相变溶剂吸收CO2研究进展

材料导报, 2014, 28(21): 94-99. doi: 10.11896/j.issn.1005-023X.2014.21.018

相变溶剂吸收CO2研究进展

张政 ^1, , 刘彪 ^2, , 覃显业 ^3, , 农洁静 ^4, , 李艳红 ^5, , 赵文波 ^6,

1.昆明理工大学化学工程学院,昆明,650500

2.昆明理工大学化学工程学院,昆明,650500

3.昆明理工大学化学工程学院,昆明,650500

4.昆明理工大学化学工程学院,昆明,650500

5.昆明理工大学化学工程学院,昆明,650500

6.昆明理工大学化学工程学院,昆明,650500

基金项目: 国家青年自然科学基金(21306071) 清华大学化学工程联合国家重点实验室开放基金(SKL-CHE-12A03)

关键词：二氧化碳捕集 , 溶剂 , 吸收 , 相变

Progress in CO2 Capture Using Phase-changing Solvents

Keywords： CO2 capture , solvents , absorption , phase change

二氧化碳捕集是应对全球变暖的有效途径,溶剂吸收法是目前最为成熟的二氧化碳燃烧后捕集技术,但过高的二氧化碳解吸能耗是限制其进一步推广的瓶颈.相变溶剂吸收CO2由于有再生能耗低的优点,受到了越来越多研究者的关注.综述了有机胺溶剂吸收CO2的反应机理,并介绍了传统溶剂吸收CO2的装置和吸收CO2的各种方法.重点阐述了热致相变溶剂吸收CO2的热力学计算方法、临界溶解温度、热致相变原理和其溶剂选择标准,在此基础上,综述了热致相变溶剂的研究现状.最后概述了近年来国内外其他相变溶剂吸收CO2的研究进展.

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相变溶剂吸收CO2研究进展

Progress in CO2 Capture Using Phase-changing Solvents

参考文献