采用共沉淀法合成了M0.02Cu0.4Mg5.6Al1.98(OH)16CO3 (M=Ru,Re)水滑石前驱体,然后经焙烧和还原制备了铜分散度较高的双功能M-Cu/固体碱催化剂.这些双功能催化剂在粗甘油氢解制备丙二醇反应中表现出了很好的催化活性.表征结果证明,M的加入增强了催化剂表面氢的吸附和活化,进而促进了甘油的转化.
参考文献
| [1] | Marceau E;Carrier X;Che M;Clause O,Marcilly C.Ertl G,Kn(o)zinger H,Schüth F,Weitkamp J.Handbook of Heterogeneous Catalysis[M].Weinheim:Wiley-VCH,2008:467. |
| [2] | Liu H B;Jiao Q Z;Zhao Y;Li H S Sun C B Li X F .[J].Journal of Alloys and Compounds,2010,496:317. |
| [3] | Yuan Z L;Wang L N;Wang J H;Xia S X Chen P Hou Z Y Zheng X M .[J].Applied Catalysis B:Environmental,2011,101:431. |
| [4] | Shao M F;Ning F Y;Zhao J W;Wei M Evans D G Duan X .[J].Journal of the American Chemical Society,2012,134:1071. |
| [5] | Meher L C;Gopinath R;Naik S N;Dalai A K .[J].Industrial and Engineering Chemistry Research,2009,48:1840. |
| [6] | Valente J S;Hernandez-Cortez J;Cantu M S;Ferrat G López-Salinas E .[J].Catalysis Today,2010,150:340. |
| [7] | Guo X H;Li Y;Song W;Shen W J .[J].Catalysis Letters,2011,141:1458. |
| [8] | Takehira K;Shishido T;Wang P;Kosaka T Takaki K .[J].Journal of Catalysis,2004,221:43. |
| [9] | Tsyganok A i;Tsunoda T;Hamakawa S;Suzuki K Takehira K Hayakawa T .[J].Journal of Catalysis,2003,213:191. |
| [10] | Morioka H;Shimizu Y;Sukenobu M;Ito K Tanabe E Shishido T Takehira K .[J].Applied Catalysis A:General,2001,215:11. |
| [11] | 黄金花,陈吉祥.Ni2P/SiO2和Ni/SiO2催化剂甘油氢解反应性能比较：催化剂活性及产物选择性影响因素的探讨[J].催化学报,2012(05):790-796. |
| [12] | Zope B N;Hibbitts D D;Neurock M;Davis R J .[J].SCIENCE,2010,330:74. |
| [13] | Villa A;Veith G M;Prati L .[J].Angew Chem Int Ed,2010,49:4499. |
| [14] | Villa, A.;Gaiassi, A.;Rossetti, I.;Bianchi, C.L.;Van Benthem, K.;Veith, G.M.;Prati, L. .Au on MgAl_2O_4 spinels: The effect of support surface properties in glycerol oxidation[J].Journal of Catalysis,2010(1):108-116. |
| [15] | Liang D;Gao J;Wang J H;Chen P Hou Z Y Zheng X M .[J].CATALYSIS COMMUNICATIONS,2009,10:1586. |
| [16] | 梁丹,崔世玉,高静,王军华,陈平,侯昭胤.常压下Pt-Bi双金属催化剂上甘油选择性氧化[J].催化学报,2011(12):1831-1837. |
| [17] | 张梦媛,梁丹,聂仁峰,吕秀阳,陈平,侯昭胤.非碱性条件下不同粒径的碳载体负载Pt催化剂上甘油的选择性氧化[J].催化学报,2012(08):1340-1346. |
| [18] | Chai S H;Wang H P;Liang Y;Xu B Q .[J].Green Chemistry,2007,9:1130. |
| [19] | Cavani F;Guidetti S;Marinelli L;Piccinini M Ghedini E Signoretto M .[J].Applied Catalysis B:Environmental,2010,100:197. |
| [20] | Wang, F.;Dubois, J.-L.;Ueda, W. .Catalytic dehydration of glycerol over vanadium phosphate oxides in the presence of molecular oxygen[J].Journal of Catalysis,2009(2):260-267. |
| [21] | Katryniok B;Paul S;Capron M;Lancelot C Bellière-Baca V Rey P Dumeignil F .[J].Green Chemistry,2010,12:1922. |
| [22] | 马兰,李宇明,贺德华.Ru-Re/SiO2催化剂上丙三醇氢解制丙二醇：催化剂的酸性质与Re组分的作用[J].催化学报,2011(05):872-876. |
| [23] | Ma L;He D H .[J].Catalysis Today,2010,149:148. |
