多壁碳纳米管采用H2SO4,KMnO4,HNO3氧化处理后用于铊吸附研究.碳纳米管经处理后表面官能团增加,采用Bohmn滴定法确定了样品的表面官能团的量.当用于吸附铊时,氧化处理显著提高了其吸附能力.采用Langmuir方程进行拟合处理后获得原始碳纳米管、H2SO4,KMnO4,HNO3氧化处理后样品的吸附量分别为3.0,11.7,21.6 and 31.55 mg/g.HNO3处理后具有对铊最佳的吸附性能.
参考文献
| [1] | Schoer J.Thallium[A].New York:springer-verlag,1984:143-214. |
| [2] | Speller SC. .Thallium based high temperature superconductors for microwave device applications [Review][J].Materials Science and Technology: MST: A publication of the Institute of Metals,2003(3):269-282. |
| [3] | Murata H;Horie N;Matsui T;Akai T;Ueda H;Oshima Y;Konishi E;Kubo T .Clinical usefulness of thallium-201 scintigraphy and magnetic resonance imaging in the diagnosis of chondromyxoid fibroma.[J].Annals of nuclear medicine,2008(3):221-224. |
| [4] | Fleischer M .Thallium[J].Analyses of Hazardous Substances in Biological Materials,1997,5:163-179. |
| [5] | Zhang Z;Zhang B G;Long J et al.Thallium pollution associated with mining of thallium deposits[J].Sci China Series D,1998,41(01):75-81. |
| [6] | Das AK;Chakraborty R;Cervera ML;De la Guardia M .Determination of thallium in biological samples[J].Analytical and bioanalytical chemistry,2006(4):665-670. |
| [7] | Chung N H;Nishimoto J;Kato O et al.Selective extraction of thallium(Ⅲ)in presence of gallium(Ⅲ),indium(Ⅲ),bismuth(Ⅲ)and antimony(Ⅲ)by salting-out of an aqueous mixture of 2-propanol[J].Analytica Chimica Acta,2003,477:243-249. |
| [8] | Rom W N.Environmetal and Occupational Medicine[A].Wolters Kluwe/Lippincott,1992:1095. |
| [9] | Kikuchi E;Itoh K;Fujishima A et al.Removal of thallium from wastewater by using the iron metal and hydrogen peroxide[J].Chemistry Letters,1990,19(02):253-254. |
| [10] | Peter A L J;Viraraghavan T .Thallium:a review of public health and environmental concerns[J].Environment International,2004,31(04):493-501. |
| [11] | Twidwell L G;Beam C W .Potential technologies for removing thallium from mine and process wastewater:an abbreviated annotation of literature[J].Eur J Miner Process Environ Protect,2002,2:1-10. |
| [12] | Yang C X;Chen Y H .FAAS Determination of thallium in environmental sample after its separation by adsorption on active carbon[J].Phys Test Chem Anal(Part B Chem Anal),2004,40:66-68. |
| [13] | Lei Zhang;Ting Huang;Min Zhang;Xingjia Guo;Zhu Yuan .Studies on the capability and behavior of adsorption of thallium on nano-Al_2O_3[J].Journal of hazardous materials,2008(2/3):352-357. |
| [14] | Fienol Z M;Ulusoy U .Thallium adsorption onto polyacryamide-aluminosilicate composites:A T1 isotope tracer study[J].Chemical Engineering Journal,2010,162:97-105. |
| [15] | Iijima S .Helical microtubules of graphitic carbon[J].Nature,1991,354:56-58. |
| [16] | Bazhenov, A.V.;Fursova, T.N.;Grazhulene, S.S.;Red'Kin, A.N.;Telegin, G.F. .Sorption of metal ions on multi-walled carbon nanotubes[J].Fullerenes, nanotubes, and carbon nanostructures,2010(1/6):564-568. |
| [17] | Xuemei Ren;Changlun Chen;Masaaki Nagatsu .Carbon nanotubes as adsorbents in environmental pollution management: A review[J].Chemical engineering journal,2011(2/3):395-410. |
| [18] | Yit Thai Ong;Abdul Latif Ahmad;Sharif Hussein Sharif Zein .A REVIEW ON CARBON NANOTUBES IN AN ENVIRONMENTAL PROTECTION AND GREEN ENGINEERING PERSPECTIVE[J].Brazilian journal of chemical engineering,2010(2):227-242. |
