欢迎登录材料期刊网

材料期刊网

中国科学院金属研究所 科学出版社
高级检索
  1. 首页
  2. 期刊
  3. 催化学报
  4. Cr-free Co-Cu/SBA-15 catalysts for hydrogenation of biomass-derivedα-,β-unsaturated aldehyde to alcohol

催化学报 , 2015, (7): 933-942. doi: 10.1016/S1872-2067(15)60870-1

Sanjay Srivastava 1, , Pravakar Mohanty 2, , Jigisha K. Parikh 3, , Ajay K. Dalai 4, , S. S. Amritphale 5, , Anup K. Khare 6,

1.a Department of Chemical Engineering, S. V. National Institute of Technology, Ichchhanath, SURAT-395 007, Gujarat, India

2.Department of Chemical Engineering, Indian Institute of Technology, New Delhi-110016, India

3.a Department of Chemical Engineering, S. V. National Institute of Technology, Ichchhanath, SURAT-395 007, Gujarat, India

4.Catalysis and Chemical Reaction Engineering Laboratories, Department of Chemical and Biological Engineering, University of Saskatchewan, Saskatoon, Saskatchewan S7N 5A9, Canada

5.Advanced Material and Processes Research Institute AMPRI, Council of Scientific & Industrial Research CSIR, Bhopal 462064, India

6.Advanced Material and Processes Research Institute AMPRI, Council of Scientific & Industrial Research CSIR, Bhopal 462064, India

Cr-free Co-Cu/SBA-15 catalysts for hydrogenation of biomass-derivedα-,β-unsaturated aldehyde to alcohol

Keywords： Mesoporous catalyst

Cr-free bi-metallic SBA-15-supported Co–Cu catalysts were examined in the conversion of bio-mass-derived α-, β-unsaturated aldehyde (furfural) to value-added chemical furfuryl alcohol (FOL). Co–Cu/SBA-15 catalysts with a fixed Cu loading of 10 wt% and varying Co loadings (2.5, 5, and 10 wt%) were prepared by the impregnation method. The catalysts were characterized by X-ray dif-fraction, N2 sorption, H2 temperature-programmed reduction, scanning electron microscopy, ener-gy-dispersive X-ray spectroscopy, high-resolution transmission electron microscopy, CO chemi-sorption, and inductively coupled plasma mass spectrometry. The influence of different reaction parameters such as temperature, pressure, catalyst dosage, and furfural concentration on the cata-lyst performance was evaluated. Relative to catalysts supported on amorphous silica, the current SBA-15-supported Co–Cu catalysts displayed higher performance, attaining a furfural conversion of 99% and furfuryl alcohol selectivity of 80%. The catalytic reactions were conducted in a 100-mL autoclave at 170 °C and 2 MPa H2 pressure for 4 h.

