Development of Ni-Based Catalysts for Steam Reforming of Tar Derived from Biomass Pyrolysis

催化学报 , 2012, 33(4): 583-594. doi: 10.1016/S1872-2067(11)60359-8

Development of Ni-Based Catalysts for Steam Reforming of Tar Derived from Biomass Pyrolysis

^1, , ^2, , ^3,

1.Department of Applied Chemistry, School of Engineering, Tohoku University, Sendai 980-8579, Japan;National Engineering Research Center of Chemical Fertilizer Catalyst, Fuzhou University, Fuzhou 350002, Fufian, China

2.Department of Applied Chemistry, School of Engineering, Tohoku University, Sendai 980-8579, Japan

3.Department of Applied Chemistry, School of Engineering, Tohoku University, Sendai 980-8579, Japan

基金项目: Japan Science and Technology Agency (JST),Ministry of Education,Culture,Sports,Science and Technology,Japan

Development of Ni-Based Catalysts for Steam Reforming of Tar Derived from Biomass Pyrolysis

Dalin LI ^1, , Yoshinao NAKAGAWA ^2, , Keiichi TOMISHIGE ^3,

1.Department of Applied Chemistry, School of Engineering, Tohoku University, Sendai 980-8579, Japan;National Engineering Research Center of Chemical Fertilizer Catalyst, Fuzhou University, Fuzhou 350002, Fufian, China

2.Department of Applied Chemistry, School of Engineering, Tohoku University, Sendai 980-8579, Japan

3.Department of Applied Chemistry, School of Engineering, Tohoku University, Sendai 980-8579, Japan

Keywords： steam reforming

Nickel catalysts are effective for the steam reforming of tar derived from biomass pyrolysis,but the improvement is needed in terms of activity,stability,suppression of coke deposition and aggregation,and regeneration.Our recent development of Ni-based catalysts for the steam reforming of tar is reviewed including the modification with CeO2 (or MnO),trace Pt,and MgO.The role of additives such as CeO2,MnO,Pt,and MgO is also discussed.

