目前直接甲醇燃料电池中阴极催化剂一般是贵金属铂,它的主要问题是成本高、对甲醇无耐受性及易中毒等.碳材料由于成本低、能大量制备和易于修饰等优点而被广泛应用于各个领域,如电催化、锂离子电池、超级电容器等.综述了近年来碳基纳米材料作为阴极催化剂的研究进展,包括碳纳米管、石墨烯、介孔碳等多种碳材料.主要通过对这些碳材料进行元素掺杂和以它为载体与非贵金属材料复合来提高和改善催化剂的性能.最后对未束发展提出了展望.
参考文献
| [1] | Vojislav R Stamenkovic;Ben Fowler;Nenad M Markovi(c) et al.Improved oxygen reduction activity on Pt3Ni (111) via increased surface site availability[J].SCIENCE,2007,315:493. |
| [2] | Wang Shuangyin;Iyyamperumal Eswaramoorthi;Dai Liming et al.Vertically aligned BCN nanotubes as efficient metal-free electrocatalysts for the oxygen reduction reaction:A synergetic effect by Co-doping with boron and nitroge[J].Angewandte Chemie,2011,123:11960. |
| [3] | Yang Chijen .An impending platinum crisis and its implications for the future of the automobile[J].ENERGY POLICY,2009,37:1805. |
| [4] | Brian C H Steele;Angelika Heinzel .Materials for fuel-cell technologies[J].NATURE,2001,414:345. |
| [5] | Dong Youzhen;Wu Yongmin;Li Jinghong et al.Electrocatalysis on shape-controlled titanium nitride nanocrystals for the oxygen reduction reaction[J].ChemSusChem,2013,6:2016. |
| [6] | Wu, H.;Chen, W. .Copper nitride nanocubes: Size-controlled synthesis and application as cathode catalyst in alkaline fuel cells[J].Journal of the American Chemical Society,2011(39):15236-15239. |
| [7] | Liang Yongye;Li Yanguang;Dai Hongjie et al.Co3O4 nanocrystals on graphene as a synergistic catalyst for oxygen reduction reaction[J].NATURE MATERIALS,2011,10:780. |
| [8] | Qu Jianying;Shen Yan;Dong Shaojun et al.Preparation of hybrid thin film modified carbon nanotubes on glassy carbon electrode and its electrocatalysis for oxygen reduction[J].Chemistry Communications,2004,10:34. |
| [9] | Prabhuram J;Zhao T S;Liang Z X et al.Multiwalled carbon nanotube supported PtRu for the anode of direct methanol fuel cells[J].Journal of Physical Chemistry B,2006,110:5245. |
| [10] | Nitrogen-doped Carbon Nanotube Arrays With High Electrocatalytic Activity For Oxygen Reduction[J].Science,2009(Feb.6 TN.5915):760. |
| [11] | Yu Dingshan;Xue Yuhua;Dai Liming .Vertically aligned carbon nanotube arrays Co-doped with phosphorus and nitrogen as efficient metal-free electrocatalysts for oxygen reduction[J].J Phys Chem Lett,2012,3:2863. |
| [12] | Iyyamperumal, E.;Wang, S.;Dai, L. .Vertically aligned BCN nanotubes with high capacitance[J].ACS nano,2012(6):5259-5265. |
| [13] | Wang, S.;Yu, D.;Dai, L. .Polyelectrolyte functionalized carbon nanotubes as efficient metal-free electrocatalysts for oxygen reduction[J].Journal of the American Chemical Society,2011(14):5182-5185. |
| [14] | Liang, Y.;Wang, H.;Diao, P.;Chang, W.;Hong, G.;Li, Y.;Gong, M.;Xie, L.;Zhou, J.;Wang, J.;Regier, T.Z.;Wei, F.;Dai, H. .Oxygen reduction electrocatalyst based on strongly coupled cobalt oxide nanocrystals and carbon nanotubes[J].Journal of the American Chemical Society,2012(38):15849-15857. |
| [15] | Zhang Yaping;Hu Yongyou;Hou Bin et al.Manganese dioxide-coated carbon nanotubes as an improved cathodic catalyst for oxygen reduction in a microbial fuel cell[J].Journal of Power Sources,2011,196:9284. |
| [16] | Sun Meng;Dong Youzhen;Zhang Gong et al.α-Fe2O3 spherical nanocrystals supported on CNTs as efficient nonnoble electrocatalysts for the oxygen reduction reaction[J].J Mater Chem A,2014,2:13635. |
| [17] | Huang, Y.;Liang, J.;Chen, Y. .An overview of the applications of graphene-based materials in supercapacitors[J].Small,2012(12):1805-1834. |
| [18] | Wang, Y.;Shao, Y.;Matson, D.W.;Li, J.;Lin, Y. .Nitrogen-doped graphene and its application in electrochemical biosensing[J].ACS nano,2010(4):1790-1798. |
| [19] | Chen Chengmeng;Zhang Qiang;Wang Maozhang et al.Structural evolution during annealing of thermally reduced graphene nanosheets for application in supercapacitors[J].CARBON,2012,50:3572. |
| [20] | Yang Shubin;Zhi Linjie;Müllen Klaus et al.Efficient synthesis of heteroatom(N or S)-doped graphene based on ultrathin graphene oxide-porous silica sheets for oxygen reduction reactions[J].Advanced Functional Materials,2012,22:3634. |
| [21] | Yang, Z.;Yao, Z.;Li, G.;Fang, G.;Nie, H.;Liu, Z.;Zhou, X.;Chen, X.;Huang, S. .Sulfur-doped graphene as an efficient metal-free cathode catalyst for oxygen reduction[J].ACS nano,2012(1):205-211. |