参考文献

[1] Corma A;Iborra S;Velty A .[J].CHEMICAL REVIEWS,2007,107:2411.
[2] Nanda S;Mohanty P;Pant K K;Naik S Kozinski J A Dalai A K .[J].Bio-energy Res,2013,6:663.
[3] Butler E;Devlin G;Meier D;McDonnell K .[J].RENEWABLE & SUSTAINABLE ENERGY REVIEWS,2011,15:4171.
[4] Chiaramonti D;Oasmaa A;Solantausta Y .[J].RENEWABLE & SUSTAINABLE ENERGY REVIEWS,2007,11:1056.
[5] Yan K;Wu G S;Lafleur T;Jarvis C .[J].RENEWABLE & SUSTAINABLE ENERGY REVIEWS,2014,38:663.
[6] Yang W;Sen A .[J].ChemSusChem,2011,4:349.
[7] Sharma R V;Das U;Sammynaiken R;Dalai A K .[J].Applied Catalysis A:General,2013,454:127.
[8] Borts M S;Gilchenok N D;Ignatev V M;Gurevich G S .[J].J Appl Chem USSR,1986,59:114.
[9] Rao R.;Baker RTK.;Vannice MA.;Dandekar A. .PROPERTIES OF COPPER CHROMITE CATALYSTS IN HYDROGENATION REACTIONS[J].Journal of Catalysis,1997(2):406-419.
[10] Vaidya P D;Mahajani V V .[J].Industrial and Engineering Chemistry Research,2003,42:3881.
[11] Rojas H;Martines J J;Reyes P .[J].Dyna,2010,163:151.
[12] Sitthisa, S.;Sooknoi, T.;Ma, Y.;Balbuena, P.B.;Resasco, D.E. .Kinetics and mechanism of hydrogenation of furfural on Cu/SiO_2 catalysts[J].Journal of Catalysis,2011(1):1-13.
[13] Villaverde M M;Bertero N M;Garetto T F;Marchi A J .[J].Catalysis Today,2013,213:87.
[14] Yan K;Chen A C .[J].ENERGY,2013,58:357.
[15] Seo G;Chon H .[J].Journal of Catalysis,1981,67:424.
[16] Lee J Y;Lee D W;Lee K Y;Wang Y .[J].Catalysis Today,2009,146:260.
[17] Yan K;Chen A C .[J].FUEL,2014,115:101.
[18] Burnette L W;Johns I B;Holdren R F;Hixon R M .[J].Industrial and Engineering Chemistry,1948,40:502.
[19] Dong F;Zhu Y L;Zheng H Y;Zhu Y F Li X Q Li Y W .[J].Journal of Molecular Catalysis A:Chemical,2015,398:140.
[20] Liu B J;Lu L H;Wang B C;Cai T X Katsuyoshi I .[J].Applied Catalysis A:General,1998,171:117.
[21] Thomas D D .[P].US Patent 4146460,1979.
[22] Erzhanova M S;Beisekov T B .[P].SU Patent 450585,1974.
[23] Beisekov T B;Masaeva S A;Kuatbekov A M;Pilipenko S V,Utebae-va A.[J].Khim Promst,1992:507.
[24] Pljusnin L D;Beisekov T;Jerzhanova M S;Daurenbekov B D.[J].Khim Promst,1988:672.
[25] Sitthisa, S.;Pham, T.;Prasomsri, T.;Sooknoi, T.;Mallinson, R.G.;Resasco, D.E. .Conversion of furfural and 2-methylpentanal on Pd/SiO2 and Pd-Cu/SiO2 catalysts[J].Journal of Catalysis,2011(1):17-27.
[26] Sitthisa, S.;An, W.;Resasco, D.E. .Selective conversion of furfural to methylfuran over silica-supported NiFe bimetallic catalysts[J].Journal of Catalysis,2011(1):90-101.
[27] Merlo A B;Vetere V;Ruggera J F;Casella M L .[J].CATALYSIS COMMUNICATIONS,2009,10:1665.
[28] Reddy BM;Reddy GK;Rao KN;Khan A;Ganesh I .Silica supported transition metal-based bimetallic catalysts for vapour phase selective hydrogenation of furfuraldehyde[J].Journal of molecular catalysis, A. Chemical,2007(1/2):276-282.
[29] Wu J;Shen Y M;Liu C H;Wang H B Geng C J Zhang Z X .[J].Catal Commum,2005,6:633.
[30] Li H;Chai W M;Luo H S;Li H X .[J].Chinese Journal of Chemistry,2006,24:1704.
[31] Chen X F;Li H X;Luo H S;Qiao M H .[J].Applied Catalysis A:General,2002,233:13.
[32] Wei S Q;Cui H Y;Wang J H;Zhuo S P Yi W M Wang L H Li Z H .[J].Particuology,2011,9:69.
[33] Zhao D Y;Feng J L;Huo Q S;Melosh N Fredrickson G H Chmelka B F Stucky G D .[J].SCIENCE,1998,279:548.
[34] Vargas-Hernandez D;Rubio-Caballero J M;Santamar?a-Gonzalez J;Moreno-Tost R Merida-Robles J M Perez-Cruz M A Jimenez-Lopez A Hernandez-Huesca A Maireles-Torres .[J].Journal of Molecular Catalysis A:Chemical,2014,383-384:106.
[35] Yan K;Lafleur T;Jarvis C;Wu G S .[J].JOURNAL OF CLEANER PRODUCTION,2014,72:230.
[36] Ramachandran P A;Chaudhari R V.Three-Phase Catalytic Reac-tors[M].New York:Gordon and Breach,1983:427.
[37] Klimova T;Reyes J;Gutierrez O;Lizama L .[J].Applied Catalysis A:General,2008,335:159.
[38] Soni K;Mouli K C;Dalai A K;Adjaye J .[J].Catalysis Letters,2010,136:116.
[39] Dhar G M;Kumaran G M;Kumar M;Rawat K S Sharma L D Raju B D Rama Rao K S .[J].Catalysis Today,2005,99:309.
[40] Carrero A;Calles JA;Vizcaino AJ .Hydrogen production by ethanol steam reforming over Cu-Ni/SBA-15 supported catalysts prepared by direct synthesis and impregnation[J].Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications,2007(1):82-94.
[41] Zhu Y Y;Wang S R;Zhu L J;Ge X L Li X B Luo Z Y .[J].Catalysis Letters,2010,135:275.
[42] Marchi A J;Di Cosimo J I;Apesteguia C R .[J].Catalysis Today,1992,15:383.
[43] Cesar D V;Perez C A;Salim V M M;Schmal M .[J].Applied Catalysis A:General,1999,176:205.
[44] Iglesia E.;Baumgartner JE.;Reyes SC.;Soled SL. .SYNTHESIS AND CATALYTIC PROPERTIES OF EGGSHELL COBALT CATALYSTS FOR THE FISCHER-TROPSCH SYNTHESIS[J].Journal of Catalysis,1995(1):108-122.
[45] Tien-Thao N;Zahedi-Niaki M H;Alamdari H;Kaliaguine S .[J].Journal of Catalysis,2007,245:348.
[46] Xu X D;Mausbeck D;Scholten J J F .[J].Catalysis Today,1991,10:429.
[47] Baker J E;Burch R;Hibble S J;Loader P K .[J].Applied Catalysis,1990,65:281.
[48] Mohanty P;Pant K K;Parikh J;Sharma D K .[J].FUEL PROCESSING TECHNOLOGY,2011,92:600.
[49] An K;Somorjai G A .[J].Catalysis Letters,2015,145:233.
[50] Nagaraja B M;Siva Kumar V;Shasikala V;Padmasri A H Sreedhar B Raju B D Rama Rao K S .[J].CATALYSIS COMMUNICATIONS,2003,4:287.
[51] Liu D X;Zemlyanov D;Wu T P;Lobo-Lapidus R J Dumesic J A Miller J T Marshall C L .[J].Journal of Catalysis,2013,299:336.
[52] Vetere V;Merlo A B;Ruggera J F;Casella M L .[J].Journal of the Brazilian Chemical Society,2010,21:914.
[53] Sitthisa S;Resasco D E .[J].Catalysis Letters,2011,141:784.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
作者相关
文章评分
  • 您的评分：
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%

版权所有©2010中国科学院金属研究所中国科技出版传媒股份有限公司

本系统由北京仁和汇智信息技术有限公司设计开发

技术支持：info@rhhz.net