纳米催化介于均相催化与多相催化之间,也称为”半多相催化”,目前正受到人们越来越多的关注.最近几年,应用双金属纳米材料进行催化研究取得了很大进展,使用这些催化材料可以增加反应活性和选择性,而且能很好地得以回收.本文综述了双金属纳米材料催化的各种有机反应,如选择性氧化/氢化、偶联和其它反应(脱卤、酰胺化、还原氨化、芳基硼酸与烯酮的1,4-不对称加成和氢解).将双金属纳米材料用于催化合成更加复杂的有机分子值得期待.在双金属纳米有机催化领域,基础理论和实际应用尚有较大的发展空间.未来该领域的发展需要开展多学科的合作,包括合理设计和可控制备相关的双金属纳米材料、深入理解催化机理及发展计算催化.
参考文献
| [1] | Yu, W.;Porosoff, M.D.;Chen, J.G. .Review of Pt-based bimetallic catalysis: From model surfaces to supported catalysts (Review)[J].Chemical Reviews,2012(11):5780-5817. |
| [2] | Cushing B L;Kolesnichenko V L;O'Connor C J .[J].Chemical Reviews,2004,104:3893. |
| [3] | Ferrando R;Jellinek J;Johnston R L .[J].Chemical Reviews,2008,108:845. |
| [4] | Wang D S;Li Y D .[J].Advanced Materials,2011,23:1044. |
| [5] | Campbell C T .[J].Annual Review of Physical Chemistry,1990,41:775. |
| [6] | Gu J;Zhang Y-W;Tao F .[J].Chemical Society Reviews,2012,41:8050. |
| [7] | Rodriguez J A .[J].Surface Science Reports,1996,24:223. |
| [8] | Madey T.E.;Pelhos K.;Kolodziej J.J.;Abdelrehim I.M.;Tao H.-S.;Nien C.-H. .Faceting induced by ultrathin metal films: structure, electronic properties and reactivity[J].Surface Science: A Journal Devoted to the Physics and Chemistry of Interfaces,1999(1/3):191-206. |
| [9] | Schauermann S;Nilius N;Shaikhutdinov S;Freund H-J .[J].Accounts of Chemical Research,2013,46:1673. |
| [10] | Zhou K B;Li Y D .[J].Angewandte Chemie International Edition,2012,51:602. |
| [11] | Pushkarev V V;Zhu Z;An K;Hervier A Somorjai G A .[J].Topics in Catalysis,2012,55:1257. |
| [12] | Shi J L .[J].Chemical Reviews,2013,113:2139. |
| [13] | Sinfelt J H.Bimetallic Catalysts:Discoveries,Concepts,and Applications[M].New York:John Wiley and Sons,Inc,1983 |
| [14] | RoucouxA;Schulz J;Patin H .[J].Chemical Reviews,2002,102:3757. |
| [15] | Pyykko P .[J].Angewandte Chemie International Edition,2002,41:3573. |
| [16] | Wu W Q;Jiang H F .[J].Accounts of Chemical Research,2012,45:1736. |
| [17] | Piera J;B(a)ckvall J-E .[J].Angewandte Chemie International Edition,2008,47:3506. |
| [18] | Punniyamurthy T;Velusamy S;Iqbal J .[J].Chemical Reviews,2005,105:2329. |
| [19] | Haruta M;Kobayashi T;Sano H;Yamada N.[J].Chemistry Letters,1987:405. |
| [20] | Zhang, Y.;Cui, X.;Shi, F.;Deng, Y. .Nano-gold catalysis in fine chemical synthesis[J].Chemical Reviews,2012(4):2467-2505. |
| [21] | Mikami Y;Dhakshinamoorthy A;Alvaro M;García H .[J].Catalysis Science & Technology,2013,3:58. |
| [22] | Matsumoto T;Ueno M;Wang N;Kobayashi S .[J].Chemistry – An Asian Journal,2008,3:196. |
| [23] | Malat T;Baiker A .[J].Chemical Reviews,2004,104:3037. |
| [24] | Della Pina C;Falletta E;Rossi M .Highly selective oxidation of benzyl alcohol to benzaldehyde catalyzed by bimetallic gold-copper catalyst[J].Journal of Catalysis,2008(2):384-386. |
| [25] | Huang X M;Wang X G;Wang X S;Wang X X Tan M W Ding W Z Lu XG .[J].Journal of Catalysis,2013,301:217. |
| [26] | Huang X M;Wang X G;Tan M W;Zou X J Ding W Z Lu X G .[J].Applied Catalysis A:General,2013,467:407. |
| [27] | Li W J;Wang A Q;Liu X Y;Zhang T .[J].Applied Catalysis A:General,2012,433-434:146. |
