molecular catalysis, A. Chemical,2013:53-62. |
| [31] | Ozturk, Bengi Ozgun;Sehitoglu, Solmaz Karabulut;Meier, Michael A. R..A latent and controllable ruthenium-indenylidene catalyst for emulsion ROMP in water[J].European Polymer Journal,2015:116-123. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%