采用普通溶液法合成了单核铈配合物[Ce(4-aba)3 (4-abaH) (phen)2]·H2O(4-abaH=对氨基苯甲酸,phen=1,10-邻菲罗啉).X射线单晶衍射结果表明:该配合物品体属单斜晶系,P21/c空间群,晶胞参数:a=1.8896(4) nm,b=1.9755(4) nm,c=1.3200(3) nm,β=97.235(2)°,V=4.8880(18) nm3,Mr=1064.06,Dc=1.446 g·cm-3,Z=4,μ=0.996 mm-1.中心铈离子的配位环境为变形的三帽三棱柱体.配合物存在着π-π堆积及丰富的氢键,将配合物扩展为三维超分子结构.
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