合成气制混合醇双功能催化研究进展

催化学报 , 2013, 34(1): 116-129. doi: 10.1016/S1872-2067(11)60496-8

合成气制混合醇双功能催化研究进展

肖康 ^1, , 鲍正洪 ^2, , 齐行振 ^3, , 王新星 ^4, , 钟良枢 ^5, , 房克功 ^6, , 林明桂 ^7, , 孙予罕 ^8,

1.中国科学院上海高等研究院低碳能源转化技术与工程中心,上海201210;中国科学院大学,北京100049

2.中国科学院上海高等研究院低碳能源转化技术与工程中心,上海201210

3.中国科学院上海高等研究院低碳能源转化技术与工程中心,上海201210

4.中国科学院上海高等研究院低碳能源转化技术与工程中心,上海201210

5.中国科学院上海高等研究院低碳能源转化技术与工程中心,上海201210

6.中国科学院山西煤炭化学研究所煤转化国家重点实验室,山西太原030001

7.中国科学院山西煤炭化学研究所煤转化国家重点实验室,山西太原030001

8.中国科学院上海高等研究院低碳能源转化技术与工程中心,上海201210;中国科学院山西煤炭化学研究所煤转化国家重点实验室,山西太原030001

基金项目: 国家重点基础研究发展计划(973计划,2011CBA00501) 上海市科委(11DZ1200300) 煤转化国家重点实验室(11-12-610)

关键词：混合醇 , 一氧化碳加氢 , 合成气 , 双功能催化 , 双活性中心

Advances in bifunctional catalysis for higher alcohol synthesis from syngas

混合醇合成要求催化剂具备至少两类活性中心,一类用于解离吸附CO以生成烷基链,另一类用于非解离吸附CO以使烷基链含氧化生成醇.两类中心通过协同作用共同构成混合醇合成所需的双活性中心.简要综述了近年来合成气制混合醇过程中涉及的双功能催化研究进展,并以几类典型的催化剂体系为例,从双活性中心的构筑、典型的双活性中心结构、反应过程中双活中心结构的演变等方面进行了阐述.混合醇催化剂的研发应从纳米尺度上对催化剂进行设计,使催化剂表面具有足够多的双活性中心,并设法稳定催化剂的双活性中心结构.

