以二甲基二烯丙基氯化铵(DMDAAC)、甲基丙烯酸(MAA)、烯丙基缩水甘油醚(AGE)、纳米ZnO为原料,通过原位法制备了聚二甲基二烯丙基氯化铵-甲基丙烯酸-烯丙基缩水甘油醚/纳米ZnO(PDMDAAC-AGE-MAA/纳米ZnO)复合材料,考察了纳米ZnO用量对复合材料性能的影响,通过FT-IR、XRD和TEM对其结构进行了表征,将其应用于棉织物整理中.结果表明:当纳米ZnO为0.8%时,PDMDAAC-AGE-MAA/纳米ZnO复合材料的稳定性最佳;复合材料中存在环氧基团以及纳米氧化锌的特征吸收峰,纳米ZnO在复合材料中具有良好的分散性;将其整理织物后,与原布相比,经10次标准洗涤织物对金黄色葡萄球菌和大肠杆菌的抗菌率高达80%以上,对白色念珠菌的抗菌性可达75%以上,具有良好的耐洗牢度;经过整理后的织物断裂强力无影响.
参考文献
[1] | Moustafa M.G. Fouda;E.S. Abdel-Halim;Salem S. Al-Deyab .Antibacterial modification of cotton using nanotechnology[J].Carbohydrate Polymers: Scientific and Technological Aspects of Industrially Important Polysaccharides,2013(2):943-954. |
[2] | Buffet-Bataillon, S.;Tattevin, P.;Bonnaure-Mallet, M.;Jolivet-Gougeon, A. .Emergence of resistance to antibacterial agents: The role of quaternary ammonium compounds - A critical review[J].International journal of antimicrobial agents,2012(5):381-389. |
[3] | 刘倩,李宏伟,王建明.等离子体引发DMDAAC接枝丙纶非织造布[J].纺织学报,2009(09):19-24. |
[4] | Satoshi lmazato;Ji-hua Chen;Sai Ma;Naomi lzutani;Fang Li .Antibacterial resin monomers based on quaternary ammonium and their benefits in restorative dentistry[J].The Japanese dental science review,2012(2):115-125. |
[5] | Marini M;Bondi M;Iseppi R;Toselli M;Pilati F .Preparation and antibacterial activity of hybrid materials containing quaternary ammonium salts via sol-gel process[J].European Polymer Journal,2007(8):3621-3628. |
[6] | 马慧敏,朱彩艳,王佳佳,王冰冰,张田林.新型N-(3-醛基-4-羟基苄基)型季铵盐的合成及其抗菌活性[J].合成化学,2014(02):230-233. |
[7] | 高党鸽,陈琛,马建中.纳米ZnO在纺织行业中的应用进展[J].印染,2012(24):43-49. |
[8] | P. Dhandapani;Arun S. Siddarth;S. Kamalasekaran.Bio-approach: Ureolytic bacteria mediated synthesis of ZnO nanocrystals on cotton fabric and evaluation of their antibacterial properties[J].Carbohydrate Polymers: Scientific and Technological Aspects of Industrially Important Polysaccharides,2014:448-455. |
[9] | I. Perelshtein;G. Applerot;N. Perkas .Antibacterial Properties of an In Situ Generated and Simultaneously Deposited Nanocrystalline ZnO on Fabrics[J].ACS applied materials & interfaces,2009(2):361-366. |
[10] | PERELSHTEIN I;RUDERMAN Y;PERKAS N et al.Enzymatic pre-treatment as a means of enhancing the antibacterial activity and stability of ZnO nanoparticles sonochemically coated on cotton fabrics[J].Journal of Materials Chemistry,2012,22(10):736-742. |
[11] | Dang-Ge Gao;Chen Chen;Jian-Zhong Ma .Preparation, characterization and application of ZnO sol containing quaternary ammonium salts[J].Journal of Sol-Gel Science and Technology,2013(3):336-343. |
[12] | Shao HB;Liang ZS;Shao MA .Osmotic regulation of 10 wheat (Triticum aestivum L.) genotypes at soil water deficits[J].Colloids and Surfaces, B. Biointerfaces,2006(2):132-139. |
[13] | Brunner TJ;Wick P;Manser P;Spohn P;Grass RN;Limbach LK;Bruinink A;Stark WJ .In vitro cytotoxicity of oxide nanoparticles: Comparison to asbestos, silica, and the effect of particle solubility[J].Environmental Science & Technology: ES&T,2006(14):4374-4381. |
[14] | JUN S W;SHOJI S B;IGARASHI H D et al.Hydrogen peroxide as an antibacterial factor in zinc oxide powder slurry[J].Journal of Fermentation and Bio-engineering,1998,86(5):521-522. |
[15] | Nasrin Talebian;Seyedeh Matin Amininezhad;Monir Doudi.Controllable synthesis of ZnO nanoparticles and their morphology-dependent antibacterial and optical properties[J].Journal of Photochemistry and Photobiology, B. Biology: Official Journal of the European Society for Photobiology,2013:66-73. |
[16] | Guy Applerot;Anat Lipovsky;Rachel Dror;Nina Perkas;Yeshayahu Nitzan;Rachel Lubart;Aharon Gedanken .Enhanced Antibacterial Activity Of Nanocrystalline Zno Due To Increased Ros-mediated Cell Injury[J].Advanced functional materials,2009(6):842-852. |
[17] | Peng Li;Yin Fun Poon;Weifeng Li .A polycationic antimicrobial and biocompatible hydrogel with microbe membrane suctioning ability[J].Nature materials,2011(2):149-156. |
[18] | Amanda C. Engler;Anita Shukla;Sravanthi Puranam .Effects of Side Group Functionality and Molecular Weight on the Activity of Synthetic Antimicrobial Polypeptides[J].Biomacromolecules,2011(5):1666-1674. |
[19] | Liu, Y.;He, L.;Mustapha, A.;Li, H.;Hu, Z. Q.;Lin, M. .Antibacterial activities of zinc oxide nanoparticles against Escherichia coli O157:H7.[J].Journal of applied microbiology,2009(4):1193-1201. |
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