A series of graphene-TiO2 composites was fabricated from graphene oxide and titanium n-butoxide (TNB) by an ultrasonic-assisted method.The structure and composition of the nanocomposites were characterized by Raman spectroscopy,BET surface area measurements,X-ray diffraction,transmission electron microscopy,and ultraviolet-visible absorption spectroscopy.The average size of the TiO2 nanoparticles on the graphene nanosheets was controlled at around 10-15 nm without using surfactant,which is attributed to the pyrolysis and condensation of dissolved TNB into TiO2 by ultrasonic irradiation.The catalytic activity of the composites under ultrasonic irradiation was determined using a rhodamine B (RhB) solution.The graphene-TiO2 composites possessed a high specific surface area,which increased the decolorization rate for RhB solution.This is because the graphene and TiO2 nanoparticles in the composites interact strongly,which enhances the photoelectric conversion of TiO2 by reducing the recombination ofphotogenerated electron-hole pairs.
参考文献
[1] | Chen X;Mao S S .[J].Chemical Reviews,2007,107:2891. |
[2] | Burda C;Chen X;Narayanan R;El-Sayed M A .[J].Chemical Reviews,2005,105:1025. |
[3] | Li G;Liu C;Liu Y .[J].ApplSurfSci,2006,253:2481. |
[4] | Kumar A;Jain A K .[J].JMol CatalA,2001,165:265. |
[5] | Oh W C;Zhang F J;Chen M L .[J].Journal of Industrial and Engineering Chemistry,2010,16:299. |
[6] | Hoffmann M R;Martin S T;Choi W;Bahnemann D W .[J].Chemical Reviews,1995,95:69. |
[7] | Wang W D;Serp P;Kalck P;Faria J L .[J].Journal of Molecular Catalysis A:Chemical,2005,235:194. |
[8] | Woan K;Pyrgiotakis G;Sigmund W .[J].Advanced Materials,2009,21:2233. |
[9] | Geim AK;Novoselov KS .The rise of graphene[J].Nature materials,2007(3):183-191. |
[10] | Gilje S;Han S;Wang M;Wang K L Kaner R B .[J].Nano Letters,2007,7:3394. |
[11] | Pasricha, R;Gupta, S;Srivastava, AK .A Facile and Novel Synthesis of Ag-Graphene-Based Nanocomposites[J].Small,2009(20):2253-2259. |
[12] | Robinson JT;Perkins FK;Snow ES;Wei ZQ;Sheehan PE .Reduced Graphene Oxide Molecular Sensors[J].Nano letters,2008(10):3137-3140. |
[13] | Arsat, R;Breedon, M;Shafiei, M;Spizziri, PG;Gilje, S;Kaner, RB;Kalantar-Zadeh, K;Wlodarski, W .Graphene-like nano-sheets for surface acoustic wave gas sensor applications[J].Chemical Physics Letters,2009(4/6):344-347. |
[14] | Stankovich S;Dikin DA;Dommett GHB;Kohlhaas KM;Zimney EJ;Stach EA;Piner RD;Nguyen ST;Ruoff RS .Graphene-based composite materials[J].Nature,2006(7100):282-286. |
[15] | Seger B;Kamat P V .[J].JPhys Chem C,2009,113:7990. |
[16] | Akhavan O;Ghaderi E;Esfandiar A .[J].Journal of Physical Chemistry B,2011,115:6279. |
[17] | Liang Y Y;Wang H L;Casalongue H S;Chen Z Dai H J .[J].Nano Res,2010,3:701. |
[18] | Williams G;Seger B;Kamat PV .[J].ACSNano,2008,2:1487. |
[19] | Wang D H;Choi D W;Li J;Yang Z G Nie Z M Kou R Hu D H Wang C M Saraf L V Zhang J G Aksay I A Liu J .[J].ACS Nano,2009,3:907. |
