水滑石类催化剂催化制氢及生物炼制

催化学报 , 2015, (2): 139-147. doi: 10.1016/S1872-2067(14)60229-1

水滑石类催化剂催化制氢及生物炼制

王伟 ^1, , 徐振新 ^2, , 郭章龙 ^3, , 江成发 ^4, , 储伟 ^5,

1.四川大学化学工程学院，四川成都610065; 四川大学四川省环境保护催化与材料工程研究中心，四川成都610064

2.四川大学化学工程学院,四川成都,610065

3.四川大学化学工程学院，四川成都610065; 四川大学四川省环境保护催化与材料工程研究中心，四川成都610064

4.四川大学化学工程学院,四川成都,610065

5.四川大学化学工程学院，四川成都610065; 四川大学四川省环境保护催化与材料工程研究中心，四川成都610064

基金项目: 国家重点基础研究发展计划(973计划,2011CB201202)

关键词：水滑石 , 非均相催化剂 , 水蒸气重整 , 制氢 , 生物炼制 , 酯交换反应

Layered double hydroxide and related catalysts for hydrogen production and a biorefinery

Keywords： Layered double hydroxide , Heterogeneous catalyst , Steam reforming , Hydrogen generation , Biorefinery , Transesterification

近年来，水滑石由于其独特的性质受到越来越多的关注。作为非均相固体催化剂，水滑石及其衍生物具有优良的催化性能，因此得到了广泛研究和应用。本文简述了水滑石的几种合成方法，重点介绍了水滑石类催化剂在催化制氢和生物炼制方面的应用，并预测了水滑石类材料在新材料合成及环境友好催化体系中的应用前景。

Layered double hydroxides (LDHs) have received much attention for their unique properties. As solid catalysts, LDHs and their derivates have been widely studied and applied for their excellent catalytic performance. Several synthesis methods of LDHs were briefly introduced, and the applica‐tions of LDHs and related catalysts for hydrogen production and a biorefinery were emphasized in this article. The prospects for LDH related compounds in the synthesis of new materials and their catalytic application in green catalysis systems were also presented.

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