设计合成了一系列由碳链长度可调节的Br?nsted酸中心阳离子及Lewis碱中心阴离子构成的酸性离子液体,,并应用于二氧化碳与环氧化合物的偶联反应合成环碳酸酯。考察了离子液体结构以及温度、压力和催化剂用量等参数的影响。结果表明,具有长碳链的离子液体表现出高催化活性及可重复使用性能。离子液体的酸性影响催化活性。
A series of Br?nsted acid ionic liquids (BAILs) containing a long chain Br?nsted acid site in the cati‐onic part and a Lewis basic site in the anionic part were designed, synthesized, and used as catalyst for the coupling of epoxides and carbon dioxide to cyclic carbonates without a co‐catalyst or co‐solvent. The effects of catalyst structure and other parameters on the catalytic performance were investigated. The long chain 2‐(N,N‐dimethyldodecylammonium) acetic acid bromide ([(CH2COOH)DMDA]Br) showed high catalytic activity and good reusability. This protocol was ex‐panded to various epoxides, which gave the corresponding cyclic carbonates in good yields. The acidity of the catalyst influenced its catalytic activity.
参考文献
| [1] | Markewitz P;Kuckshinrichs W;Leitner W;Linssen J Zapp P Bon-gartz R Schreiber A Müller T E .[J].Energy Environ Sci,2012,5:7281. |
| [2] | Li L;Zhao N;Wei W;Sun Y H .[J].FUEL,2013,108:112. |
| [3] | Li H;Bhadury P S;Song B A;Yang S .[J].RSC Adv,2012,2:12525. |
| [4] | 樊启佳,刘建华,陈静,夏春谷.环氧化合物羰基化反应研究新进展[J].催化学报,2012(09):1435-1447. |
| [5] | Castro-Osma J A;Lara-Sánchez A;North M;Otero A Villuendas P .[J].Catal Sci Technol,2012,2:1021. |
| [6] | Lu X B;Darensbourg D J .[J].CHEMICAL SOCIETY REVIEWS,2012,41:1462. |
| [7] | Ren W M;Wu G P;Lin F;Jiang J Y Liu C Luo Y Lu X B .[J].Chem Sci,2012,3:2094. |
| [8] | Beattie C;North M .[J].Chemistry-A European Journal,2014,20:8182. |
| [9] | Xie Y;Wang T T;Yang R X;Huang N Y Zou K Deng W Q .[J].ChemSusChem,2014,7:2110. |
| [10] | Iksi S;Aghmiz A;Rivas R;González M D Cuesta-Aluja L Castilla J Orejón A Guemmout F E Masdeu-Bultó A M .[J].Journal of Molecular Catalysis A:Chemical,2014,383-384:143. |
| [11] | Li B;Zhang L L;Song Y Y;Bai D S Jing H W .[J].Journal of Molecular Catalysis A:Chemical,2012,363-364:26. |
| [12] | Bai D S;Duan S H;Hai L;Jing H W .[J].ChemCatChem,2012,4:1752. |
| [13] | Ema T;Miyazaki Y;Koyama S;Yano Y Sakai T .[J].Chemistry Communications,2012,48:4489. |
| [14] | Wei R J;Zhang X H;Du B Y;Fan Z Q Qi G R .[J].Journal of Molecular Catalysis A:Chemical,2013,379:38. |
| [15] | Tharun J;Hwang Y;Roshan R;Ahn S Kathalikkattil A C Park D W .[J].Catal Sci Technol,2012,2:1674. |
| [16] | Li, C.-Y.;Wu, C.-R.;Liu, Y.-C.;Ko, B.-T. .Trimetallic magnesium complexes bearing amine-bis(benzotriazole phenolate) derivatives as bifunctional catalysts for ring-opening polymerization and CO _2/epoxide coupling[J].Chemical communications,2012(77):9628-9630. |
| [17] | Roeser J;Kailasam K;Thomas A .[J].ChemSusChem,2012,5:1793. |
| [18] | Dai W L;Jin B;Luo S L;Luo X B Tu X M Au C T .[J].Catalysis Today,2014,233:92. |