参考文献

[1]	McKendry P. .Energy production from biomass (part 3): gasification technologies [Review][J].Bioresource Technology: Biomass, Bioenergy, Biowastes, Conversion Technologies, Biotransformations, Production Technologies,2002(1):55-63.
[2]	Huber G W;Iborra S;Corma A .[J].Chemical Reviews,2006,106:4044.
[3]	Wang LJ;Weller CL;Jones DD;Hanna MA .Contemporary issues in thermal gasification of biomass and its application to electricity and fuel production.[J].Biomass & Bioenergy,2008(7):573-581.
[4]	De Lasa, H.;Salaices, E.;Mazumder, J.;Lucky, R. .Catalytic steam gasification of biomass: Catalysts, thermodynamics and kinetics[J].Chemical Reviews,2011(9):5404-5433.
[5]	Baker E G;Mudge L K;Brown M D .[J].Ind Eng Chem Re s,1987,26:1335.
[6]	Aznar M P;Corella J;Delgado J;Lahoz J .[J].Industrial and Engineering Chemistry Research,1993,32:1.
[7]	Aznar M P;Caballero M A;Gil J;Martin J A Corella J .[J].Industrial and Engineering Chemistry Research,1998,37:2668.
[8]	Marquevich M;Czernik S;Chomet E;Montané D .[J].Energy and Fuels,1999,13:1160.
[9]	Czemik S;French R;Feik C;Chomet E .[J].Industrial and Engineering Chemistry Research,2002,41:4209.
[10]	Bangala D N;Abatzoglou N;Martin J P;Chornet E .[J].Industrial and Engineering Chemistry Research,1997,36:4184.
[11]	Li J F;Liu J J;Liao S Y;Yan R .[J].International Journal of Hydrogen Energy,2010,35:7399.
[12]	Li, JF;Xiao, B;Yan, R;Xu, XR .Development of a supported tri-metallic catalyst and evaluation of the catalytic activity in biomass steam gasification[J].Bioresource Technology: Biomass, Bioenergy, Biowastes, Conversion Technologies, Biotransformations, Production Technologies,2009(21):5295-5300.
[13]	Wang T J;Chang J;Cui X Q;Zhang Q Fu Y .[J].Fuel Processing Technology,2006,87:421.
[14]	Le D D;Xiao X B;Morishita K;Takarada T .[J].Journal of Chemical Engineering of Japan,2009,42:51.
[15]	Xiao X B;Meng X L;Le D D;Takarada T .[J].Bioresource Technology,2011,102:1975.
[16]	Wang D;Yuan W Q;Ji W .[J].Applied Energy,2011,88:1656.
[17]	Corujo, A.;Yerman, L.;Arizaga, B.;Brusoni, M.;Castiglioni, J. .Improved yield parameters in catalytic steam gasification of forestry residue; optimizing biomass feed rate and catalyst type.[J].Biomass & Bioenergy,2010(12):1695-1702.
[18]	Asadullah M;Ito S-I;Kunimori K;Yamada M Tomishige K .[J].Journal of Catalysis,2002,208:255.
[19]	Asadullah M;Miyazawa T;Ito S-I;Kunimori K Yamada M Tomishige K .[J].Applied Catalysis A:General,2003,255:169.
[20]	Asadullah M;Miyazawa T;Ito S-I;Kunimori K Yamada M Tomishige K .[J].Applied Catalysis A:General,2004,267:95.
[21]	Asadullah M;Fujimoto K;Tomishige K .[J].Industrial and Engineering Chemistry Research,2001,40:5894.
[22]	Asadullah M;Ito S-I;Kunimori K;Yamada M Tomishige K .[J].Environmental Science and Technology,2002,36:4476.
[23]	Asadullah M.;Miyazawa T.;Ito S.;Kunimori K.;Tomishige K. .Demonstration of real biomass gasification drastically promoted by effective catalyst[J].Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications,2003(1):103-116.
[24]	Tomishige K;Asadullah M;Kunimori K .[J].Catalysis Today,2004,89:389.
[25]	Asadullah M;Miyazawa T;Ito S;Kunimori K;Koyama S;Tomishige K .A comparison of Rh/CeO2/SiO2 catalysts with steam reforming catalysts, dolomite and inert materials as bed materials in low throughput fluidized bed gasification systems[J].Biomass & Bioenergy,2004(3):269-279.
[26]	Miyazawa T;Kimura T;Nishikawa J;Kado S Kunimori K Tomishige K .[J].Catalysis Today,2006,115:254.
[27]	Tomishige K;Kimura T;Nishikawa J;Miyazawa T Kunimori K .[J].Catalysis Communications,2007,8:1074.
[28]	Kimura T;Miyazawa T;Nishikawa J;Kado S;Okumura K;Miyao T;Naito S;Kunimori K;Tomishige K .Development of Ni catalysts for tar removal by steam gasification of biomass[J].Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications,2006(3/4):160-170.
[29]	Nishikawa J;Miyazawa T;Nakamura K;Asadullah M Kunimori K Tomishige K .[J].Catalysis Communications,2008,9:195.
[30]	Nishikawa J;Nakamura K;Asadullah M;Miyazawa T Kunimori K Tomishige K .[J].Catalysis Today,2008,131:146.
[31]	Nakamura K;Miyazawa T;Sakurai T;Miyao T Naito S Begum N Kunimori K Tomishige K .[J].Applied Catalysis B:Environmental,2009,86:36.
[32]	Koike M;Ishikawa C;Li D L;Wang L,Nakagawa Y,Tomishige K.Fuel .[Z].
