以阴极电弧法,分别于硅基材与铜纳米线(CuNWs)/硅基材(其中铜纳米线系阳极氧化铝(AAO)模板技术成长于硅基材上)沉积非晶碳膜,,分别以扫描电子显微镜(SEM)、原子力电子显微镜(AFM)和X光电子光谱仪(XPS)表征了非晶碳膜/铜纳米线/硅基材与非品碳膜/硅基材两者之表面形貌、粗糙度、结构及键结等物理特性.并比较两者之电子场发射特性.研究结果显示:两者都拥有低起始电场及高电流密度,其中非品碳膜/铜纳米线/硅基材的场发射起始电压为3.75 V/μm优于非品碳膜/硅基材的15 V/μm,因此非晶碳膜/铜纳米线/硅基材更适用于场发射平面显示器(FED)之发射子,可应用于高稳定性及低成本之场发射平面显示器之研发.
The field emission properties of amorphous carbon/copper nanowire (CuNW)/Si composites have been in-vestigated. The CuNWs (50-80nm in diameters) were deposited anodically within the pores of a porous anodic alumi-num oxide (AAO) nano-template by electrolysis of a CuSO4-H2 SO4 solution at room temperature using DC current. Two kinds of structure, amorphous carbon/Si and amorphous carbon/CuNWs/Si , were used. Both of them can emit electrons in vacuum towards an anode at a very low tum-on field. Field emission from the amorphous carbon/CuNWs/Si shows a fourfold decrease in turn-on field compared with the amorphous carbon/Si. Results indicated that the electrons were emitted under the effect of an enhanced field because of the geometry of the amorphous carbon sample.
参考文献
[1] | Z. S. Wu;S. Z. Deng;N. S. Xu;Jian Chen;J. Zhou;Jun Chen .Needle-shaped silicon carbide nanowires: Synthesis and field electron emission properties[J].Applied physics letters,2002(20):3829-3831. |
[2] | Juntao Li;Wei Lei;Xiaobing Zhang;Xuedong Zhou;Qilong Wang;Yuning Zhang;Baoping Wang .Field emission characteristic of screen-printed carbon nanotube cathode[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2003(1/4):96-104. |
[3] | Yubao Li;Yoshio Bando;Dmitri Golberg .Quasi-Aligned Single-Crystalline W_(18)O_(49) Nanotubes and Nanowires[J].Advanced Materials,2003(15):1294-1296. |
[4] | Jun Zhou;Ning-Sheng Xu;Shao-Zhi Deng;Jun Chen;Jun-Cong She;Zhong-Lin Wang .Large-Area Nanowire Arrays of Molybdenum and Molybdenum Oxides: Synthesis and Field Emission Properties[J].Advanced Materials,2003(21):1835-1840. |
[5] | Y. B. Li;Y. Bando;D. Golberg .ZnO nanoneedles with tip surface perturbations: Excellent field emitters[J].Applied physics letters,2004(18):3603-3605. |
[6] | Xu N S;Tzeng Y;Lantham R V .Similarities in the 'cold' electron emission characteristics of diamond coated molybdenum electrodes and polished bulk graphite surfaces[J].Journal of Physics D:Applied Physics,1993,26:1776-1780. |
[7] | Kuttel Olivier M.;Groning O.;Emmenegger Ch.;Nilsson L.;Maillard E.;Diederich L. .Field emission from diamond, diamond-like and nanostructured carbon films[J].Carbon: An International Journal Sponsored by the American Carbon Society,1999(5):745-752. |
[8] | Namwoong Paik .Field emission characteristics of Diamond-like Carbon (DLC) films prepared using a Magnetron Sputter-type Negative Ion Source (MSNIS)[J].Diamond and Related Materials,2005(9):1556-1561. |
[9] | Inoue T;Frank O D;Miquel S .Field emission study of dia-mond-like carbon films with scanned-probe field-emission force microscopy[J].Applied Physics Letters,2000,76:2961. |
[10] | S. Kundoo;P. Saha;K.K. Chattopadhyay .Electron field emission from nitrogen and sulfur-doped diamond-like carbon films deposited by simple electrochemical route[J].Materials Letters,2004(30):3920-3924. |
[11] | Pate B B .The diamond surface:atomic and electronic structure[J].Surface Science,1986,165:83-142. |
[12] | Narayan RJ .Laser processing of diamond-like carbon-metal composites[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2005(1/4):420-430. |
[13] | H. Chen;M.N. Iliev;J.R. Liu;K.B. Ma;W.-K. Chu;N. Badi;A. Bensaoula;E.B. Svedberg .Room-temperature deposition of diamond-like carbon field emitter on flexible substrates[J].Nuclear Instruments and Methods in Physics Research, Section B. Beam Interactions with Materials and Atoms,2006(1):75-78. |
[14] | Masuda H;Fukuda K .ORDERED METAL NANOHOLE ARRAYS MADE BY A TWO-STEP REPLICATION OF HONEYCOMB STRUCTURES OF ANODIC ALUMINA[J].Science,1995(5216):1466-1468. |
[15] | Lin R J;Wu L H;Tsai C H et al.Effect of Template Materials on the Top Morphologies of Cu Nanowires[J].Materials Research Society Symposium Proceedings,2004,818:M5.30. |
[16] | Dobrev D;Vetter J;Angert N .Electrochemical preparation of metal microstructures on large areas of etched ion track membranes[J].Nuclear Instruments and Methods in Physics Research B:Beam Interaction with Materials and Atoms,1999,149:207-212. |
[17] | Paik N .Raman and XPS studies of DLC films prepared by a magnetron sputter-type negative ion source[J].Surface & Coatings Technology,2005(7):2170-2174. |
[18] | Wisitsora-at A.;Davidson J.L.;Li Q.;Xu J.F.;Kerns D.V.;Kang W.P. .Efficient electron emitter utilizing boron-doped diamond tips with sp2 content[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,1999(1):280-286. |
[19] | Jun Chen;S. Z. Deng;N. S. Xu;Suhua Wang;Xiaogang Wen;Shihe Yang;Chunlei Yang;Jiannong Wang;Weikun Ge .Field emission from crystalline copper sulphide nanowire arrays[J].Applied physics letters,2002(19):3620-3622. |
[20] | Fowler R H;Nordheim L W .Electron emission in intense electric fields[J].Proceedings of the Royal Society of London Series A,1928,119(781):173-181. |
[21] | A. Wisitsora-at;W. P. Kang;J. L. Davidson;Y. Gurbuz;D. V. Kerns .Field emission enhancement of diamond tips utilizing boron doping and surface treatment[J].Diamond and Related Materials,1999(7):1220-1224. |
[22] | Ming-Chi Kan;Jow-Lay Huang;James Sung .Field Emission Characteristics of Amorphous Diamond[J].Journal of the American Ceramic Society,2003(9):1513-1517. |
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