喷雾热解法在硅衬底上生长定向碳纳米管阵列

新型炭材料, 2013, 28(4): 284-288. doi: 10.1016/S1872-5805(13)60082-7

喷雾热解法在硅衬底上生长定向碳纳米管阵列

^1, , ^2, , ^3, , ^4,

1.Department of Chemistry, Kathir college of Engineering, Coimbatore, TN, India

2.Department of Nanotechnology, Anna University of Technology, Coimbatore, TN, India

3.Department of Chemistry, Chikkanna Govt.Arts College, Tirupur, TN, India

4.Department of Chemistry, Chikkanna Govt.Arts College, Tirupur, TN, India

关键词：喷雾热解法 , 定向碳纳米官阵列 , 二茂铁 , 硅衬底 , 化学气相沉积

Growth of vertically aligned carbon nanotubes on a silicon substrate by a spray pyrolysis method

V S Angulakshmi ^1, , K Rajasekar ^2, , C Sathiskumar ^3, , S Karthikeyan ^4,

1.Department of Chemistry, Kathir college of Engineering, Coimbatore, TN, India

2.Department of Nanotechnology, Anna University of Technology, Coimbatore, TN, India

3.Department of Chemistry, Chikkanna Govt.Arts College, Tirupur, TN, India

4.Department of Chemistry, Chikkanna Govt.Arts College, Tirupur, TN, India

Keywords： Spray pyrolysis , Aligned carbon nanotubes , Ferrocence , Silicon substrate , CVD

以向日葵油的甲基酯为碳源,二茂铁为催化剂前驱体,Ar为载气,通过喷雾热解法在硅衬底上合成定向碳纳米管阵列.结果表明,在硅衬底上原位形成Fe催化剂纳米颗粒.由拉曼光谱、透射电镜图和X-射线衍射谱图显示所制定向碳纳米管阵列具有较好的石墨化程度,其直径为10～30 nm,管壁约为10nm.所制定向碳纳米管阵列中残留的催化剂含量可以忽略.

参考文献

[1]	W. Feng;X. D. Bai;Y. Q. Lian .Well-aligned polyaniline / carbon-nanotube composite films grown by in-situ aniline polymerization[J].Carbon: An International Journal Sponsored by the American Carbon Society,2003(8):1551-1557.
[2]	Thess A;Lee R;Nikolaev P et al.Crystalline ropes of metallic carbon nanotubes[J].Science,1996,273(5274):483-487.
[3]	Qiang Zhang;Meng-Qiang Zhao;Jia-Qi Huang .Vertically aligned carbon nanotube arrays grown on a lamellar catalyst by fluidized bed catalytic chemical vapor deposition[J].Carbon: An International Journal Sponsored by the American Carbon Society,2009(11):2600-2610.
[4]	Zhang Q;Zhou W;Qian W et al.Synchronous growth of vertically aligned carbon nanotubes with pristine stress in the heterogeneous catalysis process[J].Journal of Physical Chemistry,2007,111(40):14638-14643.
[5]	Afre RA;Soga T;Jimbo T;Kumar M;Ando Y;Sharon M .Growth of vertically aligned carbon nanotubes on silicon and quartz substrate by spray pyrolysis of a natural precursor: Turpentine oil[J].Chemical Physics Letters,2005(1/3):6-10.
[6]	Wang, C.;Ryu, K.;Badmaev, A.;Zhang, J.;Zhou, C. .Metal contact engineering and registration-free fabrication of complementary metal-oxide semiconductor integrated circuits using aligned carbon nanotubes[J].ACS nano,2011(2):1147-1153.
[7]	Pan Z;Zhu H;Zhang Z et al.Patterned growth of vertically aligned carbon nanotubes on pre-pattemed iron/silica substrates prepared by sol-gel and shadow masking[J].Journal of Physical Chemistry B,2003,107(06):1338-1344.
[8]	Jung Y J;Wei K;Vajtai R et al.Mechanism of selective growth of carbon nanotubes on SiO2/Si patterns[J].Nano Letters,2003,3(04):561-564.
[9]	Qian-ming Gong;Zhi Li;Dan Li;Xiao-dong Bai;Ji Liang .Fabrication and structure: a study of aligned carbon nanotube/carbon nanocomposites[J].Solid State Communications,2004(6):399-404.
[10]	Itaru Gunjishima;Takashi Inoue;Saeki Yamamuro .Synthesis of vertically aligned, double-walled carbon nanotubes from highly active Fe-V-O nanoparticles[J].Carbon: An International Journal Sponsored by the American Carbon Society,2007(6):1193-1199.
[11]	Kumar M.;Ando Y. .A simple method of producing aligned carbon nanotubes from an unconventional precursor - Camphor[J].Chemical Physics Letters,2003(5-6):521-526.
[12]	Afre RA;Soga T;Jimbo T;Kumar M;Ando Y;Sharon M .Growth of vertically aligned carbon nanotubes on silicon and quartz substrate by spray pyrolysis of a natural precursor: Turpentine oil[J].Chemical Physics Letters,2005(1/3):6-10.
[13]	Pradip Ghosh;Rakesh A. Afre;T. Soga .A simple method of producing single-walled carbon nanotubes from a natural precursor: Eucalyptus oil[J].Materials Letters,2007(17):3768-3770.
[14]	A.B. Suriani;A.A. Azira;S.F. Nik;Roslan Md Nor;M. Rusop .Synthesis of vertically aligned carbon nanotubes using natural palm oil as carbon precursor[J].Materials Letters,2009(30):2704.
[15]	Kumar R;Tiwari R S;Srivastava O N .Scalable synthesis of aligned carbon nanotubes bundles using green natural precursor:neem oil[J].Nanoscale Research Letters,2011,6:92-97.
[16]	S.Paul,S.K.Samdarshi.一种适于碳纳米管制备的绿色前驱体[J].新型炭材料,2011(02):85-88.
[17]	Karthikeyan S;Mahalingam P .Studies of yield and nature of multi-walled carbon nanotubes synthesized by spray pyrolysis of pine Oil at different temperatures[J].International Journal of Nanotechnology and Applications,2010,4(03):189-197.
[18]	Karthikeyan S;Mahalingam P .Synthesis and characterization of multi-walled carbon nanotubes from biodiesel oil:green nanoteehnology route[J].International Journal of Green Nanotechnology:Physics and Chemistry,2010,2(02):39-46.
[19]	Karthikeyan S;Mageswari S .Effect of Temperature and Flow Rate on the Yield of Multiwalled Carbon Nanotubes by Spray Pyrolysis using Cymbopogen flexsuous Oil[J].Journal of Environmental Nanotechnology,2012,1(01):28-31.
[20]	Z.Sadeghian.己烷低耗喷雾热解法大规模制备多壁碳纳米管[J].新型炭材料,2009(01):33-38.
[21]	Lesfeey M Cele;Neil J Couille .The negative effects of alcohols on carbon nanotube synthesis in a nebulised spray pyrolysis process[J].Carbon: An International Journal Sponsored by the American Carbon Society,2009(7):1824-1832.
[22]	Charanjeet Singh;Milo S.P. Shaffer;Alan H. Windle .Production of controlled architectures of aligned carbon nanotubes by an injection chemical vapour deposition method[J].Carbon: An International Journal Sponsored by the American Carbon Society,2003(2):359-368.

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