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通过水热处理凹凸棒石和纤维素获得凹凸棒石/炭纳米复合材料,研究该复合材料对亚甲基蓝的吸附性能。考察吸附条件对吸附行为的影响,以及吸附动力学和热力学研究。亚甲基蓝的吸附行为符合二级吸附速率方程,吸附等温方程符合Langmuir方程。吸附热力学参数的计算值表明,亚甲基蓝在该复合材料上的吸附是自发、吸热的过程。

A palygorskite/carbon composite was prepared through hydrothermal treatment of palygorskite and cellulose, and its adsorption behavior for methylene blue ( MB) was investigated. The effect of adsorption conditions on the capacity and kinetics was also investigated. The adsorption kinetics of MB onto the composite is best described by a pseudo_second_order equation. The ad_sorption isotherms conform to the Langmuir isothermal adsorption equation. The adsorption thermodynamic parameters calculated from the isotherms indicate that the adsorption of MB on the composite is endothermic.

参考文献

[1] Liu T H;Li Y H;Du Q J et al.Adsorption of methylene blue from aqueous solution by grapheme[J].Colloids and Surfaces B-Biointerfaces,2012,90:197_203.
[2] Hao Chen;Jie Zhao;Aiguo Zhong .Removal capacity and adsorption mechanism of heat-treated palygorskite clay for methylene blue[J].Chemical engineering journal,2011(1):143-150.
[3] Peng Shuchuan;Wang Shisheng;Chen Tianhu .Adsorption Kinetics of Methylene Blue from Aqueous Solutions onto Palygorskite[J].Acta geologica Sinica,2006(2):236-242.
[4] 林冠烽,蒋剑春,吴开金,孙康.醋酸乙烯载体竹活性炭的磷酸法制备与性能表征[J].新型炭材料,2013(06):461-466.
[5] 仲凯凯,黄张根,韩小金,张昌鸣.柠檬酸钠改性的活性炭对铜离子的吸附性能[J].新型炭材料,2013(02):156-160.
[6] Xiuli Han;Wei Wang;Xiaojian Ma .Adsorption characteristics of methylene blue onto low cost biomass material lotus leaf[J].Chemical engineering journal,2011(1):1-8.
[7] Hui Deng;Jianjiang Lu;Guoxue Li .Adsorption of methylene blue on adsorbent materials produced from cotton stalk[J].Chemical engineering journal,2011(1):326-334.
[8] Liuqing Yang;Yanfeng Li;Huaiyuan Hu .Preparation of novel spherical PVA/ATP composites with macroreticular structure and their adsorption behavior for methylene blue and lead in aqueous solution[J].Chemical engineering journal,2011(2):446-455.
[9] Chen H;Wang A Q .Adsorption characteristics of Cu(II)from aqueous solution onto poly(acrylamide)/attapulgite composite[J].Journal of Hazardous Materials,2008,165:223_231.
[10] Rui Dong;Yuanfa Liu;Xingguo Wang .Adsorption of Sulfate Ions from Aqueous Solution by Surfactant-Modified Palygorskite[J].Journal of Chemical and Engineering Data: the ACS Journal for Data,2011(10):3890-3896.
[11] Yue Chang;Hongwei Liu;Fei Zha .Adsorption of Pb(II) by N-methylimidazole modified palygorskite[J].Chemical engineering journal,2011(1):183-189.
[12] Xueping Wu;Wangyong Zhu;Xianlong Zhang;Tianhu Chen;Ray L Frost .Catalytic deposition of nanocarbon onto palygorskite and its adsorption of phenol[J].Applied clay science,2011(4):400-406.
[13] Falco C;Baccile N;Titirici M M .Morhpological and structural differences between glucose,cellulose and lignocellulosic bio_mass derived hydrothermal carbons[J].Green Chemistry,2011,13:3273_3281.
[14] Wu X P;Gao P;Zhang X L et al.Synthesis of clay/carbon adsorbent through hydrothermal carbonizationof cellulose on pa_lygorskite[J].Applied Clay Science,2014,95:60_66.
[15] Yi Liu;Wenbo Wang;Aiqin Wang.Effect of dry grinding on the microstructure of palygorskite and adsorption efficiency for methylene blue[J].Powder Technology: An International Journal on the Science and Technology of Wet and Dry Particulate Systems,2012:124-129.
[16] Bradley W F .The structural scheme of attapulgite[J].American Mineralogist,1940,25:405_410.
[17] McKAY G;Ho Y S .Pseudo_second order model for sorption processes[J].Process Biochemistry,1999,34:451_465.
[18] Langmuir I .The adsorption of gases on plane surfaces of glass,mica,and platinum[J].J Am Soc,1918,40:1361_1403.
[19] Seader J D;Herley E J.Separation Process Principles[M].New York:Wiley,1998
[20] Sorption of copper(II) onto super-adsorbent of bentonite-polyacrylamide composites[J].Journal of hazardous materials,2010(1/3):661.
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