催化学报 , 2015, (2): 175-180. doi: 10.1016/S1872-2067(14)60249-7
碳载氧化锰表面氧还原反应路径研究
姜鲁华 1, , 唐琪雯 2, , 刘静 包结二乙烯三胺（DETA）分子,并且这种包结也具有pH依赖性。也就是说在改性前后,当pH值为11.5时,β-CD包合DETA的能力最佳,从1H-NMR上可以计算出其包合比为1∶1;而降低或者升高pH值后,都不能形成有效包合。","authors":[{"authorName":"韩晓鹃","id":"26de0f85-e146-4ee2-98e0-f8919d167d9a","originalAuthorName":"韩晓鹃"},{"authorName":"董振强","id":"86c7fa3d-fa81-44cd-b29e-62c1bd894811","originalAuthorName":"董振强"},{"authorName":"范敏敏","id":"ba51b4e7-8469-4376-96ed-b64303f32618","originalAuthorName":"范敏敏"},{"authorName":"李邦经","id":"2923ca97-1a8e-488f-867b-d090c9906932","originalAuthorName":"李邦经"},{"authorName":"张剑","id":"6834fd96-521b-44ea-a9b7-6da5b87a5501","originalAuthorName":"张剑"},{"authorName":"张晟","id":"c8f5bfbe-fe1a-4093-8289-fc0a20e212d1","originalAuthorName":"张晟"}],"doi":"","fpage":"13","id":"7afb3e52-5e52-494a-ab1f-3c5520b7f18d","issue":"9","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"e651c196-3799-416c-9524-e99c91511f7b","keyword":"β-环糊精","originalKeyword":"β-环糊精"},{"id":"75e61fc8-663a-4deb-ae89-c6149603b6c4","keyword":"聚丙烯酸","originalKeyword":"聚丙烯酸"},{"id":"10a08b02-f2f0-47fe-883c-2c7814622feb","keyword":"增溶","originalKeyword":"增溶"},{"id":"4ce46e90-dd95-440c-a301-019812afca20","keyword":"主客体包结","originalKeyword":"主客体包结"}],"language":"zh","publisherId":"gfzclkxygc201209004","title":"β-环糊精-聚丙烯酸的合成及对β-环糊精的包结与增溶性","volume":"28","year":"2012"},{"abstractinfo":"研究了主客体纳米结构ZnS半导体在光催化甲醇水溶液产氢同时产乙二醇反应中的界面\"钉住效应\".认为在主体β-环糊精(β-CD)分子包覆作用下,客体ZnS的界面能带被钉住;溶液酸碱性的变化,在很大程度上通过改变溶液相中各种氧化还原电对来间接影响客体的界面电荷输出行为.由此观点出发,并结合已有的光电实验结果,解释了主客体包容物ZnS/β-CD的最高光催化产氧活性发生在溶液pH=10～11的实验现象.","authors":[{"authorName":"吴鸣","id":"23c6bd17-8b1e-4351-8a28-8c4e05ef0d97","originalAuthorName":"吴鸣"},{"authorName":"李文钊","id":"74c83946-9701-4922-87a3-75aafe577857","originalAuthorName":"李文钊"},{"authorName":"顾婉贞","id":"2f187ff7-37a9-4742-9a2c-55d08d018205","originalAuthorName":"顾婉贞"},{"authorName":"孙福侠","id":"fcf33892-eb92-431a-97f4-c9195ec66cf4","originalAuthorName":"孙福侠"},{"authorName":"朱相伟","id":"8fed5fe9-1a1c-4bfe-b753-b34e3b67cc4c","originalAuthorName":"朱相伟"},{"authorName":"王复东","id":"d41aa7d5-2bfd-49be-9a70-a4283b8b2e5d","originalAuthorName":"王复东"},{"authorName":"林原","id":"5613dc81-642a-410a-b286-6890ea9b8e45","originalAuthorName":"林原"},{"authorName":"肖绪瑞","id":"74dc5588-0fd6-4c22-8d71-0de939a9bbd4","originalAuthorName":"肖绪瑞"}],"doi":"","fpage":"297","id":"1f9f6dc3-8086-459d-b275-5db4ba8f617d","issue":"3","journal":{"abbrevTitle":"CHXB","coverImgSrc":"journal/img/cover/CHXB.jpg","id":"18","issnPpub":"0253-9837","publisherId":"CHXB","title":"催化学报 "},"keywords":[{"id":"87fd2ee7-9f43-4643-b1dd-a1326c456b19","keyword":"钉住效应","originalKeyword":"钉住效应"},{"id":"120eaf49-a742-40c9-b14e-28c9f4b14389","keyword":"半导体","originalKeyword":"半导体"},{"id":"f311d00c-a995-425c-85d0-e54b2c518a0f","keyword":"硫化锌","originalKeyword":"硫化锌"},{"id":"629ece77-a09f-4986-9ecd-e7353d51d2bf","keyword":"β-环糊精","originalKeyword":"β-环糊精"},{"id":"4707d4d1-f2f8-4379-ba0d-fc2dc864738a","keyword":"主客体结构","originalKeyword":"主客体结构"},{"id":"68c688ff-0f0a-449e-9439-4db2d34ec592","keyword":"光催化","originalKeyword":"光催化"}],"language":"zh","publisherId":"cuihuaxb199903026","title":"主客体结构纳米半导体光催化的界面钉住效应","volume":"20","year":"1999"},{"abstractinfo":"以C-十一烷基间苯二酚杯(6)芳烃作为主体分子修饰玻碳电极表面,制成一种主客体化学传感器.并用其对溶液中的客体分子--对甲酚进行测定.该电极具有良好的选择性,对5.0×10-5～2.0×10-3mol/L的对甲酚具有很好的线性响应,检测下限为3.0×10-5mol/L.同时,对修饰前后玻碳电极的表面状态进行了研究.","authors":[{"authorName":"关槐","id":"87f6279a-f69e-4934-ab7c-89a045f192eb","originalAuthorName":"关槐"},{"authorName":"贾志华","id":"325e77cd-b34b-4b2e-8aac-ce5a3911e59a","originalAuthorName":"贾志华"}],"doi":"10.3969/j.issn.1673-2812.2004.06.037","fpage":"920","id":"46162393-2d0b-4a74-bb6e-9f420b512a83","issue":"6","journal":{"abbrevTitle":"CLKXYGCXB","coverImgSrc":"journal/img/cover/CLKXYGCXB.jpg","id":"13","issnPpub":"1673-2812","publisherId":"CLKXYGCXB","title":"材料科学与工程学报"},"keywords":[{"id":"6b83cdd6-cf57-4b9d-b1a2-d43104d2098d","keyword":"杯芳烃","originalKeyword":"杯芳烃"},{"id":"fcd523b1-077e-4c97-8966-0bc64ebff086","keyword":"对甲酚","originalKeyword":"对甲酚"},{"id":"fdc8dd58-483a-4e44-a9d6-763dd1a7c440","keyword":"主客体","originalKeyword":"主客体"}],"language":"zh","publisherId":"clkxygc200406037","title":"杯芳烃主客体化学传感器","volume":"22","year":"2004"},{"abstractinfo":"树枝状大分子具有高度支化和规整的特殊结构,在生物医药、催化化学等多个领域深具发展前景,但目前其制备均采用化学合成方法.文中发展了一种利用自组装手段构筑树枝状大分子的新方法.通过中心分子4臂-聚乙二醇-金刚烷(4 arm-PEG-Ad)和迭代单元β-环糊精-肉桂(β-CD Ci)以及α-环糊精-己二胺-金刚烷(α-CD-hex-Ad)之间的主客体识别,在水体系中,逐步组装得到超分子树状聚合物.通过动态光散射及透射电镜发现,随着代数增长,超分子树状聚合物在溶液中粒径逐渐变大.