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HfO2 films were deposited by atomic layer deposition through alternating pulsing of Hf[N(C2H5)(CH3)]4 and H2O2.A trace amount of nitrogen was incorporated into the HfO2 through ammonia annealing.The composition,the interface stability of the HfO2/Si stack and the optical properties of the annealed films were analyzed to investigate the property evolution of HfO2 during thermal treatment.With a nitrogen concentration increase from 1.41 to 7.45%,the bandgap of the films decreased from 5.82 to 4.94 eV.

参考文献

[1] Wilk G D,Wallace R M,Anthony J M.High-k gate dielectrics:current status and materials properties considerations.J Appl Phys,2001,89:5243
[2] Perekins C M,Triplett B B,McIntyre P C,et al.Electrical and materials properties of ZrO2 gate dielectric grown by atomic layer chemical vapor deposition.Appl Phys Lett,2001,78:2357
[3] Robertson J.Band offsets of wide-band-gap oxides and implications for future electronic devices.J Vac Sci Technol B,2000,18:1785
[4] Wilk G D,Wallace R M,Anthony J M.Hafnium and zirconium silicates for advanced gate dielectric.J Appl Phys,2000,87:484
[5] Quevedo-Lopez M A,El-Bouanani M,Kim M J,et al.Boron penetration studies from p polycrystalline Si through HfSixOy.Appl Phys Lett,2002,81:1074
[6] Visokay M R,Chambers J J,Rotondaro A L P,et al.Application of HfSiON as a gate dielectric material.Appl Phys Lett,2002,80:3183
[7] Quevedo-Lopez M A,El-Bouanani M,Kim M J,et al.Effect of N incorporation on boron penetration from p+ polycrystalline-Si through HfSixOy films.Appl Phys Lett,2003,82:4669
[8] Arranz A.Synthesis of hafnium nitride films by 0.5-5 keV nitrogen implantation of metallic Hf:an X-ray photoelectron spectroscopy and factor analysis study.Surf Sci,2004,563:1
[9] Chung K B,Whang C N,Cho M H,et al.Suppression of phase separation in Hf-silicate films using NH3 annealing treatment.Appl Phys Lett,2006,88:081903
[10] Becker J S,Kim E,Gordon R G.Atomic layer deposition of insulating hafnium and zirconium nitrides.Chem Mater,2004,16:18
[11] Oshima M,Toyoda S,Okumura T,et al.Chemistry and band offsets of HfO2 thin films for gate insulators.Appl Phys Lett,2003,83:2172
[12] Martínez F L,Toledano-Luque M,Gandía J J,et al.Optical properties and structure of HfO2 thin films grown by pressure reactive sputtering.J Phys D:Appl Phys,2007,40:5256
[13] Miyamoto K,Furumai K,Urban B E,et al.Nitrogen-content dependence of crystalline structures and resistivity of Hf-Si-N gate electrodes for metal-oxide-semiconductor field-effect transistors.Jpn J Appl Phys,2009,48:045505
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