采用改进的溶胶-凝胶法制备Ca Zn1-xFe2O4粉体.用X射线粉末衍射仪(XRD)对样品进行结构表 征,随着Ca2+掺杂量的增加,样品出现CaFe2O4的衍射峰.使用扫描电子显微镜(SEM)对样品进行形貌表征,结果表明样品的形貌呈不规则的颗粒状,且颗粒大小为2 μm,并显现出片层堆叠情况.通过对甲基橙进行光催化降解实验,对CaxZn1-xFe2O4粉体的光催化活性进行了研究.结果表明,经过Ca2+掺杂的CaxZn1-xFe2O4样品,光催化活性明显提高.
参考文献
| [1] | Wang Defa;Zou Zhigang;Ye Jinhua .A new spinel type photocatalyts BaCr2O4 for H2 evolution under UV and visible light irradiation[J].CHEMICAL PHYSICS LETTERS,2003,373(01):191. |
| [2] | 陈仕祥,刘红,王翠,彭秀达,王小华.微乳液法制备纳米SiO_2/TiO_2及其光催化性能[J].化工进展,2012(05):1052-1056,1064. |
| [3] | Pingfan Du;Lixin Song;Jie Xiong;Houbao Cao .Photocatalytic degradation of Rhodamine B using electrospun TiO_2 and ZnO nanofibers: a comparative study[J].Journal of Materials Science,2013(24):8386-8392. |
| [4] | Fujishima A et al.Electrochemical photolysis of water at a semiconductor electrode[J].NATURE,1972,238(5358):37. |
| [5] | Nasr C;Vinodgopal K;Hotchandani S et al.Photocatalytic reduction of azo dyes naphthol blue black and disperse blue 79[J].Research on Chemical Intermediates,1997,23(03):219. |
| [6] | 李新勇;李树本;吕功煊 .纳米尺寸铁锌半导体光催化的表征及催化性能研究[J].分子催化,1996,10(03):187. |
| [7] | Wang J;Sun W;Zhang ZH;Jiang Z;Wang XF;Xu R;Li RH;Zhang XD .Preparation of Fe-doped mixed crystal TiO2 catalyst and investigation of its sonocatalytic activity during degradation of azo fuchsine under ultrasonic irradiation[J].Journal of Colloid and Interface Science,2008(1):202-209. |
| [8] | Enhanced photocatalytic discoloration of acid fuchsine wastewater by TiO_2/schorl composite catalyst[J].Journal of hazardous materials,2010(1/3):658. |
| [9] | Zhang Jianling;song Yuanqing;Yang Haigang et al.TiO2/T-PVA composites immobilized on cordierite:Structure and photocatalytic activity for degrading RhB under visible light[J].WATER AIR AND SOIL POLLUTION,2013,224:1555. |
| [10] | 焦万丽,张磊.交变磁场诱导自蔓延法制备Mn-Zn铁氧体及其磁性能[J].硅酸盐学报,2010(09):1852-1856. |
| [11] | 杨丽丽,翟博文,王哲,孙云飞,张志强,杨景海.ZnFe2O4纳米颗粒的制备及其磁学性能研究[J].吉林师范大学学报：自然科学版,2012(04):36-38. |
| [12] | Fatmahan Ozel;Hakan Kockar;Seda Beyaz;Oznur Karaagac;Taner Tanrisever .Superparamagnetic iron oxide nanoparticles: effect of iron oleate precursors obtained with a simple way[J].Journal of Materials Science. Materials in Electronics,2013(8):3073-3080. |
| [13] | Young-Min Chung;Yong-Tak Kwon;Tae Jin Kim .Factors Affect on the Reaction Performance of the Oxidative Dehydrogenation of n-Butene to 1,3-Butadiene Over Zn-Ferrite Catalysts[J].Catalysis Letters,2009(3/4):417-423. |
| [14] | 尖晶石型铁氧体Co1-xZnxFe2O4的制备及其光催化性能研究[J].材料导报,2012(z1):220-222. |
| [15] | Harish K N;Bhojya Naik H S;Prashanth kumar P N et al.Optical and photocatalytic properties of solar light active Nd-substituted Ni ferrite catalysts:For environmental protection[J].ACS Sustain Chem Eng,2013,1(09):1143. |
| [16] | 亓淑艳,丁嘉宝,司梦瑶,任美婷.Cr掺杂对尖晶石型CoFe2-xCrxO4的结构及光催化性能的影响[J].材料导报,2012(14):33-35. |
| [17] | 李平 .尖晶石型ZnFe2O4制备及光催化性能研究[D].哈尔滨理工大学,2013. |
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