参考文献

[1]	Wender I .[J].Fuel Processing Technology,1996,48:189.
[2]	Xu X D;Doesburg E B M;Scholten J J F .[J].Catalysis Today,1987,2:125.
[3]	Fang K G;Li D B;Lin M G;Xiang M L Wei W Sun Y H .[J].Catalysis Today,2009,147:133.
[4]	Surisetty V R;Dalai A K;Kozinski J .[J].Applied Catalysis A:General,2011,404:1.
[5]	Slaa J C;Vanommen J G;Ross J R H .[J].Catalysis Today,1992,15:129.
[6]	Zaman S;Smith K J .[J].Catalysis Review:Science and Engineering,2012,54:41.
[7]	Chuang S S C;Stevens R W;Khatri R .[J].Topics in Catalysis,2005,32:225.
[8]	Forzatti P;Tronconi E;Pasquon I .[J].Catalysis Review:Science and Engineering,1991,33:109.
[9]	Herman R G .[J].Catalysis Today,2000,55:233.
[10]	Spivey J J;Egbebi A .[J].Chemical Society Reviews,2007,36:1514.
[11]	Hindermann J P;Hutchings G J;Kiennemann A .[J].Catalysis Review:Science and Engineering,1993,35:1.
[12]	Subramanian N D;Balaji G;Kumar C S S R;Spivey J J .[J].Catalysis Today,2009,147:100.
[13]	Smith M L;Kumar N;Spivey J J .[J].Journal of Physical Chemistry C,2012,116:7931.
[14]	Kumar N;Jothimurugesan K;Stanley G G;Schwartz V Spivey J J .[J].Journal of Physical Chemistry C,2011,115:990.
[15]	Kumar, N.;Smith, M.L.;Spivey, J.J..Characterization and testing of silica-supported cobalt-palladium catalysts for conversion of syngas to oxygenates[J].Journal of Catalysis,2012:218-226.
[16]	Mo X;Tsai Y-T;Gao J;Mao D Goodwin J G Jr .[J].Journal of Catalysis,2012,285:208.
[17]	Tsai Y-T;Mo X;Goodwin J G Jr .[J].Journal of Catalysis,2012,285:242.
[18]	Haider MA;Gogate MR;Davis RJ .Fe-promotion of supported Rh catalysts for direct conversion of syngas to ethanol[J].Journal of Catalysis,2009(1):9-16.
[19]	Gogate M R;Davis R J .[J].ChemCatChem,2009,1:295.
[20]	Shou H;Ferrari D;Barton D G;Jones C W Davis R J .[J].ACS Catal,2012,2:1408.
[21]	Shou, H.;Davis, R.J. .Reactivity and in situ X-ray absorption spectroscopy of Rb-promoted Mo _2C/MgO catalysts for higher alcohol synthesis[J].Journal of Catalysis,2011(1):83-93.
[22]	Zaman S F;Smith K J .[J].Catalysis Today,2011,171:266.
[23]	Zaman S F;Smith K J .[J].Applied Catalysis A:General,2010,378:59.
[24]	Zaman S F;Smith K J .[J].Catalysis Communications,2009,10:468.
[25]	Dong X;Liang X L;Li H Y;Lin G D Zhang P Zhang H B .[J].Catalysis Today,2009,147:158.
[26]	Zhang H B;Dong X;Lin G D;Liang X L,Li H Y.[J].Chemical Communications,2005:5094.
[27]	Ma C H;Li H Y;Lin G D;Zhang H B .[J].Catalysis Letters,2010,137:171.
[28]	Ma C H;Li H Y;Lin G D;Zhang H B .[J].Applied Catalysis B:Environmental,2010,100:245.
[29]	Wu XM;Guo YY;Zhou JM;Lin GD;Dong X;Zhang HB .Co-decorated carbon nanotubes as a promoter of Co-Mo-K oxide catalyst for synthesis of higher alcohols from syngas[J].Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications,2008(1):87-97.
[30]	马晓明,林国栋,张鸿斌.碳纳米管促进的Co-Mo-K硫化物基催化剂用于合成气制低碳混合醇[J].催化学报,2006(11):1019-1027.
[31]	Ma X M;Lin G D;Zhang H B .[J].Catalysis Letters,2006,111:141.
[32]	Zhang H B;Liang X L;Dong X;Li H Y Lin G D .[J].Catalysis Surveys From Asia,2009,13:41.
[33]	Pan X L;Fan Z L;Chen W;Ding Y J Luo H Y Bao X H .[J].Nature Materials,2007,6:507.
[34]	Yu L;Li W X;Pan X L;Bao X H .[J].Journal of Physical Chemistry C,2012,116:16461.
[35]	徐慧远,储伟,邓思玉.射频等离子体技术制备合成低碳醇用新型Cu-Co/SiO_2催化剂[J].物理化学学报,2010(02):345-349.
[36]	Zhang H;Chu W;Xu H Y;Zhou J .[J].Fuel,2010,89:3127.
[37]	Xu H Y;Chu W;Shi L M;Deng S Y Zhang H .[J].Reaction Kinetics and Catalysis Letters,2009,97:243.
[38]	徐慧远,储伟,士丽敏,张辉,周俊.射频等离子体技术制备合成低碳醇用铜钴基催化剂[J].物理化学学报,2008(06):1085-1089.
[39]	Jiao G P;Ding Y J;Zhu H J;Li X M Li J W Lin R H Dong W D Gong L F Pei Y P Lü Y .[J].Applied Catalysis A:General,2009,364:137.
[40]	焦桂萍,丁云杰,朱何俊,李显明,董文达,李经伟,吕元.还原温度对Co-La-Zr/AC催化剂合成气制高碳混合醇性能的影响[J].催化学报,2009(02):92-94.
[41]	焦桂萍,丁云杰,朱何俊,李显明,李经伟,董文达,裴彦鹏.活性炭负载钴基催化剂上合成气制混合醇[J].催化学报,2009(08):825-829.
[42]	毛东森,郭强胜,俞俊,韩璐蓬,卢冠忠.Ce添加对Cu-Fe/SiO2催化合成气制低碳醇性能的影响[J].物理化学学报,2011(11):2639-2645.
[43]	Han L P;Mao D S;Yu J;Guo Q Sh Lu G Zh .[J].Catalysis Communications,2012,23:20.
[44]	Yu J;Mao D S;Lu G Zh;Guo Q S Han L P .[J].Catalysis Communications,2012,24:25.
