金属离子掺杂纳米TiO2(M-TiO2, M = Zn2+, Cu2+, Co2+, Mn2+, Ni2+)在CO2与环氧化合物的偶联反应中表现出较高的催化活性。反应以四正丁基碘化铵(TBAI)为共催化剂,在无溶剂条件下进行。考察了反应温度、反应时间和CO2压力在Zn-TiO2/TBAI体系中对反应性能的影响。作为无毒的多相催化剂, Zn-TiO2可循环使用5次,其催化活性没有明显降低。
TiO2 doped with metal ions (M-TiO2, M=Zn2+, Cu2+, Co2+, Mn2+, or Ni2+) was investigated as a heter-ogeneous catalyst for the coupling reaction of CO2 and epoxides, using tetrabutylammonium iodide (TBAI) as a co-catalyst under solvent-free conditions. These compounds were found to exhibit high catalytic activities. The effects of reaction temperature, reaction time, and CO2 pressure on the effec-tiveness of a Zn-TiO2/TBAI catalyst system were also examined. Zn-TiO2 represents a nontoxic, heterogeneous catalyst that can be reutilized up to five times without a significant loss of catalytic activity.
参考文献
[1] | North M;Pasquale R;Young C .[J].Green Chemistry,2010,12:1514. |
[2] | Sakakura T;Kohno K.[J].Chemistry Communications,2009:1312. |
[3] | Mikkelsen M;Jorgensen M;Krebs F C .[J].Energy Environ Sci,2010,3:43. |
[4] | Jutz, F.;Andanson, J.-M.;Baiker, A. .Ionic liquids and dense carbon dioxide: A beneficial biphasic system for catalysis[J].Chemical Reviews,2011(2):322-353. |
[5] | Darensbourg D J;Holtcamp M W .[J].Coordination Chemistry Review,1996,153:155. |
[6] | Shaikh A A G;Sivaram S .[J].CHEMICAL REVIEWS,1996,96:951. |
[7] | Clements J H .[J].Industrial and Engineering Chemistry Research,2003,42:663. |
[8] | Spinner N S;Vega J A;Mustain W E .[J].Catal Sci Technol,2012,2:19. |
[9] | Sit, WN;Ng, SM;Kwong, KY;Lau, CP .Coupling reactions of CO2 with neat epoxides catalyzed by PPN salts to yield cyclic carbonates[J].The Journal of Organic Chemistry,2005(21):8583-8586. |
[10] | Motokura K;Itagaki S;Iwasawa Y;Miyaji A Baba T .[J].Green Chemistry,2009,11:1876. |
[11] | Kawanami H;Sasaki A;Matsui K;Ikushima Y.[J].Chemistry Communications,2003:896. |
[12] | Sun J;Zhang S J;Cheng W G;Ren J Y .[J].Tetrahedron Letters,2008,49:3588. |
[13] | Wang J Q;Yue X D;Cai F;He L N .[J].CATALYSIS COMMUNICATIONS,2007,8:167. |
[14] | Yasuda H;He L N;Sakakura T .[J].Journal of Catalysis,2002,209:547. |
[15] | Jing HW;Nguyen ST .SnCl4-organic base: Highly efficient catalyst system for coupling reaction of CO2 and epoxides[J].Journal of molecular catalysis, A. Chemical,2007(26):12-15. |
[16] | Lu X B;Darensbourg D J .[J].CHEMICAL SOCIETY REVIEWS,2012,41:1462. |
[17] | Tian D W;Liu B Y;Gan Q Y;Li H R Darensbourg D J .[J].ACS Catal,2012,2:2029. |
[18] | Jin LL;Jing HW;Chang T;Bu XL;Wang L;Liu ZL .Metal porphyrin/phenyltrimethylammonium tribromide: High efficient catalysts for coupling reaction of CO2 and epoxides[J].Journal of molecular catalysis, A. Chemical,2007(26):262-266. |
[19] | Chang T;Jing HW;Jin L;Qiu WY .Quaternary onium tribromide catalyzed cyclic carbonate synthesis from carbon dioxide and epoxides[J].Journal of molecular catalysis, A. Chemical,2007(1/2):241-247. |
[20] | Jing H W;Chang T;Jin L L;Wu M Qiu W Y .[J].CATALYSIS COMMUNICATIONS,2007,8:1630. |
[21] | Bhanage B M;Fujita S;Ikushima Y;Arai M .[J].Applied Catalysis A:General,2001,219:259. |
[22] | Aresta M.;Dibenedetto A.;Gianfrate L.;Pastore C. .Nb(V) compounds as epoxides carboxylation catalysts: the role of the solvent[J].Journal of molecular catalysis, A. Chemical,2003(0):245-252. |
[23] | Du Y;Cai F;Kong DL;He LN .Organic solvent-free process for the synthesis of propylene carbonate from supercritical carbon dioxide and propylene oxide catalyzed by insoluble ion exchange resins[J].Green chemistry,2005(7):518-523. |
[24] | Tu M;Davis R J .[J].Journal of Catalysis,2001,199:85. |
[25] | Lu X B;Wang H;He R .[J].Journal of Molecular Catalysis A:Chemical,2002,186:33. |
[26] | Lu X B;Xiu J H;He R;Jin K Luo L M Feng X J .[J].Applied Catalysis A:General,2004,275:73. |
[27] | 曹婷,孙立婷,石玉,华丽,张然,郭立,朱闻闻,侯震山.无机氧化物载体对催化 CO2 与环氧化合物合成环状碳酸酯的促进作用[J].催化学报,2012(03):416-424. |
[28] | Zhou X;Zhang Y;Yang X G;Zhao L Z Wang G Y .[J].Journal of Molecular Catalysis A:Chemical,2012,361-362:12. |
[29] | Liang S G;Liu H Z;Jiang T;Song J L Yang G Y Han B X .[J].Chem Com-mun,2011,47:2131. |
[30] | Pfaff G;Reynders P .[J].CHEMICAL REVIEWS,1999,99:1963. |
[31] | Salvador A;Pascual Marti-MC;Adell JR;Requeni A;March JG .Analytical methodologies for atomic spectrometric determination of metallic oxides in UV sunscreen creams.[J].Journal of Pharmaceutical and Biomedical Analysis: An International Journal on All Drug-Related Topics in Pharmaceutical, Biomedical and Clinical Analysis,2000(2):301-306. |
[32] | Zallen R;Moret MP .The optical absorption edge of brookite TiO2[J].Solid State Communications,2006(3):154-157. |
[33] | Wang A Q;Jing H W .[J].DALTON TRANSACTIONS,2014,43:1011. |
[34] | Mar L G;Timbrell P Y;Lamb R N .[J].THIN SOLID FILMS,1993,223:341. |
[35] | Webb P B;Sellin M F;Kunene T E;Williamson S Slawin A M Z Cole-Hamilton D J .[J].Journal of the American Chemical Society,2003,125:15577. |
- 下载量()
- 访问量()
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%