| [28] | Sugano Y;Shiraishi Y;Tsukamoto D;lchikawa S Tanaka 5 Hirai T .[J].Angewandte Chemie International Edition,2013,52:5295. |
| [29] | Chen Y T;Lim H M;Tang Q H;Gao Y T Sun T Yan Q Y Yang Y H .[J].Applied Catalysis A:General,2010,380:55. |
| [30] | Balcha T;Strobl J R;Fowler C;Dash P Scott R W J .[J].ACS Catalysis,2011,1:425. |
| [31] | Miyamura, H;Matsubara, R;Kobayashi, S .Gold-platinum bimetallic clusters for aerobic oxidation of alcohols under ambient conditions[J].Chemical communications,2008(17):2031-2033. |
| [32] | Dimitratos N;Villa A;Wang D;Porta F Su D S Prati L .[J].Journal of Catalysis,2006,244:113. |
| [33] | Villa A;Janjic N;Spontoni P;Wang D Su D S Prati L .[J].Applied Catalysis A:General,2009,364:221. |
| [34] | Enache DI;Edwards JK;Landon P;Solsona-Espriu B;Carley AF;Herzing AA;Watanabe M;Kiely CJ;Knight DW;Hutchings GJ .Solvent-free oxidation of primary alcohols to aldehydes using Au-Pd/TiO2 catalysts[J].Science,2006(5759):362-365. |
| [35] | Kaizuka, K.;Miyamura, H.;Kobayashi, S. .Remarkable effect of bimetallic nanocluster catalysts for aerobic oxidation of alcohols: Combining metals changes the activities and the reaction pathways to aldehydes/carboxylic acids or esters[J].Journal of the American Chemical Society,2010(43):15096-15098. |
| [36] | Yoo, W.-J.;Miyamura, H.;Kobayashi, S. .Polymer-incarcerated gold-palladium nanoclusters with boron on carbon: A mild and efficient catalyst for the sequential aerobic oxidation-Michael addition of 1,3-dicarbonyl compounds to allylic alcohols[J].Journal of the American Chemical Society,2011(9):3095-3103. |
| [37] | Kesavan L;Tiruvalam R;Ab Rahim M H;bin Saiman M I Enache D I Jenkins R L Dimitratos N Lopez-Sanchez J A Taylor S H Knight D W Kiely C J Hutchings G J .[J].Science,2011,331:195. |
| [38] | bin Saiman M I;Brett G L;Tiruvalam R;Forde M M Sharples K Thetford A Jenkins R L Dimitratos N Lopez-Sanchez J A Murphy D M Bethell D Willock D J Taylor S H Knight D W Kiely C J Hutchings G J .[J].Angewandte Chemie International Edition,2012,51:5981. |
| [39] | Alonso F;Riente P;Yus M .[J].Accounts of Chemical Research,2011,44:379. |
| [40] | Yan N;Zhao C;Luo C;Dyson P J Liu H C Kou Y .[J].Journal of the American Chemical Society,2006,128:8714. |
| [41] | Xu K L;Zhang Y;Chen X R;Huang L Zhang R Huang J .[J].Advanced Synthesis and Catalysis,2011,353:1260. |
| [42] | Corma A;Serna P;Concepcion P;Calvino JJ .Transforming nonselective into chemoselective metal catalysts for the hydrogenation of substituted nitroaromatics[J].Journal of the American Chemical Society,2008(27):8748-8753. |
| [43] | Tsang, S.C.;Cailuo, N.;Oduro, W.;Kong, A.T.S.;Clifton, L.;Yu, K.M.K.;Thiebaut, B.;Cookson, J.;Bishop, P. .Engineering preformed cobalt-doped platinum nanocatalysts for ultraselective hydrogenation[J].ACS nano,2008(12):2547-2553. |
| [44] | Zheng R Y;Porosoff M D;Weiner J L;Lu S L Zhu Y X Chen J G .[J].Applied Catalysis A:General,2012,419-420:126. |
| [45] | Gual, A.;Godard, C.;Castillón, S.;Claver, C. .Soluble transition-metal nanoparticles-catalysed hydrogenation of arenes[J].Dalton transactions: An international journal of inorganic chemistry,2010(48):11499-11512. |