[45]	Ding M Y;Qiu M H;Wang T J;Ma L L,Wu C Z,Liu J G .[J].Applied Energy,2012,97:543.
[46]	刘建国,定明月,王铁军,马隆龙.Cu-Fe基双孔载体催化剂结构和低碳醇合成反应性能[J].物理化学学报,2012(08):1964-1970.
[47]	朱秋锋,张荣俊,贺德华.CaO改性对CuZnAlZr催化剂在合成气制低碳醇中性能的影响[J].物理化学学报,2012(06):1461-1466.
[48]	Geerlings J J C;Wilson J H;Kramer G J;Kuipers H P C E Hoek A Huisman H M .[J].Applied Catalysis A:General,1999,186:27.
[49]	Dry M E .[J].Catalysis Today,2002,71:227.
[50]	Liu X M;Lu G Q;Yan Z F;Beltramini J .[J].Industrial and Engineering Chemistry Research,2003,42:6518.
[51]	Kiennemann A;Barama A;Boujana S;Bettahar M M .[J].Applied Catalysis A:General,1993,99:175.
[52]	Xu R;Wei W;Dong Q N;Sun Y H .[J].Spectroscopy and Spectral Analysis,2003,23:1093.
[53]	Xu R;Ma Z Y;Yang C;Wei W Li W H Sun Y H .[J].Journal of Molecular Catalysis A:Chemical,2004,218:133.
[54]	Xu R;Ma Z Y;Yang C;Wei W Sun Y H .[J].Reaction Kinetics and Catalysis Letters,2004,81:91.
[55]	Xu R;Yang C;Wei W;Li W H Sun Y H Hu T D .[J].Journal of Molecular Catalysis A:Chemical,2004,221:51.
[56]	Xu R;Wei W;Li WH;Hu TD;Sun YH .Fe modified CuMnZrO2 catalysts for higher alcohols synthesis from syngas: Effect of calcination temperature[J].Journal of molecular catalysis, A. Chemical,2005(1/2):75-83.
[57]	Lin M G;Fang K G;Li D B;Sun Y H .[J].Catalysis Communications,2008,9:1869.
[58]	Gupta M;Smith M L;Spivey J J .[J].ACS Catal,2011,1:641.
[59]	Xiao K;Bao Z;Qi X;Wang X,Zhong L,Lin M,Fang K,Sun Y .[J].Prepr Pap-Am Chem Soc Div Energy Fuels Chem,2012,572:928.
[60]	Blanchard M;Derule H;Canesson P .[J].Catalysis Letters,1989,2:319.
[61]	Baker J E;Burch R;Hibble S J;Loader P K .[J].Applied Catalysis,1990,65:281.
[62]	Fujimoto K;Oba T .[J].Applied Catalysis,1985,13:289.
[63]	Matsuzaki T;Hanaoka T-A;Takeuchi K;Arakawa H Sugi Y Wei K Dong T Reinikainen M .[J].Catalysis Today,1997,36:311.
[64]	Chaumette P;Courty P;Kiennemann A;Kieffer R Boujana S Martin G A Dalmon J A Meriaudeau P Mirodatos C Holhein B Mausbeck D Hubert A J Germain A Noels A .[J].Industrial and Engineering Chemistry Research,1994,33:1460.
[65]	Hwu H H;Chen J G G .[J].Chemical Reviews,2005,105:185.
[66]	Zhang Y;Sun Y H;Zhong B .[J].Catalysis Letters,2001,76:249.
[67]	Xiang M L;Li D B;Li W H;Zhong B Sun Y H .[J].Fuel,2006,85:2662.
[68]	Xiang M L;Li D B;Qi H J;Li W H Zhong B Sun Y H .[J].Fuel,2007,86:1298.
[69]	Xiang M L;Li D B;Xiao H C;Hanli Z L Qi H J Li W H Zhong B Sun Y H .[J].Fuel,2008,87:599.
[70]	Xiang M L;Li D B;Xiao H C;Zhang J L Li W H Zhong B Sun Y H .[J].Catalysis Today,2008,131:489.
[71]	Wang N;Fang K G;Jiang D;Li D B Sun Y H .[J].Catalysis Today,2010,158:241.
[72]	Zhao L H;Fang K G;Jiang D;Li D B Sun Y H .[J].Catalysis Today,2010,158:490.
[73]	Woo H C;Park K Y;Kim Y G;Nam i S Chung J S Lee J S .[J].Applied Catalysis,1991,75:267.
[74]	Li ZR.;Jiang M.;Meng M.;Xie YN.;Hu TD.;Liu T.;Fu YL. .Structures and performance of Pd-Mo-K/Al2O3 catalysts used for mixed alcohol synthesis from synthesis gas[J].Catalysis Letters,2000(1/3):43-48.
[75]	Shi X R;Jiao H J;Hermann K;Wang J G .[J].J Mol CatalA,2009,312:7.
[76]	Surisetty V R;Dalai A K;Kozinski J .[J].Applied Catalysis A:General,2010,385:153.
[77]	Surisetty V R;Dalai A K;Kozinski J .[J].Applied Catalysis A:General,2010,381:282.
[78]	Andersson R;Boutonnet M;J(a)r(a)s S .[J].Applied Catalysis A:General,2012,417-418:119.
[79]	Li D B;Yang C;Qi H J;Zhang H R Li W H Sun Y H Zhong B .[J].Catalysis Communications,2004,5:605.
[80]	Li D B;Yang C;Li W H;Sun Y H Zhong B .[J].Topics in Catalysis,2005,32:233.
[81]	李德宝,齐会杰,李文怀,孙予罕,钟炳.Ni/K2CO3/MoS2低碳醇催化剂的表面结构和电子效应[J].物理化学学报,2006(09):1132-1136.
[82]	Li D B;Yang C;Zhao N;Qi H J Li W H Sun Y H Zhong B .[J].Fuel Processing Technology,2007,88:125.
[83]	Xiao H C;Li D B;Li W H;Sun Y H .[J].Fuel Processing Technology,2010,91:383.
[84]	Li Z R;Fu Y L;Bao J;Jiang M Hu T Liu T Xie Y N .[J].Applied Catalysis A:General,2001,220:21.
[85]	Ogawa Y;Toba M;Yoshimura Y .[J].Applied Catalysis A:General,2003,246:213.
[86]	李德宝 .[D].太原:中国科学院山西煤炭化学研究所,2004.

上一张下一张

计量

下载量()
访问量()

作者相关

文章评分

您的评分：
1

0%
2

0%
3

0%
4

0%
5

0%

材料期刊网