[20] | Chen, C.;Cai, W.;Long, M.;Zhou, B.;Wu, Y.;Wu, D.;Feng, Y. .Synthesis of visible-light responsive graphene oxide/TiO_2 composites with p/n heterojunction[J].ACS nano,2010(11):6425-6432. |
[21] | Zhang, H.;Lv, X.;Li, Y.;Wang, Y.;Li, J. .P25-graphene composite as a high performance photocatalyst[J].ACS nano,2010(1):380-386. |
[22] | Zhang Y H;Tang Z R;Fu X Z;Xu Y J .[J].ACS Nano,2010,4:7303. |
[23] | Nakui H;Okitsu K;Maeda Y;Nishimura R .[J].Journal of Hazardous Materials,2007,146:636. |
[24] | Abdullah AZ;Ling PY .[J].Journal of Hazardous Materials,2010,173:159. |
[25] | Wang J;Sun W;Zhang ZH;Jiang Z;Wang XF;Xu R;Li RH;Zhang XD .Preparation of Fe-doped mixed crystal TiO2 catalyst and investigation of its sonocatalytic activity during degradation of azo fuchsine under ultrasonic irradiation[J].Journal of Colloid and Interface Science,2008(1):202-209. |
[26] | Wang J;Lv Y H;Zhang Z H;Deng Y Q Zhang L Q Liu B Xu R Zhang X D .[J].Journal of Hazardous Materials,2009,170:398. |
[27] | Wang J;Sun W;Zhang ZH;Xing ZQ;Xu R;Li RH;Li Y;Zhang XD .Treatment of nano-sized rutile phase TiO2 powder under ultrasonic irradiation in hydrogen peroxide solution and investigation of its sonocatalytic activity[J].Ultrasonics sonochemistry,2008(4):301-307. |
[28] | Kubo M;Matsuoka K;Takahashi A;Shibasaki-Kitakawa N;Yonemoto T .Kinetics of ultrasonic degradation of phenol in the presence of TiO2 particles[J].Ultrasonics sonochemistry,2005(4):263-269. |
[29] | Wang, J;Jiang, Z;Zhang, LQ;Kang, PL;Xie, YP;Lv, YH;Xu, R;Zhang, XD .Sonocatalytic degradation of some dyestuffs and comparison of catalytic activities of nano-sized TiO2, nano-sized ZnO and composite TiO2/ZnO powders under ultrasonic irradiation[J].Ultrasonics sonochemistry,2009(2):225-231. |
[30] | Neppolian, B.;Bruno, A.;Bianchi, C.L.;Ashokkumar, M. .Graphene oxide based Pt-TiO_2 photocatalyst: Ultrasound assisted synthesis, characterization and catalytic efficiency[J].Ultrasonics sonochemistry,2012(1):9-15. |
[31] | Guo J J;Zhu S M;Chen Z X;Li Y Yu Z Y Liu Q L Li J B Feng C L Zhang D .[J].Ultrasonics Sonochemistry,2011,18:1082. |
[32] | Hummers W S;Offeman R E .[J].Journal of the American Chemical Society,1958,80:1339. |
[33] | Oh W C;Chen M L;Zhang K;Zhang F J Jang W K Zhang F J .[J].Journal of the Korean Physical Society,2010,56:1097. |
[34] | Graf D;Molitor F;Ensslin K;Stampfer C;Jungen A;Hierold C;Wirtz L .Spatially resolved raman spectroscopy of single- and few-layer graphene[J].Nano letters,2007(2):238-242. |
[35] | Dresselhaus, MS;Jorio, A;Hofmann, M;Dresselhaus, G;Saito, R .Perspectives on Carbon Nanotubes and Graphene Raman Spectroscopy[J].Nano letters,2010(3):751-758. |
[36] | Zhang W X;Cui J C;Tao C A;Wu Y G,Li Z P.Ma L,Wen Y Q,Li G T .[J].Angewandte Chemie International Edition,2009,48:5864. |
[37] | Lu, J.;Yang, J.-X.;Wang, J.;Lim, A.;Wang, S.;Loh, K.P. .One-pot synthesis of fluorescent carbon nanoribbons, nanoparticles, and graphene by the exfoliation of graphite in ionic liquids[J].ACS nano,2009(8):2367-2375. |