| [19] | Perez-Aguilar, NV;Munoz-Sandoval, E;Diaz-Flores, PE;Rangel-Mendez, JR .Adsorption of cadmium and lead onto oxidized nitrogen-doped multiwall carbon nanotubes in aqueous solution: equilibrium and kinetics[J].Journal of nanoparticle research: An interdisciplinary forum for nanoscale science and technology,2010(2):467-480. |
| [20] | Toebes M L;van Heeswijk E M P;Bitter J H et al.Theinfluence of oxidation on the texture and the number of oxygen-containing surface groups of carbon nanofibers[J].Carbon,2004,42:307-315. |
| [21] | Byl O;Liu J;Yates JT .Etching of carbon nanotubes by ozone - A surface area study[J].Langmuir: The ACS Journal of Surfaces and Colloids,2005(9):4200-4204. |
| [22] | Liu L V;Tian W Q;Wang Y A .Ozonization at the vacancy defect site of the single walled carbon nanotube[J].Journal of Physical Chemistry B,2006,110:13037-13044. |
| [23] | Man-Lung Sham;Jang-Kyo Kim .Surface functionalities of multi-wall carbon nanotubes after UV/Ozone and TETA treatments[J].Carbon: An International Journal Sponsored by the American Carbon Society,2006(4):768-777. |
| [24] | Changhm Chen;Bo Liang;Akihisa Ogino .Oxygen Functionalization of Multiwall Carbon Nanotubes by Microwave-Excited Surface-Wave Plasma Treatment[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2009(18):7659-7665. |
| [25] | H. Takagi;Y Soneda;H. Hatori .Effects of Nitric Acid and Heat Treatment on Hydrogen Adsorption of Single-Walled Carbon Nanotubes[J].Australian Journal of Chemistry,2007(7):519-523. |
| [26] | Wang HJ;Zhou AL;Peng F;Yu H;Chen LF .Adsorption characteristic of acidified carbon nanotubes for heavy metal Pb(II) in aqueous solution[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,2007(1-2):201-206. |
| [27] | Ravelo-Perez, LM;Herrera-Herrera, AV;Hernandez-Borges, J;Rodriguez-Delgado, MA .Carbon nanotubes: Solid-phase extraction[J].Journal of chromatography, A: Including electrophoresis and other separation methods,2010(16):2618-2641. |
| [28] | Isoshi Nukatsuka;Hiroyuki Seitoh;Kunio Ohzeki .Solid-Phase Extraction with Slurry Injection of the Resin Into ETAAS for Trace Determination of Thallium in Natural Water[J].Mikrochimica Acta: An International Journal for Physical and Chemical Methods of Analysis,2004(3/4):177-182. |
| [29] | Maryam Ahmadzadeh Tofighy;Toraj Mohammadi .Adsorption of divalent heavy metal ions from water using carbon nanotube sheets[J].Journal of hazardous materials,2011(1):140-147. |
| [30] | Chiang HL.;Huang CP.;Chiang PC. .The surface characteristics of activated carbon as affected by ozone and alkaline treatment[J].Chemosphere,2002(3):257-265. |
| [31] | John Kathi;Kyong-Yop Rhee;Joong Hee Lee .Effect of chemical functionalization of multi-walled carbon nanotubes with 3-aminopropyltriethoxysilane on mechanical and morphological properties of epoxy nanocomposites[J].Composites. Part A, Applied science and manufacturing,2009(6/7):800-809. |
| [32] | Won-Il Park;Hun-Sik Kim;Soon-Min Kwon .Synthesis of bacterial celluloses in multiwalled carbon nanotube-dispersed medium[J].Carbohydrate Polymers: Scientific and Technological Aspects of Industrially Important Polysaccharides,2009(3):457-463. |
