One-pot multicomponent synthesis of unsymmetrical polyhydroquinoline derivatives with 1,1'-butylenebispyridinium hydrogen sulfate as an efficient, halogen-free and reusable Br?nsted ionic liquid catalyst

催化学报 , 2014, (9): 1497-1503. doi: 10.1016/S1872-2067(14)60087-5

1.Research House of Professor Reza, Education Guilan, Rasht, District 1, 41569-17139, Iran

One-pot multicomponent synthesis of unsymmetrical polyhydroquinoline derivatives with 1,1'-butylenebispyridinium hydrogen sulfate as an efficient, halogen-free and reusable Br?nsted ionic liquid catalyst

Keywords： Unsymmetric polyhydroquinolines

1,1'-Butylenebispyridinium hydrogen sulfate is an efficient, halogen-free and reusable Br?nsted ionic liquid catalyst for the synthesis of ethyl-4-aryl/heteryl-hexahydro-trimehtyl-5-oxoquino-line-3-carboxylates by the one-pot condensation of dimedone, aryl/heteryl aldehydes, ethyl aceto-acetate, and ammonium acetate under solvent-free conditions. This method has the advantages of high yield, clean reaction, simple methodology, and short reaction time. The ionic liquid can be re-cycled five times without significant loss of the catalytic activity.

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One-pot multicomponent synthesis of unsymmetrical polyhydroquinoline derivatives with 1,1'-butylenebispyridinium hydrogen sulfate as an efficient, halogen-free and reusable Br?nsted ionic liquid catalyst

参考文献