由于环糊精与客体基团可响应温度变化产生解包舍,这种树状超分子结构在温度上升到60℃以上时会发生瓦解,超分子树状聚合物的粒径由最初的单分散性变为多分散性.","authors":[{"authorName":"居新","id":"6bd470d3-fe48-454b-9b4d-e3f5b7c97960","originalAuthorName":"居新"},{"authorName":"康洋","id":"b5929cf2-1333-4d6e-ad0f-0f1db9ee32b3","originalAuthorName":"康洋"},{"authorName":"胥运","id":"7993cc4b-06ce-4f55-9f3d-df6e4b427519","originalAuthorName":"胥运"},{"authorName":"潘敏","id":"af864403-fc49-4ba2-832a-5d889c28c949","originalAuthorName":"潘敏"},{"authorName":"张晟","id":"f0a1c021-50fb-4533-bb0b-b2a07119d864","originalAuthorName":"张晟"}],"doi":"10.16865/j.cnki.1000-7555.2016.09.028","fpage":"158","id":"c40e8185-04f4-4fad-96c7-113b5d447cc1","issue":"9","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"c3e8bf56-d251-4d70-a2e4-888c2f66654a","keyword":"主客体识别","originalKeyword":"主客体识别"},{"id":"5e64b80c-2172-4ce5-9299-efa5ba4003ba","keyword":"树状聚合物","originalKeyword":"树状聚合物"},{"id":"8d3afb13-2234-40c5-a54c-e4ea9c2803ac","keyword":"自组装","originalKeyword":"自组装"}],"language":"zh","publisherId":"gfzclkxygc201609028","title":"利用主客体识别构建的树状超分子","volume":"32","year":"2016"},{"abstractinfo":"以铱配合物蓝色磷光材料Firpic作为掺杂剂,制备了基于CBP为主体的蓝色有机电致发光器件,其结构为ITO/CuPc/FIrpic:CBP(x%)/BCP/Alq3/LiF/Al,其中x%为发光层主客体掺杂浓度.分别研究了主客体掺杂浓度和空穴阻挡层BCP的厚度对器件发光性能的影响,当掺杂浓度为8%时,主客体间的能量传转移最充分,器件的启亮电压为5V,器件在20V时的亮度为7122.25cd/m2.器件电致发光(EL)光谱出现明显的红移现象,为Alq3部分参与了发光,影响了发光的色纯度,改变BCP的厚度,可以调节载流子复合区域和器件发光的色度坐标,达到改善器件发光性能的目的.","authors":[{"authorName":"杨少鹏","id":"235eba42-0499-4f43-93eb-efbb201a1f88","originalAuthorName":"杨少鹏"},{"authorName":"居秀琴","id":"783f5158-3e62-4086-83bc-9619e135ca14","originalAuthorName":"居秀琴"},{"authorName":"赵方超","id":"24fdf5f9-335b-419c-a768-5e247d6e348a","originalAuthorName":"赵方超"},{"authorName":"邱晓丽","id":"19e730dd-9958-45cc-8f2d-36f7930a496a","originalAuthorName":"邱晓丽"},{"authorName":"王利顺","id":"29215036-d1c6-4cb1-95e9-5c33c6e9a96b","originalAuthorName":"王利顺"},{"authorName":"刘素玲","id":"9048707e-037a-4258-9988-b58a83f8c552","originalAuthorName":"刘素玲"}],"doi":"","fpage":"1422","id":"5425a468-b69a-4f67-9282-3cb890e2e0dc","issue":"9","journal":{"abbrevTitle":"GNCL","coverImgSrc":"journal/img/cover/GNCL.jpg","id":"33","issnPpub":"1001-9731","publisherId":"GNCL","title":"功能材料"},"keywords":[{"id":"b44f3862-54f9-4044-847e-c73300100123","keyword":"有机电致发光器件","originalKeyword":"有机电致发光器件"},{"id":"3562dd3e-83eb-4b43-9a14-0f1ab