| [19] | Chen J X;Jin B;Dai W L;Deng S L Cao L R Cao Z J Luo S L Luo X B Tu X M Au C T .[J].Applied Catalysis A:General,2014,484:26. |
| [20] | Yu T;Weiss R G .[J].Green Chemistry,2012,14:209. |
| [21] | Gao, J.;Song, Q.-W.;He, L.-N.;Liu, C.;Yang, Z.-Z.;Han, X.;Li, X.-D.;Song, Q.-C. .Preparation of polystyrene-supported Lewis acidic Fe(III) ionic liquid and its application in catalytic conversion of carbon dioxide[J].Tetrahedron,2012(20):3835-3842. |
| [22] | He Q;O'Brien J W;Kitselman K A;Tompkins L E Curtis G C T Ker-ton F M .[J].Catal Sci Technol,2014,4:1513. |
| [23] | Ghazali-Esfahani S;Song H B;Paunescu E;Bobbink F D Liu H Z Fei Z F Laurenczy G Bagherzadeh M Yan N Dyson P J .[J].Green Chemistry,2013,15:1584. |
| [24] | Dai W L;Jin B;Luo S L;Luo X B Tu X M Au C T .[J].Journal of Molecular Catalysis A:Chemical,2013,378:326. |
| [25] | Song Q W;He L N;Wang J Q;Yasuda H Sakakura T .[J].Green Chemistry,2013,15:110. |
| [26] | Tharun J;Kim D W;Roshan R;Hwang Y Park D W .[J].CATALYSIS COMMUNICATIONS,2013,31:62. |
| [27] | Wong W L;Lee L Y S;Ho K P;Zhou Z Y Fan T Lin Z Y Wong K Y .[J].Applied Catalysis A:General,2014,472:160. |
| [28] | Wang F;Xu C Z;Li Z;Xia C G Chen J .[J].Journal of Molecular Catalysis A:Chemical,2014,385:133. |
| [29] | Dai W L;Jin B;Luo S L;Luo X B Tu X M Au C T .[J].Applied Catalysis A:General,2014,470:183. |
| [30] | Xiao L F;Sun D;Yue C T;Wu W .[J].J CO2 Utilization,2014,6:1. |
| [31] | Dai W L;Jin B;Luo S L;Yin S F Luo X B Au C T .[J].J CO2 Utilization,2013,3-4:7. |
| [32] | Sun J;Wang J Q;Cheng W G;Zhang J X Li X H Zhang S J She Y B .[J].Green Chemistry,2012,14:654. |
| [33] | Watile R A;Deshmukh K M;Dhake K P;Bhanage B M .[J].Catal Sci Technol,2012,2:1051. |
| [34] | Qu J;Cao C Y;Dou Z F;Liu H Yu Y Li P Song W G .[J].ChemSusChem,2012,5:652. |
| [35] | Xiao L F;Lü D W;Su D;Wu W Li H F .[J].JOURNAL OF CLEANER PRODUCTION,2014,67:285. |
| [36] | Han L N;Choi S J;Park M S;Lee S M Kim Y J Kim M I Liu B Y Park D W .[J].React Kinet Mech Catal,2012,106:25. |
| [37] | Zhang Y Y;Yin S F;Luo S L;Au C T .[J].Industrial and Engineering Chemistry Research,2012,51:3951. |
| [38] | He L Q;Qin S J;Chang T;Sun Y Z Zhao J Q .[J].INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES,2014,15:8656. |
| [39] | He L Q;Qin S J;Chang T;Sun Y Z Gao X R .[J].Catal Sci Technol,2013,3:1102. |
| [40] | Chang T;He L Q;Bian L;Han H Y Yuan M X Gao X R .[J].RSC Adv,2014,4:727. |
| [41] | Fei ZF;Zhao DB;Geldbach TJ;Scopelliti R;Dyson PJ .Bronsted acidic ionic liquids and their zwitterions: Synthesis, characterization and pK(a) determination[J].Chemistry: A European journal,2004(19):4886-4893. |
| [42] | Zhang J L;Han B X;Zhao Y J;Li J S Hou M Q Yang G Y .[J].Chem Com-mun,2011,47:1033. |
| [43] | Miao C X;Wang J Q;Wu Y;Du Y He L N .[J].ChemSusChem,2008,1:236. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%