| [22] | Bj(o)rn Trauzettel;Denis V Bulaev;Guido Burkard et al.Spin qubits in graphene quantum dots[J].Nature Physics,2007,3:192. |
| [23] | Xu, Z.;Buehler, M.J. .Geometry controls conformation of graphene sheets: Membranes, ribbons, and scrolls[J].ACS nano,2010(7):3869-3876. |
| [24] | Yan, Z.;Liu, Y.;Lin, J.;Peng, Z.;Wang, G.;Pembroke, E.;Zhou, H.;Xiang, C.;Raji, A.-R.O.;Samuel, E.L.G.;Yu, T.;Yakobson, B.I.;Tour, J.M. .Hexagonal graphene onion rings[J].Journal of the American Chemical Society,2013(29):10755-10762. |
| [25] | Cao, X.;Shi, Y.;Shi, W.;Lu, G.;Huang, X.;Yan, Q.;Zhang, Q.;Zhang, H. .Preparation of novel 3D graphene networks for supercapacitor applications[J].Small,2011(22):3163-3168. |
| [26] | Wu Longfei;Feng Hongbin et al.Graphene-based hollow spheres as efficient electrocatalysts for oxygen reduction[J].Nanoscale,2013,5:10839. |
| [27] | Tian Guili;Zhao Mengqiang;Yu Dingshan et al.Nitrogendoped graphene/carbon nanotube hybrids:In situ formation on bifunctional catalysts and their superior electrocatalytic activity for oxygen evolution/reduction reaction[J].SMALL,2014,10:2251. |
| [28] | Liu Mengjia;Dong Youzhen;Li Jinghong et al.Titanium nitride nanocrystals on nitrogen-doped graphene as an efficient electrocatalyst for oxygen reduction reaction[J].Chemistry-A European Journal,2013,19:14781. |
| [29] | Wu Zhongshuai;Yang Shubin;Müllen Klaus et al.3D nitrogen-doped graphene aerogel-supported Fe3O4 nanoparticles as efficient electrocatalysts for the oxygen reduction reaction[J].Journal of the American Chemical Society,2012,134:9082. |
| [30] | Yeong Suk Choi;Sang Hoon Joo;Seol-Ah Lee;Dae Jong You;Hansu Kim .Surface Selective Polymerization of Polypyrrole on Ordered Mesoporous Carbon:Enhancing Interfacial Conductivity for Direct Methanol Fuel Cell Application[J].Macromolecules,2006(9):3275-3282. |
| [31] | Joo Sang Hoon;Pak Chanho;Seung Doyoung et al.Ordered mesoporous carbons (OMC) as supports of electrocatalysts for direct methanol fuel cells (DMFC):Effect of carbon precursors of OMC on DMFC performances[J].Electrochimica Acta,2006,52:1618. |
| [32] | Su Fabing;Zeng Jianhuang;Zhao Xiusong et al.Preparation and characterization of highly ordered graphitic mesoporous carbon as a Pt catalyst support for direct methanol fuel cells[J].CHEMISTRY OF MATERIALS,2005,17:3960. |
| [33] | Yang Daesoo;Bhattacharjya Dhrubajyoti;Yu Jongsung et al.Phosphorus-doped ordered mesoporous carbons with different lengths as efficient metal-free electrocatalysts for oxygen reduction reaction in alkaline media[J].Journal of the American Chemical Society,2012,134:16127. |
| [34] | Ju, J.;Bo, X.;Wang, H.;Zhang, Y.;Luhana, C.;Guo, L..Poly-o-toluidine cobalt supported on ordered mesoporous carbon as an efficient electrocatalyst for oxygen reduction[J].Electrochemistry communications,2012:35-38. |
| [35] | Liang Haiwei;Wei Wei;Müllen Klaus et al.Mesoporous metal-nitrogen-doped carbon electrocatalysts for highly efficient oxygen reduction reaction[J].Journal of the American Chemical Society,2013,135:16002. |
| [36] | Zhong Rensheng;Qin Yuanhang;Yuan Weikang et al.Effect of carbon nanofiber surface functional groups on oxygen reduction in alkaline solution[J].Journal of Power Sources,2013,225:192. |
| [37] | Shanmugam, S.;Osaka, T. .Efficient electrocatalytic oxygen reduction over metal free-nitrogen doped carbon nanocapsules[J].Chemical communications,2011(15):4463-4465. |
| [38] | Jin Hong;Zhang Huamin;Zhang Jianlu et al.Nitrogendoped carbon xerogel:A novel carbon-based electrocatalyst for oxygen reduction reaction in proton exchange membrane (PEM) fuel cells[J].Energy Environ Sci,2011,4:3389. |
| [39] | Liu Ziwu;Peng Feng;Wei Xianyong et al.Preparation of phosphorus-doped carbon nanospheres and their electrocatalytic performance for O2 reduction[J].Journal of Natural Gas Chemistry,2012,21:257. |
| [40] | Zheng Ning;Zhu Chunmei;Wang Yuan et al.Nanocomposite cathode catalyst with high methanol tolerance and durability[J].ACTA PHYSICO-CHIMICA SINICA,2012,28:2263. |
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