5655332","keyword":"掺杂","originalKeyword":"掺杂"},{"id":"b9e066fd-8a21-4e0d-9531-88fec6424b6d","keyword":"空穴阻挡层","originalKeyword":"空穴阻挡层"},{"id":"856d03eb-5988-4521-83c5-7dfff8439e11","keyword":"发光性能","originalKeyword":"发光性能"}],"language":"zh","publisherId":"gncl200909003","title":"主客体掺杂和空穴阻挡对蓝色磷光OLED发光性能的影响研究","volume":"40","year":"2009"},{"abstractinfo":"综述了近年来介孔分子筛催化材料制备的研究成果及其在催化领域特别是精细化学品合成中的应用. 文章分为两部分,分别讨论了介孔材料本身作为催化剂以及介孔主客体催化材料的应用. ","authors":[{"authorName":"李亮","id":"a0537bfd-c13e-45c0-bbd4-6dec35059150","originalAuthorName":"李亮"},{"authorName":"施剑林","id":"81ef9895-a281-484a-aefb-39ac408c0c5b","originalAuthorName":"施剑林"}],"doi":"","fpage":"159","id":"8fa96ba1-b556-4636-b65b-5a005234ed15","issue":"2","journal":{"abbrevTitle":"CHXB","coverImgSrc":"journal/img/cover/CHXB.jpg","id":"18","issnPpub":"0253-9837","publisherId":"CHXB","title":"催化学报 "},"keywords":[{"id":"0f0c28e6-ac7e-4d4b-be4c-5824c959fa7b","keyword":"介孔分子筛","originalKeyword":"介孔分子筛"},{"id":"8b3a91fd-1b08-4752-8960-f7f8da083b1a","keyword":"介孔主客体材料","originalKeyword":"介孔主客体材料"},{"id":"24f131ee-d503-4f20-a5ee-c1d3997f2dea","keyword":"催化","originalKeyword":"催化"},{"id":"bc588473-1fd8-40ef-be15-2e92ac37cf28","keyword":"应用","originalKeyword":"应用"}],"language":"zh","publisherId":"cuihuaxb200502015","title":"介孔与介孔主客体材料在催化领域的应用","volume":"26","year":"2005"},{"abstractinfo":"介绍了近年来功能树枝状大分子在主客体化学中的研究概况,总结了当前该研究领域中取得的若干研究成果,展望了功能树枝状大分子在该领域中的研究与应用前景.","authors":[{"authorName":"唐新德","id":"d612916a-d640-49df-81ae-2558dc410926","originalAuthorName":"唐新德"},{"authorName":"张其震","id":"b495da07-75a4-4c56-b2a1-f9b52eeee66a","originalAuthorName":"张其震"},{"authorName":"王大庆","id":"27414005-5ef4-46ea-9b69-3192d86e07f8","originalAuthorName":"王大庆"},{"authorName":"周其凤","id":"b178cd91-d338-440a-b1ae-abf6f61a9623","originalAuthorName":"周其凤"}],"doi":"","fpage":"1","id":"a9d6cf6c-f4d7-4bfd-9c5a-1e73712322aa","issue":"1","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"b7926eba-6d9b-4771-8904-e5c5c4cd53ee","keyword":"功能树枝状大分子","originalKeyword":"功能树枝状大分子"},{"id":"369de488-c0b4-4b71-a093-dc3d22c9193d","keyword":"主客体化学","originalKeyword":"主客体化学"},{"id":"970023d4-679b-4269-b8b1-49941e578612","keyword":"位置分离","originalKeyword":"位置分离"},{"id":"7bc211a0-3db5-4ae9-846f-dd260a6c1791","keyword":"络合作用","originalKeyword":"络合作用"}],"language":"zh","publisherId":"gfzclkxygc200401001","title":"功能树枝状大分子在主客体化学中的研究进展","volume":"20","year":"2004"},{"abstractinfo":"基于环糊精/金刚烷主客体作用制备了催化活力具有温度响应的超分子仿生硒酶(PNIPAM-CD-Te).