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  4. Oxidative carbonylation of phenol with a Pd-O/CeO2-nanotube catalyst

催化学报 , 2015, (7): 1142-1149. doi: 10.1016/S1872-2067(14)60312-0

Ye Yuan 1, , Zhimiao Wang 2, , Hualiang An 3, , Wei Xue 4, , Yanji Wang 5,

1.Hebei Provincial Key Laboratory of Green Chemistry & High Efficient Energy Saving, School of Chemical Engineering and Technology, Hebei University of Technology, Tianjin 300130, China

2.Hebei Provincial Key Laboratory of Green Chemistry & High Efficient Energy Saving, School of Chemical Engineering and Technology, Hebei University of Technology, Tianjin 300130, China

3.Hebei Provincial Key Laboratory of Green Chemistry & High Efficient Energy Saving, School of Chemical Engineering and Technology, Hebei University of Technology, Tianjin 300130, China

4.Hebei Provincial Key Laboratory of Green Chemistry & High Efficient Energy Saving, School of Chemical Engineering and Technology, Hebei University of Technology, Tianjin 300130, China

5.Hebei Provincial Key Laboratory of Green Chemistry & High Efficient Energy Saving, School of Chemical Engineering and Technology, Hebei University of Technology, Tianjin 300130, China

基金项目:   the National Natural Science Foundation of China(21236001,21176056,21106031)   the Programme for 100 Excellent Talents in University of Hebei Province (II)(BR2-208)   the Natural Science Foundation of Hebei Province(B2015202228)  

Oxidative carbonylation of phenol with a Pd-O/CeO2-nanotube catalyst

Keywords： Diphenyl carbonate

CeO2 nanotubes (CeO2-NT) were synthesized using carbon nanotubes as template by a liquid phase deposition and hydrothermal method. X-ray diffraction, transmission electron microscopy, and N2 adsorption-desorption were used to characterize the CeO2-NT. The wall of CeO2-NT was composed of small interconnected nanocrystallites ranging from 4 to 9 nm in size. The specific surface area of CeO2-NT was 108.8 m2/g with an outer diameter of 25 nm and length > 300 nm. Supported Pd cata-lyst, Pd-O/CeO2-NT, was prepared using CeO2-NT as the support. Temperature-programmed reduc-tion analysis showed that the surface oxygen on Pd-O/CeO2-NT could be reduced at low tempera-ture, therefore it showed high activity in the reaction. Pd-O/CeO2-NT was used as the catalyst for the oxidative carbonylation of phenol. It has better activity and DPC selectivity than Pd-O/CeO2-P, which was prepared by supporting Pd on zero dimensional CeO2particles. Under the optimized conditions, phenol conversion was 67.7% with 93.3% DPC selectivity with Pd-O/CeO2-NT. However, its catalyt-ic activity decreased when the catalyst was used for the second time. This was attributed to the destruction of the tubular structure of Pd-O/CeO2-NT and Pd leaching during the reaction.