[33]	Wang L;Li D L;Koike M;Koso S Nakagawa Y Xu Y Tomishige K .[J].Applied Catalysis A:General,2011,392:248.
[34]	Li D L;Wang L;Koike M;Nakagawa Y Tomishige K .[J].Applied Catalysis B:Environmental,2011,102:528.
[35]	Tanaka H;Kaino R;Okumura K;Kizuka T Nakagawa Y Tomishige K .[J].Applied Catalysis A:General,2010,378:175.
[36]	Tanaka H;Kaino R;Nakagawa Y;Tomishige K .[J].Applied Catalysis A:General,2010,378:187.
[37]	Naito S;Tanaka H;Kado S;Miyao T;Naito S;Okumura K;Kunimori K;Tomishige K .Promoting effect of Co addition on the catalytic partial oxidation of methane at short contact time over a Rh/MgO catalyst[J].Journal of Catalysis,2008(1):138-146.
[38]	Koso, S;Furikado, I;Shimao, A;Miyazawa, T;Kunimori, K;Tomishige, K .Chemoselective hydrogenolysis of tetrahydrofurfuryl alcohol to 1,5-pentanediol[J].Chemical communications,2009(15):2035-2037.
[39]	Koso, S.;Ueda, N.;Shinmi, Y.;Okumura, K.;Kizuka, T.;Tomishige, K. .Promoting effect of Mo on the hydrogenolysis of tetrahydrofurfuryl alcohol to 1,5-pentanediol over Rh/SiO_2[J].Journal of Catalysis,2009(1):89-92.
[40]	Shinmi Y;Koso S;Kubota T;Nakagawa Y Tomishige K .[J].Applied Catalysis B:Environmental,2010,94:318.
[41]	Chen K Y;Koso S;Kubota T;Nakagawa Y Tomishige K .[J].ChemCatChem,2010,2:547.
[42]	Amada Y;Koso S;Nakagawa Y;Tomishige K .[J].ChemSusChem,2010,3:728.
[43]	Ishida, Y;Ebashi, T;Ito, S;Kubota, T;Kunimori, K;Tomishige, K .Preferential CO oxidation in a H-2-rich stream promoted by ReOx species attached to Pt metal particles[J].Chemical communications,2009(35):5308-5310.
[44]	Ebashi T;Ishida Y;Nakagawa Y;Ito S-I Kubota T Tomishige K .[J].J Phy Chem C,2010,114:6518.
[45]	Bartholomew C H;Pannell R B;Butler J L .[J].Journal of Catalysis,1980,65:335.
[46]	Arena F;Horrell B A;Cocke D L;Parmaliana A Giordano N .[J].Journal of Catalysis,1991,132:58.
[47]	Yamazaki O;Tomishige K;Fujimoto K .[J].Applied Catalysis A:General,1996,136:49.
[48]	Tomishige K;Chen Y G;Fujimoto K .[J].Journal of Catalysis,1999,181:91.
[49]	Nurunnabi M;Mukainakano Y;Kado S;Li BT;Kunimori K;Suzuki K;Fujimoto K;Tomishige K .Additive effect of noble metals on NiO-MgO solid solution in oxidative steam reforming of methane under atmospheric and pressurized conditions[J].Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications,2006(0):145-156.
[50]	Miyazawa T;Okurnura K;Kunimori K;Tomishige K .[J].Journal of Physical Chemistry C,2008,112:2574.
[51]	Chen Y G;Tomishige K;Yokoyama K;Fujimoto K .[J].Applied Catalysis A:General,1997,165:335.
[52]	Li D L;Nakagawa Y;Tomishige K .[J].Applied Catalysis A:General,2011,408:1.
[53]	Li B T;Kado S;Mukainakano Y;Miyazawa T Miyao T Naito S Okumura K Kunimori K Tomishige K .[J].Journal of Catalysis,2007,245:144.
[54]	Tomishige K;Kanazawa S;Sato M;Ikushima K Kunimori K .[J].Catalysis Letters,2002,84:69.
[55]	Li B T;Kado S;Mukainakano Y;Nurunnabi M,Miyao T,Naito S,Kunimori K,Tomishige K .[J].Appl Catal 4,2006,304:62.
[56]	Mukainakano Y;Li BT;Kado S;Miyazawa T;Okumura K;Miyao T;Naito S;Kunimori K;Tomishige K .Surface modification of Ni catalysts with trace Pd and Rh for oxidative steam reforming of methane[J].Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications,2007(0):252-264.
[57]	Miyata T;Li D;Shiraga M;Shishido T;Oumi Y;Sano T;Takehira K .Promoting effect of Rh, Pd and Pt noble metals to the Ni/Mg(Al)O catalysts for the DSS-like operation in CH4 steam reforming[J].Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications,2006(0):97-104.
[58]	Li D L;Atake I;Shishido T;Oumi Y Sano T Takehira K .[J].Journal of Catalysis,2007,250:299.
[59]	Li D L;Shishido T;Oumi Y;Sano T Takehira K .[J].Applied Catalysis A:General,2007,332:98.
[60]	Li D L;Nishida K;Zhan Y Y;Shishido T Oumi Y Sano T Takehira K .[J].Applied Catalysis A:General,2008,350:225.
[61]	Nurunnabi M;Li B T;Kunimori K;Suzuki K Fujimoto K-I Tomishige K .[J].Catalysis Letters,2005,103:277.
[62]	Nurunnabi M;Li B T;Kunimori K;Suzuki K Fujimoto K-I Tomishige K .[J].Applied Catalysis A:General,2005,292:272.
[63]	Nurunnabi M;Mukainakano Y;Kado S;Miyazawa T;Okumura K;Miyao T;Naito S;Suzuki K;Fujimoto KI;Kunimori K .Oxidative steam reforming of methane under atmospheric and pressurized conditions over Pd/NiO-MgO solid solution catalysts[J].Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications,2006(0):1-12.

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