研究表明,PNIPAM-CD-Te的催化活力在25～45℃温度区间内具有典型的温度响应特性,37℃时具有最高催化活力(v0=4.97 mmol·L-1·min-1);同时,PNIPAM-CD-Te还展现出典型的酶催化饱和动力学行为.此外,研究表明,PNIPAM-CD-Te聚合物骨架在温度响应过程中会发生自组装结构的变化,这一变化对调控PNIPAM-CD-Te的底物结合能力具有重要作用,是导致PNIPAM-CD-Te催化活力具有温度响应特性的根本原因.","authors":[{"authorName":"焦淑菲","id":"20ef37e1-8f1f-456f-9b73-fc10dd48e8a0","originalAuthorName":"焦淑菲"},{"authorName":"尹艳镇","id":"6510cf67-64a0-44c1-b6e0-babf3a841040","originalAuthorName":"尹艳镇"},{"authorName":"史忠丰","id":"fdb7b323-67db-4010-9f8e-9f6209085144","originalAuthorName":"史忠丰"},{"authorName":"胡晓熙","id":"22962cc1-8947-4011-af56-c38f4c5eea76","originalAuthorName":"胡晓熙"},{"authorName":"王学谦","id":"23443fc1-e612-4697-910a-265805a45dd4","originalAuthorName":"王学谦"},{"authorName":"张丽","id":"d8549e71-7f11-42eb-b1a6-211451b25c45","originalAuthorName":"张丽"},{"authorName":"杨兰","id":"71e6cadb-b96e-4f16-92d4-b8d60b9938a0","originalAuthorName":"杨兰"}],"doi":"10.11896/j.issn.1005-023X.2015.02.009","fpage":"38","id":"cf8d206e-fadd-4d7a-bb42-5949facf0409","issue":"2","journal":{"abbrevTitle":"CLDB","coverImgSrc":"journal/img/cover/CLDB.jpg","id":"8","issnPpub":"1005-023X","publisherId":"CLDB","title":"材料导报"},"keywords":[{"id":"77bb56fd-53b6-4cfd-8ff4-163dd9c7b9dc","keyword":"超分子","originalKeyword":"超分子"},{"id":"8b66ad7b-5c9f-4788-9540-db6092364157","keyword":"主客体","originalKeyword":"主客体"},{"id":"435a69fe-e497-4a00-a94c-1d7b8f326dcf","keyword":"仿生硒酶","originalKeyword":"仿生硒酶"},{"id":"4802dab3-ac4a-4314-b668-9415e8eedf96","keyword":"温度响应","originalKeyword":"温度响应"},{"id":"9c241061-f3da-42d1-bbd8-281e75f60556","keyword":"催化机制","originalKeyword":"催化机制"}],"language":"zh","publisherId":"cldb201502009","title":"温度响应的主客体超分子人工硒酶构建及催化机制研究","volume":"29","year":"2015"},{"abstractinfo":"采用分子自组装的方法制备了β-环糊精聚合物包结物颗粒用荧光分析和红外光谱表征了包结物的结构.发现客体1-(2吡啶偶氮)-2-萘酚中极性较小的萘环进入了环糊精内腔.用β-环糊精聚合物及其自组装包结物颗粒与二甲基硅油配制了两种电流变液.对其流变学性能的研究发现.包结物电流变液在直流电场5 kV/mm中的静态屈服应力可达6.2 kPa,比主体提高近3倍:介电测试的结果表明包结物的介电常数为5.35,电导率为2.97×10-9 S/m,均高于主体.其中电导率比主体提高了10倍多:抗沉降性能测试结果为:自组装包结物存放300 h,其沉降率为89%,而主体仅为76%.