| [46] | Blaser H-U;Steiner H;Studer M .[J].ChemCatChem,2009,1:210. |
| [47] | Wei H-H;Yen C H;Lin H-W;Tan C-S .[J].Journal of Supercritical Fluids,2013,81:1. |
| [48] | Wu Y E;Cai S F;Wang D S;He W Li Y D .[J].Journal of the American Chemical Society,2012,134:8975. |
| [49] | Wang D S;Li Y D .[J].Journal of the American Chemical Society,2010,132:6280. |
| [50] | Duan H H;Wang D S;Kou Y;Li Y D .[J].Chemical Communications,2013,49:303. |
| [51] | Lonergan, W.W.;Vlachos, D.G.;Chen, J.G. .Correlating extent of Pt-Ni bond formation with low-temperature hydrogenation of benzene and 1,3-butadiene over supported Pt/Ni bimetallic catalysts[J].Journal of Catalysis,2010(2):239-250. |
| [52] | Studt F;Abild-Pedersen F;Bligaard T;Sorensen RZ;Christensen CH;Norskov JK .Identification of non-precious metal alloy catalysts for selective hydrogenation of acetylene.[J].Science,2008(5881):1320-1322. |
| [53] | Vang R T;Honkala K;Dahl S;Vestergaard E K Schnadt J Laegsgaard E Clausen B S N(Φ)rskov J K Besenbacher F .[J].Nature Materials,2005,4:160. |
| [54] | Wehrli J T;Thomas D J;Wainwright M S;Trimm D L Cant N W .[J].Applied Catalysis,1990,66:199. |
| [55] | Wehrli J T;Thomas D J;Wainwright M S;Trimm D L Cant N W .[J].Applied Catalysis,1991,70:253. |
| [56] | Menezes, W.G.;Altmann, L.;Zielasek, V.;Thiel, K.;B?umer, M..Bimetallic Co-Pd catalysts: Study of preparation methods and their influence on the selective hydrogenation of acetylene[J].Journal of Catalysis,2013:125-135. |
| [57] | Nakamula I;Yamanoi Y;Imaoka T;Yamamoto K Nishihara H .[J].Angewandte Chemie International Edition,2011,50:5830. |
| [58] | Cai S F;Duan H H;Rong H P;Wang D S Li L S He W Li Y D .[J].ACS Catalysis,2013,3:608. |
| [59] | Xia B H;He F;Li L D .[J].Langmuir,2013,29:4901. |
| [60] | Jiang, H.-L.;Akita, T.;Ishida, T.;Haruta, M.;Xu, Q. .Synergistic catalysis of Au@Ag core-shell nanoparticles stabilized on metal-organic framework[J].Journal of the American Chemical Society,2011(5):1304-1306. |
| [61] | Cardenas-Lizana F;Gomez-Quero S;Hugon A;Delannoy L Louis C Keane M A .[J].Journal of Catalysis,2009,262:235. |
| [62] | Corbos E C;Ellis P R;Cookson J;Briois V,Hyde T I,Sankar G,Bishop P T.[J].Catalysis Science & Technology,2013 |
| [63] | Liu M H;Bai Q;Xiao H L;Liu Y Y Zhao J Yu W W .[J].Chemical Engineering Journal,2013,232:89. |
| [64] | 解雅玲,肖南,凌铮,柳月,于畅,邱介山.高活性三维花型 Co-Ni/C 双金属催化剂用于邻氯硝基苯选择性加氢反应[J].催化学报,2012(12):1883-1888. |
| [65] | Müslehiddino(g)lu J;Li J;Tummala S;Deshpande R .[J].Organic Process Research & Development,2010,14:890. |
| [66] | Johansson Seechurn C C C;Kitching M O;Colacot T J;Snieckus V .[J].Angewandte Chemie International Edition,2012,51:5062. |
| [67] | Hyotanishi, M.;Isomura, Y.;Yamamoto, H.;Kawasaki, H.;Obora, Y. .Surfactant-free synthesis of palladium nanoclusters for their use in catalytic cross-coupling reactions[J].Chemical communications,2011(20):5750-5752. |
| [68] | Li C C;Sato R;Kanehara M;Zeng H B Bando Y Teranishi T .[J].Angewandte Chemie International Edition,2009,48:1. |
