简要回顾了钙钛矿太阳能电池的发展历史,解释了钙钛矿太阳能电池本质上是固态染料敏化太阳能电池。介绍了钙钛矿太阳能电池的微观发电机理,结合钙钛矿太阳能电池的能级图分析讨论了钙钛矿与电子传输层和空穴传输层的能级匹配。分析总结了钙钛矿太阳能电池的光伏技术参数,包括光生电流密度、开路电压、填充因子、能量转换效率以及光伏性能的稳定性。钙钛矿太阳能电池的能量转换效率、短路电流密度和开路电压均已超过非晶硅薄膜太阳能电池,填充因子与非晶硅薄膜太阳能电池很接近。钙钛矿太阳能电池有希望实现产业化而成为下一代薄膜太阳能电池。指出了钙钛矿太阳能电池大规模市场应用在制造技术上的瓶颈即空穴传输层的造价昂贵,并综述了解决该瓶颈的最新研究工作。
Development history of perovskite solar cells is briefly reviewed.Perovskite solar cells are solid-state dye-sensitized solar cells.The microcosmic mechanism of perovskite solar cells is put forward.Energy levels of the TiO2/CH 3 NH 3 PbI3/spiro-OMeTAD junction are given,showing that the conduction band minimum and valence band maximum of CH 3 NH 3 PbI3 are well positioned for electrons injection into TiO2 and holes transfer to spiro-OMeTAD, respectively.Photovoltaic performance parameters of perovskite solar cells such as short-circuit current density,open-circuit voltages,power conversion efficiency and fill factor are summarized.The power conversion efficiency,short-circuit current density and open-circuit voltage of perovskite solar cells exceed that of a-Si thin film solar cells,while the fill factor approaches that of the latter.A conclusion is drawn that perovskite-based solar cells are expected to rea-lize industrialization and become the next generation thin-film solar cells.The bottleneck of marketization for perovs-kite-based solar cells is the fabrication of expensive hole transportation layer.The researches aim to resolve it are sum-marized.
参考文献
[1] | Hodes G .Perovskite-based solar cells[J].SCIENCE,2013,342:317. |
[2] | Yella A;Lee H W;Tsao H N et al.Porphyrin-sensitized solar cells with cobalt(Ⅱ/Ⅲ)-based redox electrolyte ex-ceed 12% efficiency[J].SCIENCE,2011,334:629. |
[3] | Chondroudis K;Mitzi D B .Electroluminescence from an or-ganic-inorganic perovskite incorporating a quaterthiophene dye within lead halide perovskite layers[J].CHEMISTRY OF MATERIALS,1999,11:3028. |
[4] | Era M;Tsutsui T;Shogo S .Polarized electroluminescence from oriented p-sexiphenyl vacuum-deposited film[J].Applied Physics Letters,1995,67:2436. |
[5] | Kagan C R;Mitzi D B .Organic-inorganic hybrid materials as semiconductor channels in thin film field effect transistors[J].SCIENCE,1999,286:945. |
[6] | O’Regan B;Gr?tzel M .A low-cost,high-efficiency solar cell based on dye-sensitized colloidal TiO2 films[J].NATURE,1991,353:737. |
[7] | Snaith H J;Schmidt-Mende L .Advances in liquid-electro-lyte and solid-state dye-sensitized solar cells[J].Adv Ma-ter,2007,19:3187. |
[8] | Snaith H J;Stavrinadis A;Docampo P et al.Lead-sulphide quantum-dot sensitization of tin oxide based hybrid solar cells[J].SOLAR ENERGY,2011,85:1283. |
[9] | Kamat P V .Quantum dot solar cells:Semiconductor nano-crystals as light harvesters[J].J Phy Chem C,2008,112:18737. |
[10] | Lee H;Leventis H C;Moon S J et al.PbS and US quan-tum dot-sensitized solid-state solar cells:Old concepts,new results[J].Advanced Functional Materials,2009,19:2735. |
[11] | Itzhaik Y;Niitsoo O;Page M et al.Sb2 S3-sensitized nano-porous TiO2 solar cells[J].J Phys Chem C,2009,113:4254. |
[12] | Kamat P V .Quantum dot solar cells.The next big thing in photovoltaics[J].J Phys Chem Lett,2013,4:908. |
[13] | Kojima A;Teshima K;Miyasaka T.Novel photoelec-trochemical cell with mesoscopic electrodes sensitized by lead-halide compounds[A].Cancun, Mexico,2006:92. |
[14] | Kojima A;Teshima K;Miyasaka T.Novel photoelec-trochemical cell with mesoscopic electrodes sensitized by lead-halide compounds[A].Honolulu, Hawaii,2008:105. |
[15] | Kojima A;Teshima K;Miyasaka T .Organometal halide perovskites as visible-light sensitizers for photovoltaic cells[J].Journal of the American Chemical Society,2009,131:6050. |
[16] | Im J H;Lee C R;Lee J W et al.Efficient perovskite quan-tum-dot-sensitized solar cell[J].Nanoscale,2011,3:4088. |
