Indium incorporated silica samples with different indium contents were synthesized using a template free sol-gel method. The silica used was extracted from rice husk (RH) and the resulting catalyst was labeled as RH-xIn (x=5%,10%,15%, and 20%). From the N2 adsorption analysis the presence of type IV isotherm in RH-blank and RH-xIn indicated the mesoporous nature of the catalysts. In the XRD pattern, a broad band at ca.2θ=25° was observed for all the catalysts which showed them to be amorphous. TEM micrographs revealed that the material is composed of nanoparticles. Friedel-Craft benzoylation of toluene was carried out using the RH-xIn catalyst. The optimum conditions for the benzoylation of toluene were determined and at 373 K,100%conversion and 89%selectivity for the para-product (i.e.4-methylbenzophenone) were obtained.
参考文献
[1] | Liou T H;Yang C C .[J].Materials Science and Engineering B,2011,176:521. |
[2] | Kim K D;Kim H T .[J].Journal of Sol-Gel Science and Technology,2002,25:183. |
[3] | Markowitz M A;Schoen P E;Kust P;Gaber B P .[J].Colloid Sur-face A,1999,150:85. |
[4] | Nassar E J;Nassor E C De O;ávila L R;Pereira P F S Cestari A Luz L M Ciuffi K J Calefi P S .[J].Journal of Sol-Gel Science and Technology,2007,43:21. |
[5] | Baccile N;Babonneau F;Thomas B .[J].Journal of Materials Chemistry,2009,19:8537. |
[6] | Moleski R;Leontidis E;Krumeich F .Controlled production of ZnO nanoparticles from zinc glycerolate in a sol-gel silica matrix[J].Journal of Colloid and Interface Science,2006(1):246-253. |
[7] | Chiarakorn S;Areerob T;Grisdanurak N .[J].Science and Technology of Advanced Materials,2007,8:110. |
[8] | Ahmed A E;Adam F .[J].Microporous and Mesoporous Materials,2007,103:284. |
[9] | Amutha K;Ravibaskar R;Sivakumar G .[J].Int J Technol Appl,2010,4:61. |
[10] | Adam F;Chew T S;Andas J .[J].Journal of Sol-Gel Science and Technology,2011,59:580. |
[11] | Dimitriev Y;Ivanova Y;Iordanova R .[J].J Univ Chem Technol Metallurgy,2008,43:181. |
[12] | Singh A P;Bhattacharya D;Sharma S .[J].Journal of Molecular Catalysis A:Chemical,1995,102:139. |
[13] | Gawande M B;Deshpande S S;Sonavane S U;Jayaram R V .[J].Journal of Molecular Catalysis A:Chemical,2005,241:151. |
[14] | Laidlawa P;Bethell P D;Brown S M;Hutchings G J .[J].Journal of Molecular Catalysis A:Chemical,2001,174:187. |
[15] | Arata K;Nakamura H;Shouji M .[J].Applied Catalysis A:General,2000,197:213. |
[16] | Choudhary VR.;Jana SK.;Narkhede VS. .Benzylation and benzoylation of substituted benzenes over solid catalysts containing Ga- and Mg-oxides and/or chlorides derived from Ga-Mg-hydrotalcite by its HCl pre-treatment or calcination[J].Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications,2002(1/2):207-215. |
[17] | Nguyen L T L;Le K K A;Phan N T S .[J].Chinese Journal of Catalysis,2012,33:688. |
[18] | Bordoloi A;Mathew N T;Devassy B M;Mirajkar S P Halligudi S B .[J].Journal of Molecular Catalysis A:Chemical,2006,247:58. |
[19] | Liu E;Locke A J;Frost R L;Martens W N .[J].Journal of Molecular Catalysis A:Chemical,2012,353-354:95. |
[20] | Choudhary VR;Jha R .GaClx- or GaAlClx-grafted Si-MCM-41: Highly active and moisture insensitive/stable catalyst for the acylation and benzylation of benzene, naphthalene and substituted benzenes[J].Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications,2007(1):42-48. |
[21] | Choudhary V R;Jana S K .[J].Journal of Molecular Catalysis A:Chemical,2002,184:247. |
[22] | Jang DO;Moon KS;Cho DH;Kim JG .Highly selective catalytic Friedel-Crafts acylation and sulfonylation of activated aromatic compounds using indium metal[J].Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry,2006(34):6063-6066. |
[23] | Wildermann A;Foricher Y;Netscher Y T;Bonrath W .[J].Pure and Applied Chemistry,2007,79(11):1839. |
[24] | Miyai T;Onishi Y;Baba A .[J].Tetrahedron,1999,55:1017. |
[25] | Miyai T;Onishi Y;Baba A .[J].Tetrahedron Letters,1998,39:6291. |
[26] | Xia Y;Dai H;Jiang H;Zhang L Deng J Liu Y .[J].J Hazard Ma-ter,2011,186:84. |
[27] | Chang S S;Clair B;Ruelle J;Beauchéne J FRenzo F D Quignard F Zhao G J Yamamoto H Gril J .[J].Journal of Experimental Botany,2009,60(11):3023. |
[28] | Vinu, A;Krithiga, T;Gokulakrishnan, N;Srinivasu, P;Anandan, S;Ariga, K;Murugesan, V;Balasubramanian, VV;Mori, T .Halogen-free acylation of toluene over FeSBA-1 molecular sieves[J].Microporous and Mesoporous Materials,2007(1/3):87-94. |
[29] | Waghmare AA;Bose P;Pati H N .[J].Pharma Chem,2010,2:212. |
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