| [69] | Zhang R Z;Liu J M;Li F W;Wang S F Xia C G Sun W .[J].Chinese Journal of Chemistry,2011,29:525. |
| [70] | Shen Y-M;Du Y-J;Zeng M-F;Zhi D Zhao S-X Rong L-M Lv S-Q Du L Qi C-Z .[J].Applied Organometallic Chemistry,2010,24:631. |
| [71] | Wu Y E;Wang D S;Zhao P;Niu 7.Q Peng Q Li Y D .[J].Inorganic Chemistry,2011,50:2046. |
| [72] | Tan L F;Wu X L;Chen D;Liu H Y Meng X W Tang F Q .[J].Journal of Materials Chemistry A,2013,1:10382. |
| [73] | Shaabani A;Mahyari M .[J].Journal of Materials Chemistry A,2013,1:9303. |
| [74] | Alonso A;Shafir A;Macanás J;Vallribera A Mu(n)oz M Muraviev D N .[J].Catalysis Today,2012,193:200. |
| [75] | Kim S-J;Oh S-D;Lee S;Choi S-H .[J].Journal of Industrial and Engineering Chemistry,2008,14:449. |
| [76] | 徐伟,孙原龙,郭萌涵,张伟强,高子伟.蒙脱土负载Pd/Cu双金属纳米微粒催化Sonogashira偶联反应[J].有机化学,2013(04):820-826. |
| [77] | Durand J;Teuma E;Gomez M.[J].European Journal of Internal Medicine,2008:3577. |
| [78] | Phan NTS;Van Der Sluys M;Jones CW .On the nature of the active species in palladium catalyzed Mizoroki-Heck and Suzuki-Miyaura couplings - Homogeneous or heterogeneous catalysis, a critical review[J].Advanced synthesis & catalysis,2006(6):609-679. |
| [79] | Widegren J A;Finke R G .[J].Journal of Molecular Catalysis A:Chemical,2003,198:317. |
| [80] | Fang P-P;Jutand A;Tian Z-Q;Amatore C .[J].Angewandte Chemie International Edition,2011,50:12184. |
| [81] | Karam A;Alonso J C;Gerganova T I;Ferreira P,Bion N,Barrault J,Jerome F.[J].Chemical Communications,2009:7000. |
| [82] | Dhital R N;Kamonsatikul C;Somsook E;Sakurai H.[J].Catalysis Science & Technology,2013 |
| [83] | Niu Z Q;Peng Q;Zhuang Z B;He W Li Y D .[J].Chemistry - A European Journal,2012,18:9813. |
| [84] | Ordó(n)ez S;Sastre H;Diez F V .[J].Reaction Kinetics & Catalysis Letters,2000,70:61. |
| [85] | Shin EJ.;Keane MA. .Catalytic hydrogen treatment of aromatic alcohols[J].Journal of Catalysis,1998(2):450-459. |
| [86] | Feng, J.-T.;Lin, Y.-J.;Evans, D.G.;Duan, X.;Li, D.-Q. .Enhanced metal dispersion and hydrodechlorination properties of a Ni/Al_2O_3 catalyst derived from layered double hydroxides[J].Journal of Catalysis,2009(2):351-358. |
| [87] | Wu W H;Xu J;Ohnishi R .[J].Applied Catalysis B:Environmental,2005,60:129. |
| [88] | Meshesha B T;Chimentao R J;Segarra A M;Llorca J Medina F Coq B Sueiras J E .[J].Applied Catalysis B:Environmental,2011,105:361. |
| [89] | Díaz E;Faba L;Ordó(n)ez S .[J].Applied Catalysis B:Environmental,2011,104:415. |
| [90] | Díaz E;Ordó(n)ez S;Bueres R F;Asedegbega-Nieto E Sastre H .[J].Applied Catalysis B:Environmental,2010,99:181. |
| [91] | Janiak T;Okal J .[J].Applied Catalysis B:Environmental,2009,92:384. |
| [92] | Bonarowska M;Kaszkur Z;Kepi(n)ski L;Karpi(n)ski Z .[J].Applied Catalysis B:Environmental,2010,99:248. |
| [93] | Coq B;Ferrat G;Figueras F .[J].Journal of Catalysis,1986,101:434. |
| [94] | Ordó(n)ez S;Sastre H;Díez F V .[J].Applied Catalysis B:Environmental,2003,40:119. |
| [95] | Amenomiya Y;Birss V I;Goledzinowski M;Galuszka J Singer A R .[J].Catalysis Reviews - Science and Engineering,1990,32:163. |