| [24] | Miyazawa T;Koso S;Kunimori K;Tomishige K .Development of a Ru/C catalyst for glycerol hydrogenolysis in combination with an ion-exchange resin[J].Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications,2007(0):244-251. |
| [25] | Maris E P;Davis R J .[J].Journal of Catalysis,2007,249:328. |
| [26] | Oh J;Dash S;Lee H .[J].Green Chemistry,2011,13:2004. |
| [27] | Maris E P;Ketchie W C;Murayama M;Davis R J .[J].Journal of Catalysis,2007,251:281. |
| [28] | Daniel O M;DeLaRiva A;Kunkes E L;Datye A K Dumesic J A Davis R J .[J].ChemCatChem,2010,2:1107. |
| [29] | Amada Y;Shinmi Y;Koso S;Kubotac T Nakagawa Y Tomishige K .[J].Applied Catalysis B:Environmental,2011,105:117. |
| [30] | Zhou J;Zhang J;Guo X;Mao J Zhang S .[J].Green Chemistry,2012,14:156. |
| [31] | Xia S X;Nie R F;Lu X Y;Wang L N Chen P Hou Z Y .[J].Journal of Catalysis,2012,296:1. |
| [32] | Yuan Z L;Wu P;Gao J;Lu X Y Hou Z Y Zheng X M .[J].Catalysis Letters,2009,130:261. |
| [33] | Yuan Z L;Wang J H;Wang L N;Xie W H Chen P Hou Z Y Zheng XM .[J].Bioresource Technology,2010,101:7088. |
| [34] | Wu Z;Mao Y;Wang X;Zhang M .[J].Green Chemistry,2011,13:1311. |
| [35] | Bienholz A;Schwab F;Claus P .[J].Green Chemistry,2010,12:290. |
| [36] | Bienholz A;Blume R;Knop-Gericke A;Girgsdies F Behrens M Claus P .[J].J Phys Chem C,2011,115:999. |
| [37] | 郭小惠,李勇,刘琪英,申文杰.微波辅助的多元醇法合成CoNi纳米材料[J].催化学报,2012(04):645-650. |
| [38] | 胡基业,刘晓钰,王彬,裴燕,乔明华,范康年.制备方法对Ni/ZnO催化丙三醇重整-氢解性能的影响[J].催化学报,2012(08):1266-1275,前插1. |
| [39] | Xia S X;Yuan Z L;Wang L N;Chen P Hou Z Y .[J].Applied Catalysis A:General,2011,403:173. |
| [40] | Musolino M G;Scarpino L A;Mauriello F;Pietropaolo R .[J].ChemSusChem,2011,4:1143. |
| [41] | Labajos F M;Rives V;Ulibarri M A .[J].Journal of Materials Science,1992,27:1546. |
| [42] | Liang J;Ma R;Iyi N;Ebina Y Takada K Sasaki T .[J].CHEMISTRY OF MATERIALS,2010,22:371. |
| [43] | Xia S X;Yuan Z L;Wang L N;Chen P Hou Z Y .[J].Bioresource Technology,2012,104:814. |
| [44] | Li B D;Wang J;Yuan Y Z;Ariga H Takakusagi S Asakura K .[J].ACS Catal,2011,1:1521. |
| [45] | Genger T.;Hinrichsen,O. .The temperature-programmed desorption of hydrogen from copper surfaces[J].Catalysis Letters,1999(2/4):137-141. |
| [46] | Wilmer H.;Genger T.;Hinrichsen O. .The interaction of hydrogen with alumina-supported copper catalysts: a temperature-programmed adsorption/temperature-programmed desorption/isotopic exchange reaction study[J].Journal of Catalysis,2003(2):188-198. |
| [47] | Ahlers, JA;Grasser, JA;Loveless, BT;Muggli, DS .Room-temperature oxidation of reduced Cu/ZnO surfaces by lattice oxygen diffusion[J].Catalysis Letters,2007(3/4):185-191. |
| [48] | Arena F;Italiano G;Barbera K;Bordiga S Bonura G Spadaro L Frusteri F .[J].Applied Catalysis A:General,2008,350:16. |
| [49] | Bienholz A;Schwab F;Claus P .[J].Green Chemistry,2010,12:290. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%