参考文献

[1] 王延吉;赵新强.绿色催化过程与工艺[M].北京:化学工业出版社,2002:160.
[2] Gong JL;Ma XB;Wang SP .Phosgene-free approaches to catalytic synthesis of diphenyl carbonate and its intermediates[J].Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications,2007(1):1-21.
[3] Xue W;Teng Z;Wang Z M;Yuan Y Zhang D S Wang Y J(薛伟 滕哲 王志苗 袁烨 张东升 王延吉) .[P].CN Patent 103611532 A,2013.
[4] Zhou W Q;Zhao X Q;Wang Y J;Zhang J Y .[J].Applied Catalysis A:General,2004,260:19.
[5] 周喜,葛鑫,唐荣芝,陈彤,王公应.表面修饰多壁碳纳米管负载二氧化钛的制备及催化碳酸二甲酯与苯酚酯交换反应的性能[J].催化学报,2014(04):481-495.
[6] Hallgren J E;Lucas G M;Matthews R O .[J].Journal of Organometallic Chemistry,1981,204:135.
[7] Vavasori A;Toniolo L .[J].Journal of Molecular Catalysis A:Chemical,1999,139:109.
[8] Goyal M.;Sugiyama J.;Asai M.;Ueda M.;Takeuchi K.;Nagahata R. .Effect of inorganic redox cocatalyst on Pd-catalyzed oxidative carbonylation of phenol for direct synthesis of diphenyl carbonate[J].Catalysis Letters,1998(1/2):29-31.
[9] Linsen K J L;Libens J;Jacobs P A.[J].Chemistry Communications,2002:2728.
[10] Xue W;Zhang JC;Wang YJ;Zhao Q;Zhao XQ .Effect of promoter copper on the oxidative carbonylation of phenol over the ultrafine embedded catalyst Pd-Cu-O/SiO2[J].Journal of molecular catalysis, A. Chemical,2005(1/2):77-81.
[11] Song HY.;Lee JS.;Park ED. .Oxidative carbonylation of phenol to diphenyl carbonate over supported palladium catalysts[J].Journal of molecular catalysis, A. Chemical,2000(1/2):243-250.
[12] Ishii H;Takeuchi K;Asai M;Ueda M .[J].CATALYSIS COMMUNICATIONS,2001,2:145.
[13] 张光旭,吴元欣,马沛生,吴广文,李定或.非均相催化一步合成碳酸二苯酯的研究Ⅰ. 载体制备方法对催化剂性能的影响[J].催化学报,2002(02):130-132.
[14] Kim WB.;Park ED.;Lee CW.;Lee JS. .Nature and role of active states of Pd and Cu in the oxidative carbonylation of phenols with Pd/C and cuprous oxide[J].Journal of Catalysis,2003(2):334-347.
[15] Fan GZ;Huang J;Li ZQ;Li T;Li GX .Palladium complexes anchored on silica functionalized by 1,2-diaminocyclohexane: Preparation and catalytic application[J].Journal of molecular catalysis, A. Chemical,2007(1/2):34-40.
[16] Lu W;Du Z P;Yuan H;Tian Q F Wu Y X .[J].Chinese Journal of Chemical Engineering,2013,21:8.
[17] Yang X J;Han J Y;Du Z P;Yuan H Jin F Wu Y X .[J].CATALYSIS COMMUNICATIONS,2010,11:643.
[18] Ronchin L;Vavasori A;Amadio E;Cavinato G Toniolo L .[J].Journal of Molecular Catalysis A:Chemical,2009,298:23.
[19] Xue W;Zhang J C;Wang Y J;Zhao X Q Zhao Q .[J].CATALYSIS COMMUNICATIONS,2005,6:431.
[20] Zhang Y L;Xiang S L;Wang G Q;Jiang H Xiong C R .[J].Catal Sci Tech-nol,2014,4:1055.
[21] 邬茂,袁华,杜治平,吴元欣.CeO2基氧化物在氧化羰基化合成碳酸二苯酯中的应用[J].应用化工,2008(09):990-992.
[22] 王志苗 .[D].天津:河北工业大学,2012.
[23] 塔娜,刘景月,申文杰.基于催化应用调控氧化铈纳米材料的形貌[J].催化学报,2013(05):838-850.
[24] 李勇,申文杰.金属氧化物纳米催化的形貌效应[J].中国科学（化学）,2012(04):376-389.
[25] Liu L J;Cao Y;Sun W J;Yao Z J Liu B Gao F Dong L .[J].Catalysis Today,2011,175:48.
[26] Wu Z L;Li M J;Overbury S H .[J].Journal of Catalysis,2012,285:61.
[27] Wang S P;Zhao L F;Wang W;Zhao Y J Zhang G L Ma X B Gong J L .[J].Nanoscale,2013,5:5582.
[28] Pan CS;Zhang DS;Shi LY;Fang JH .Template-free synthesis, controlled conversion, and CO oxidation properties of CeO2 nanorods, nanotubes, nanowires, and nanocubes[J].European journal of inorganic chemistry,2008(15):2429-2436.
[29] 单文娟,刘畅,郭红娟,杨利华,王晓楠,冯兆池.0,1,3维CeO2的可控制备及CuO/CeO2催化剂上CO氧化反应[J].催化学报,2011(08):1336-1341.
[30] Zhou K B;Yang Z Q;Yang S .[J].CHEMISTRY OF MATERIALS,2007,19:1215.
[31] Zhang D S;Fu H X;Shi L Y;Fang J H Li Q .[J].Journal of Solid State Chemistry,2007,180:654.
[32] Cargnello M;Doan-Nguyen V V T;Gordon T R;Diaz R E Stach E A Gorte R J Fornasiero P Nurray C B .[J].SCIENCE,2013,341:771.
[33] Boronin A I;Slavinskaya E M;Danilova I G;Gulyaev R V Amosov Y I Kuznetsov P A Polukhina I A Koscheev S V Zaikovskii V I Nos-kov A S .[J].Catalysis Today,2009,144:201.
[34] 唐紫蓉,尹霞,张燕辉,张楠,徐艺军.一维CeO2纳米管载体对Pd纳米粒子团聚的抑制及催化性能的提高[J].催化学报,2013(06):1123-1127.
[35] Sing K S W;Everett D H;Haul R A W;Moscou L Pierotti R A Rouquérol J Siemieniewska T .[J].Pure and Applied Chemistry,1985,57:603.
[36] Yao H C;Yu Yao Y F .[J].Journal of Catalysis,1984,86:254.
[37] 李娟,塔娜,李勇,申文杰.纳米尺度CeO2在多相催化反应中的形貌效应[J].催化学报,2008(09):823-830.
[38] Shan W J;Dong X W;Ma N;Yao S Y Feng Z C .[J].Catalysis Letters,2009,131:350.
[39] Rao G R .[J].Bulletin of Materials Sciences In press,1999,22:89.
[40] Zhu H Q;Qin Z F;Shan W J;Shen W J Wang J G .[J].Journal of Catalysis,2004,225:267.
[41] Luo MF.;Yuan XX.;Zheng XM.;Hou ZY. .Characterization study of CeO2 supported Pd catalyst for low-temperature carbon monoxide oxidation[J].Catalysis Letters,1998(3/4):205-209.
[42] Amorim C;Wang X D;Keane M A .[J].催化学报,2011,32:746.
[43] Cargnello, M;Montini, T;Polizzi, S;Wieder, NL;Gorte, RJ;Graziani, M;Fornasiero, P .Novel embedded Pd@CeO2 catalysts: a way to active and stable catalysts[J].Dalton transactions: An international journal of inorganic chemistry,2010(8):2122-2127.
[44] Meng L;Jia A P;Lu J Q;Luo L F Huang W X Luo M F .[J].J Phys Chem C,2011,115:19789.
[45] Reddy B M;Katta L;Thrimurthulu G .[J].CHEMISTRY OF MATERIALS,2010,22:467.
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