| [96] | Diaz E;Mohedano A F;Casas J A;Calvo L Gilarranz M A Rodriguez J J .[J].Applied Catalysis B:Environmental,2011,106:469. |
| [97] | Bertolini J C;Jugnet Y;Woodruff D P.Surfaces Alloy and Alloys Surface[M].Amsterdam:Elsevier Science,2002:404. |
| [98] | Wang X Y;Chen C;Chang Y;Liu H L .[J].Journal of Hazardous Materials,2009,161:815. |
| [99] | Shih, YH;Chen, YC;Chen, MY;Tai, YT;Tso, CP .Dechlorination of hexachlorobenzene by using nanoscale Fe and nanoscale Pd/Fe bimetallic particles[J].Colloids and Surfaces. A, Physicochemical and Engineering Aspects,2009(2/3):84-89. |
| [100] | Zahran E M;Bhattacharyya D;Bachas L G .[J].Chemosphere,2013,91:165. |
| [101] | Babu N S;Lingaiah N;Sai Prasad P S .[J].Applied Catalysis B:Environmental,2012,111-112:309. |
| [102] | Yang B;Deng S B;Yu G;Zhang H Wu J H Zhuo Q F .[J].Journal of Hazardous Materials,2011,189:76. |
| [103] | Rong H P;Cai S F;Niu Z O Li Y D .[J].ACS Catalysis,2013,3:1560. |
| [104] | Nie X Q;Liu J G;Yue D B;Zeng X W Nie Y F .[J].Chemosphere,2013,90:2403. |
| [105] | Parshetti G K;Doong RA .[J].Chemosphere,2012,86:392. |
| [106] | Keane M A;Gómez-Quero S;Cárdenas-Lizana F;Shen W Q .[J].ChemCatChem,2009,1:270. |
| [107] | Legawiec-Jarzyna M;Juszczyk W;Bonarowska M;Kaszkur Z Kepi(n)ski L Kowalczyk Z Karpi(n)ski Z .[J].Topics in Catalysis,2009,52:1037. |
| [108] | Soulé, J.-F.;Miyamura, H.;Kobayashi, S. .Powerful amide synthesis from alcohols and amines under aerobic conditions catalyzed by gold or gold/iron, -nickel or-cobalt nanoparticles[J].Journal of the American Chemical Society,2011(46):18550-18553. |
| [109] | Hu, L.;Cao, X.;Ge, D.;Hong, H.;Guo, Z.;Chen, L.;Sun, X.;Tang, J.;Zheng, J.;Lu, J.;Gu, H. .Ultrathin platinum nanowire catalysts for direct C-N coupling of carbonyls with aromatic nitro compounds under 1 bar of hydrogen[J].Chemistry: A European journal,2011(50):14283-14287. |
| [110] | Sreedhar B;Reddy P S;Devi D K .[J].Journal of Organic Chemistry,2009,74:8806. |
| [111] | Li L S;Niu Z 0;Cai S F;Li H Rong H P Zhi Y Liu L C Liu L He W Li Y D .[J].Chemical Communications,2013,49:6843. |
| [112] | Yasukawa, T.;Miyamura, H.;Kobayashi, S. .Polymer-incarcerated chiral Rh/Ag nanoparticles for asymmetric 1,4-addition reactions of arylboronic acids to enones: Remarkable effects of bimetallic structure on activity and metal leaching[J].Journal of the American Chemical Society,2012(41):16963-16966. |
| [113] | Ma L;He D H .[J].Topics in Catalysis,2009,52:834. |
| [114] | Li B D;Wang J;Yuan Y Z;Ariga H Takakusagi S Asakura K .[J].ACS Catalysis,2011,1:1521. |
| [115] | Astruc D.Nanoparticles and Catalysis[M].Weinheim:Wiley-VCH Verlag GmbH & Co.KGaA,2008 |
| [116] | Patil N T .[J].ChemCatChem,2011,3:1121. |
| [117] | Myers V S;Weir M G;Carino E V;Yancey D F Pande S Crooks R M .[J].Chemical Science,2011,2:1632. |
| [118] | Cong H;Porco J A Jr .[J].ACS Catalysis,2012,2:65. |
| [119] | Liu X W;Wang D S;Li Y D .[J].Nano Today,2012,7:448. |
| [120] | Tao F .[J].Chemical Society Reviews,2012,41:7977. |
| [121] | Tao F;Zhang S;Nguyen L;Zhang X Q .[J].Chemical Society Reviews,2012,41:7980. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%