| [33] | Kuznetsova A.;Naumenko V.;Yates JT.;Liu J.;Smalley RE.;Mawhinney DB. .Enhancement of adsorption inside of single-walled nanotubes: opening the entry ports[J].Chemical Physics Letters,2000(3-4):292-296. |
| [34] | David W M;Erickson C L;Johnston C T et al.Quantitative fourier transform infrared spectroscopic investigation of humic substance functional group composition[J].Chemosphere,1999,38:2913-2928. |
| [35] | G.Ovejero;J.L.Sotelo;M.D.Romero;A.Rodriguez;M.A.Ocana;G.Rodriguez;J.Garcia .Multiwalled Carbon Nanotubes for Liquid-Phase Oxidation.Functionalization,Characterization,and Catalytic Activity[J].Industrial & Engineering Chemistry Research,2006(7):2206-2212. |
| [36] | F. Auiles;J.V. Cauich-Rodriguez;L. Moo-Tah .Evaluation of mild acid oxidation treatments for MWCNT functionalization[J].Carbon: An International Journal Sponsored by the American Carbon Society,2009(13):2970-2975. |
| [37] | Su SH;Chiang WT;Lin CC;Yokoyama M .Multi-wall carbon nanotubes: Purification, morphology and field emission performance[J].Physica, E. Low-dimensional systems & nanostructures,2008(7):2322-2326. |
| [38] | V. Datsyuk;M. Kalyva;K. Papagelis .Chemical oxidation of multiwalled carbon nanotubes[J].Carbon: An International Journal Sponsored by the American Carbon Society,2008(6):833-840. |
| [39] | Munther Issa Kandah;Jean-Luc Meunier .Removal of nickel ions from water by multi-walled carbon nanotubes[J].Journal of hazardous materials,2007(1/2):283-288. |
| [40] | Kuo C Y .Water purification of removal aqueous copper(Ⅱ)by as-grown and modified multi-walled carbon nanotubes[J].Desalination,2009,249:781-785. |
| [41] | Cho H H;Wepasnick K;Smith B A et al.Sorption of aqueous Zn(Ⅱ)and Cd(Ⅱ)by multiwall carbon nanotubes:The relative roles of oxygen-containing functional groups and graphenic carbon[J].Langmuir,2010,26(02):967-981. |
| [42] | Yavari, R.;Huang, Y.D.;Mostofizadeh, A. .Sorption of strontium ions from aqueous solutions by oxidized multiwall carbon nanotubes[J].Journal of Radioanalytical and Nuclear Chemistry: An International Journal Dealing with All Aspects and Applications of Nuclear Chemistry,2010(3):703-710. |
| [43] | Xiaojiao Deng;Lili Lue;Hongwei Li;Fang Luo .The adsorption properties of Pb(Ⅱ) and Cd(Ⅱ) on functionalized graphene prepared by electrolysis method[J].Journal of hazardous materials,2010(1/3):923-930. |
| [44] | Upadhyayula, VKK;Deng, SG;Mitchell, MC;Smith, GB .Application of carbon nanotube technology for removal of contaminants in drinking water: A review[J].Science of the Total Environment,2009(1):1-13. |
| [45] | Sheng G;Li J;Shao D et al.Adsorption of copper(Ⅱ)on multiwalled carbon nanotubes in the absence and presence of humic or fulvic acids[J].Journal of Hazardous Materials,2010,178:333-340. |
| [46] | Moradi, O.;Zare, K.;Monajjemi, M.;Yari, M.;Aghaie, H. .The studies of equilibrium and thermodynamic adsorption of Pb(II), Cd(II) and Cu(II) ions from aqueous solution onto SWCNTs and SWCNT-COOH surfaces[J].Fullerenes, nanotubes, and carbon nanostructures,2010(1/6):285-302. |
| [47] | Chen C;Li X;Zhao D et al.Adsorption kinetic,thermodynamic and desorption studies of Th(Ⅳ)on oxidized multi-wall carbon nanotubes[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,2007,302:449-454. |
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