[38] | Akhavan, O. .Graphene nanomesh by ZnO nanorod photocatalysts[J].ACS nano,2010(7):4174-4180. |
[39] | Lambert T N;Chavez C A;Hernandez-Sanchez B;Lu P Bell N S Ambrosini A Friedman T Boyle T J Wheeler D R Huber D L .[J].JPhys Chem C,2009,113:19812. |
[40] | Stankovich S;Dikin D A;Piner R D;Kohlhaas KA Kleinhammes A Jia Y Wu Y Nguyen S T RuoffR S .[J].Carbon,2007,45:1558. |
[41] | Qourzal S;Barka N;Tamimi M;Assabbane A Nounah A Ihlal A Ait-Ichou Y .[J].Materials Science and Engineering C:Biomimetic and Supramolecular Systems,2009,29:1616. |
[42] | Gotoh K;Kinumoto T;Fujii E;Yamamoto A Hashimoto H Ohkubo T Itsudani A Kuroda Y Ishida H .[J].Carbon,2011,49:1118. |
[43] | Zhang X Y;Li H P;Cui X L;Lin Y H .[J].Journal of Materials Chemistry,2010,20:2801. |
[44] | Zhang, H.;Lv, X.;Li, Y.;Wang, Y.;Li, J. .P25-graphene composite as a high performance photocatalyst[J].ACS nano,2010(1):380-386. |
[45] | Bourlinos AB.;Gournis D.;Petridis D.;Szabo T.;Szeri A.;Dekany I. .Graphite oxide: Chemical reduction to graphite and surface modification with primary aliphatic amines and amino acids[J].Langmuir: The ACS Journal of Surfaces and Colloids,2003(15):6050-6055. |
[46] | Zhu L;Meng Z D;Oh W C .[J].Chinese Journal of Catalysis,2011,32:926. |
[47] | Chen M L;Zhang F J;Oh W C .[J].New Carbon Materials,2009,24:159. |
[48] | Stankovich S;Piner R D;Chen X Q;Wu N Q Nguyen S T RuoffR S .[J].Journal of Materials Chemistry,2006,16:155. |
[49] | Okitsu K;Iwasaki K;Yobiko Y;Bandow H;Nishimura R;Maeda Y .Sonochemical degradation of azo dyes in aqueous solution: a new heterogeneous kinetics model taking into account the local concentration of OH radicals and azo dyes[J].Ultrasonics sonochemistry,2005(4):255-262. |
[50] | Shimizu N;Ogino C;Dadjour MF;Murata T .Sonocatalytic degradation of methylene blue with TiO2 pellets in water[J].Ultrasonics sonochemistry,2007(2):184-190. |
[51] | Zhang K;Oh W C .[J].Bulletin of the Korean Chemical Society,2010,31:1589. |
[52] | Saien J;Delavari H;Solymani A R .[J].Journal of Hazardous Materials,2010,177:1031. |
[53] | Wang N;Zhu L H;Wang M Q;Wang D L Tang H Q .[J].Ultrasonics Sonochemistry,2010,17:78. |
[54] | Zhang XW;Zhou MH;Lei L .Preparation of photocatalytic TiO2 coatings of nanosized particles on activated carbon by AP-MOCVD[J].Carbon: An International Journal Sponsored by the American Carbon Society,2005(8):1700-1708. |
[55] | Liu Z;Robinson JT;Sun XM;Dai HJ .PEGylated nanographene oxide for delivery of water-insoluble cancer drugs[J].Journal of the American Chemical Society,2008(33):10876-10877. |
[56] | Lightcap, IV;Kosel, TH;Kamat, PV .Anchoring Semiconductor and Metal Nanoparticles on a Two-Dimensional Catalyst Mat. Storing and Shuttling Electrons with Reduced Graphene Oxide[J].Nano letters,2010(2):577-583. |
[57] | Akhavan O;Ghaderi E .[J].JPhys Chem C,2009,113:20214. |
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