以高软化点煤沥青和热塑性酚醛树脂为主要原料,机械混合均匀后,采用悬浮法制备沥青/树脂基复合球形活性炭.使用扫描电子显微镜(SEM)、N2物理吸脱附仪、颗粒强度测定仪,对复合球的表面形貌、孔道结构和机械强度进行表征.实验结果表明:树脂的加入不仅能够拓宽球形活性炭的孔径分布,而且能够有效地提高球形活性炭的机械强度.树脂含量为30%的球形活性炭BET表面积为1049 m2/g,总孔容为0.62 cm3/g,平均孔径为8.8nm,同时机械强度达6.2N.通过苯的静态吸脱附测试研究了沥青树脂基球形活性炭的吸附性能,结果表明:复合球形活性炭基本上保持了沥青基球形活性炭的快速吸脱附性能,树脂的加入并没有明显延长复合球形活性炭对苯的吸脱附时间.
参考文献
[1] | Jun-Bing Yang;Li-Cheng Ling;Lang Liu;Fei-Yu Kang;Zheng-Hong Huang;Hui Wu .Preparation and properties of phenolic resin-based activated carbon spheres with controlled pore size distribution[J].Carbon: An International Journal Sponsored by the American Carbon Society,2002(6):911-916. |
[2] | 杨骏兵,康飞宇.球形活性炭及其应用[J].材料导报,2002(05):59-61. |
[3] | Zhang H Y;Dai B;Wang X G et al.Non-mercury catalytic acetylene hydrochlorination over bimetallic Au-Co(Ⅲ)/SAC catalysts for vinyl chloride monomer production[J].Green Chemistry,2013,15(3):829. |
[4] | 吕春祥,李开喜,吕永根,梁晓怿,宋燕,凌立成,王占仁,国建琴.沥青基球状活性炭的医用性能评价[J].新型炭材料,2002(03):11-14. |
[5] | 刘小军,梁晓怿,刘朝军,张睿,詹亮,乔文明,凌立成.沥青球的HNO_3氧化和炭化行为[J].新型炭材料,2010(01):29-34. |
[6] | S. Yenisoy-Karakas;A. Aygun;M. Gunes .Physical and chemical characteristics of polymer-based spherical activated carbon and its ability to adsorb organics[J].Carbon: An International Journal Sponsored by the American Carbon Society,2004(3):477-484. |
[7] | 张永刚,王成扬,闫裴.石油沥青基球形活性炭孔结构和吸附性能的研究[J].炭素技术,2006(03):10-13. |
[8] | 张永刚,王成扬,闫裴.添加炭黑对石油沥青基球形活性炭孔结构的影响[J].天津大学学报,2003(02):201-204. |
[9] | Lillo-Rodenas MA;Cazorla-Amoros D;Linares-Solano A .Behaviour of activated carbons with different pore size distributions and surface oxygen groups for benzene and toluene adsorption at low concentrations[J].Carbon: An International Journal Sponsored by the American Carbon Society,2005(8):1758-1767. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%