Rice husk ash supported FeCl2·2H2O:A mild and highly efficient heterogeneous catalyst for the synthesis of polysubstituted quinolines by Friedl?nder heteroannulation

催化学报 , 2013, (12): 2200-2208. doi: 10.1016/S1872-2067(12)60684-6

¹ , ² , ³

1.Department of Chemistry, College of Sciences, University of Guilan, Rasht 41335, Iran

2.Department of Chemistry, College of Sciences, University of Guilan, Rasht 41335, Iran

3.Department of Chemistry, College of Sciences, University of Guilan, Rasht 41335, Iran

Rice husk ash supported FeCl2·2H2O:A mild and highly efficient heterogeneous catalyst for the synthesis of polysubstituted quinolines by Friedl?nder heteroannulation

Farhad Shirini ¹ , Somayeh Akbari-Dadamahaleh ² , Ali Mohammad-Khah ³

1.Department of Chemistry, College of Sciences, University of Guilan, Rasht 41335, Iran

2.Department of Chemistry, College of Sciences, University of Guilan, Rasht 41335, Iran

3.Department of Chemistry, College of Sciences, University of Guilan, Rasht 41335, Iran

Keywords： Rice husk ash

Rice husk ash was used as a new, green, and cheap adsorbent for FeCl3. Characterization of the ob-tained reagent showed that rice husk ash supported FeCl2·2H2O was formed. This reagent is effi-cient at catalyzing the synthesis of multisubstituted quinolines by the Friedl?nder heteroannulation of o-aminoaryl ketones with ketones orβ-diketones under mild reaction conditions. This method-ology allows for the synthesis of a broad range of substituted quinolines in high yields and with excellent regioselectivity in the absence of a solvent.

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Rice husk ash supported FeCl2·2H2O:A mild and highly efficient heterogeneous catalyst for the synthesis of polysubstituted quinolines by Friedl?nder heteroannulation

参考文献