[17] | Kim H S;Lee C R;Im J H et al.Lead iodide perovskite sen-sitized all-solid-state submicron thin film mesoscopic solar cell with efficiency exceeding 9%[J].Sci Rep,2012,2:591. |
[18] | Lee M M;Miyasaka T;Snaith H J et al.Efficient hybrid solar cells based on meso-superstructured organometal halide perovskites[J].SCIENCE,2012,338:643. |
[19] | Burschka, J.;Dualeh, A.;Kessler, F.;Baranoff, E.;Cevey-Ha, N.-L.;Yi, C.;Nazeeruddin, M.K.;Gr?tzel, M. .Tris(2-(1 H -pyrazol-1-yl)pyridine)cobalt(III) as p-type dopant for organic semiconductors and its application in highly efficient solid-state dye-sensitized solar cells[J].Journal of the American Chemical Society,2011(45):18042-18045. |
[20] | Heo, J.H.;Im, S.H.;Noh, J.H.;Mandal, T.N.;Lim, C.-S.;Chang, J.A.;Lee, Y.H.;Kim, H.-J.;Sarkar, A.;Nazeeruddin, M.K.;Gr?tzel, M.;Seok, S.I. .Efficient inorganic-organic hybrid heterojunction solar cells containing perovskite compound and polymeric hole conductors[J].Nature photonics,2013(6):486-491. |
[21] | Liu M Z;Johnston M B;Snaith H J .Efficient planar he-terojunction perovskite solar cells by vapor deposition[J].NATURE,2013,501:395. |
[22] | Xing G;Sum T C;Mathews N et al.Long-range balanced electron-and hole-transport lengths in organic-inorganic CH 3 NH 3 PbI3[J].SCIENCE,2013,342:344. |
[23] | Stranks S D;Eperon Gelis E .Electron-hole diffusion lengths exceeding 1 micrometer in an organometal trihalide perovskite absorber[J].SCIENCE,2013,3429:341. |
[24] | Park N G .Organometal perovskite light absorbers toward a 20% efficiency low-cost solid-state mesoscopic solar cell[J].J Phys Chem Lett,2013,4:2423. |
[25] | Nayak P K;Bisquert J;Cahen D .Assessing possibilities and limits for solar cells[J].Advanced Materials,2011,23:2870. |
[26] | Edri E;Kirmaye S R;Cahen D et al.High open-circuit voltage solar cells based on organic-inorganic lead bromide perovskite[J].J Phys Chem Lett,2013,4:897. |
[27] | Tom Markvart;Luis Castaner;梁俊吾.太阳电池:材料、制备工艺及检测[M].北京:机械工业出版社,2009:154. |
[28] | Burschka J;Pellet N;Gr?tzel M et al.Sequential deposi-tion as a route to high-performance perovskite-sensitized so-lar cells[J].NATURE,2013,499:316. |
[29] | Noh, J.H.;Im, S.H.;Heo, J.H.;Mandal, T.N.;Seok, S.I. .Chemical management for colorful, efficient, and stable inorganic-organic hybrid nanostructured solar cells[J].Nano letters,2013(4):1764-1769. |
[30] | Melas K J;Ding I K;Marchioro A et al.The effect of hole transport material pore filling on photovoltaic performance in solid-state dye-sensitized solar cells[J].Adv Energy Ma-ter,2011,1:407. |
[31] | 马丁·格林;李秀文;谢鸿礼;赵海滨.太阳电池工作原理、工艺和系统的应用[M].北京:电子工业出版社,1987:84. |
[32] | Christians J A;Fung R M;Kamat P V .An inorganic hole conductor for organic-lead halide perovskite solar cells im-proved hole conductivity with copper iodide[J].Journal of the American Chemical Society,2014,136:758. |
[33] | Peng Q;Soichiro T;Seigo I et al.Inorganic hole conduc-tor-based lead halide perovskite solar cells with 12.4% con-version efficienc[J].J Phys Chem Lett,2014,5:3834. |
[34] | Severin N H;Tomas L;Giles E E et al.Enhanced hole extraction in perovskite solar cells through carbon nanotubes[J].J Phys Chem Lett,2014,5:4207. |
[35] | Unger E L;Hoke E T;Bailie C D et al.Hysteresis and transient behavior in current-voltage measurements of hy-brid-perovskite absorber solar cells[J].Energy Environ Sci,2014,7:3690. |
[36] | Wei J;Zhao Y C;Li H et al.Hysteresis analysis based on the ferroelectric effect in hybrid perovskite solar cells[J].J Phys Chem Lett,2014,5:3937. |
[37] | Chen H W;Sakai N;Ikegami M et al.Emergence of hys-teresis and transient ferroelectric response in organo-lead halide perovskite solar cells[J].J Phys Chem Lett,2015,6:164. |
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