包结物电流变液性能的提高可能与主客体间存在的超分子作用、客体的属性等有关.","authors":[{"authorName":"高子伟","id":"8e0c21ee-af68-4edf-8d85-74937c454513","originalAuthorName":"高子伟"},{"authorName":"赵晓鹏","id":"9fc48949-e4b8-4e93-93ad-731de7fb61eb","originalAuthorName":"赵晓鹏"},{"authorName":"梁晓强","id":"7b3fd6ea-c41e-43af-9eac-cd207ad5e3ea","originalAuthorName":"梁晓强"},{"authorName":"司刚","id":"aefef662-af26-448b-a1e3-382dd4b75e1b","originalAuthorName":"司刚"}],"doi":"10.3321/j.issn:1005-3093.2002.02.003","fpage":"126","id":"d1b0856f-2435-42ca-acfa-8839e6f6e008","issue":"2","journal":{"abbrevTitle":"CLYJXB","coverImgSrc":"journal/img/cover/CLYJXB.jpg","id":"16","issnPpub":"1005-3093","publisherId":"CLYJXB","title":"材料研究学报"},"keywords":[{"id":"175613e0-897c-4d21-88c2-e7b18f387be2","keyword":"电流变液","originalKeyword":"电流变液"},{"id":"168d9013-892a-4a1b-beb2-3e2ec7be836d","keyword":"白组装","originalKeyword":"白组装"},{"id":"aa1f7edb-807a-489a-b1a3-b8b42a122933","keyword":"β-环糊精交联聚合物","originalKeyword":"β-环糊精交联聚合物"}],"language":"zh","publisherId":"clyjxb200202003","title":"β-环糊精包结物电流变颗粒的制备和性能","volume":"16","year":"2002"},{"abstractinfo":"利用分子链上α-环糊精（α-CD）与苯基、丁基和十二烷基的微观复合作用,实现了毫米/厘米尺寸主、客体凝胶在水溶液中的聚集。实验显示,主、客体凝胶之间的聚集是选择性的,其与空白凝胶,或主体凝胶、客体凝胶自身之间都没有观察到任何相互作用产生。自由α-CD对凝胶聚集体的离解作用进一步证明了主、客体凝胶的宏观自聚集是由接枝于聚合物大分子链上的α-CD与客体基团的微观相互作用引起的。在此过程中,凝胶表面层的充分溶胀对于主、客体凝胶表面官能团能够相互接近,并发生复合起到了关键作用。","authors":[{"authorName":"胡杰","id":"93efd43d-7b27-4b58-b47d-8fcb461732cb","originalAuthorName":"胡杰"},{"authorName":"王香","id":"ccdceb2e-5964-4efd-95a2-b2da1f06e49b","originalAuthorName":"王香"},{"authorName":"郑时恒","id":"66429490-c59f-4855-abcb-5416d75a93fc","originalAuthorName":"郑时恒"}],"doi":"","fpage":"72","id":"d73ef2e4-47a4-4bb0-8d13-a2948f39346d","issue":"9","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"4e060f2a-572e-4b0c-9a27-b1f65145a493","keyword":"宏观自聚集","originalKeyword":"宏观自聚集"},{"id":"e2194567-27ee-4aca-9cfa-92527cddb25a","keyword":"凝胶","originalKeyword":"凝胶"},{"id":"3d314f64-321f-4a9f-840a-8f161bcf2fea","keyword":"主客体复合","originalKeyword":"主客体复合"},{"id":"2f5f3b34-e3a9-417a-b95d-659ed8898e36","keyword":"超分子","originalKeyword":"超分子"},{"id":"319b57d0-95a7-446a-b261-f61660d06f46","keyword":"微观作用力","originalKeyword":"微观作用力"}],"language":"zh","publisherId":"gfzclkxygc201209019","title":"主客体微观复合作用导致的凝胶宏观聚集效应","volume":"28","year":"2012"}],"totalpage":495,"totalrecord":4941}