以阳离子表面活性剂十六烷基三甲基溴化铵和阴离子水溶性聚丙烯酸钠(NaPAA)混合物为模板剂,在较高温度和碱度下采用St(o)ber法合成介孔材料.通过调变助剂乙醇含量、晶化温度、晶化时间、NaPAA含量和分子量等制得结构和形貌不同的硅基介孔材料.研究表明,这是NaPAA和乙醇共同作用的结果.
参考文献
| [1] | Beck J S;Vartuli J C;Roth W J;Leonowicz M E Kresge C T Schmitt K D Chu C T W Olson D H Sheppard E W .[J].Journal of the American Chemical Society,1992,114:10834. |
| [2] | Kresge C T;Leonowicz M E;Roth W J;Vartuli J C Beck J S .[J].Nature,1992,359:710. |
| [3] | Selvam P;Bhatia S K;Sonwane C G .[J].Industrial and Engineering Chemistry Research,2001,40:3237. |
| [4] | Linssen T.;Cassiers K.;Cool P.;Vansant EF. .Mesoporous templated silicates: an overview of their synthesis, catalytic activation and evaluation of the stability [Review][J].Advances in Colloid and Interface Science,2003(2):121-147. |
| [5] | Liu X B;Li L S;Du Y;Guo Z Ong T T Chen Y Ng S C Yang Y H .[J].Journal of Chromatography A,2009,1216:7767. |
| [6] | Li YY;Cheng SY;Dai PC;Liang XM;Ke YX .Large-pore monodispersed mesoporous silica spheres: synthesis and application in HPLC[J].Chemical communications,2009(9):1085-1087. |
| [7] | 冯雪风,金卫根,刘芬,罗建勋.介孔中空二氧化硅及硅基微球制备研究进展[J].无机盐工业,2008(12):12-14. |
| [8] | Zhao D Y;Feng J L;Huo Q S;Melosh N Fredrickson G H Chmelka B F Stucky G D .[J].Science,1998,279:548. |
| [9] | Jin ZW;Wang XD;Cui XG .Synthesis and morphological investigation of ordered SBA-15-type mesoporous silica with an amphiphilic triblock copolymer template under various conditions[J].Colloids and Surfaces, A. Physicochemical and Engineering Aspects,2008(1/3):27-36. |
| [10] | Suzuki K;lkari K;Imai H .[J].Journal of the American Chemical Society,2004,126:462. |
| [11] | Ye, JF;Zhang, HJ;Yang, R;Li, XG;Qi, LM .Morphology-Controlled Synthesis of SnO2 Nanotubes by Using 1D Silica Mesostructures as Sacrificial Templates and Their Applications in Lithium-Ion Batteries[J].Small,2010(2):296-306. |
| [12] | Liu Y R .[J].Microporous and Mesoporous Materials,2009,124:190. |
| [13] | Braga T P;Gomes E C C;de Sousa A F;Carre(n)o N L V Longhinotti E Valentini A .[J].Journal of Non-Crystalline Solids,2009,355:860. |
| [14] | Lin H M;Zhu G H;Xing J J;Gao B Qiu S L .[J].Langmuir,2009,25:10159. |
| [15] | Wang Y;Song H H;Zhang H;Liao L F Liu N Chen X H .[J].Journal of Materials Chemistry,2011,21:5576. |
| [16] | Chen Q R;Han L;Gao C B;Che S A .[J].Microporous and Mesoporous Materials,2010,128:203. |
| [17] | Gu X;Li C L;Liu X H;Ren J W Wang Y Q Guo Y L Guo Y Lu G Z .[J].Journal of Physical Chemistry C,2009,113:6472. |
| [18] | Li, Y;Bi, LF;Wang, SB;Chen, YL;Li, BZ;Zhu, XL;Yang, YG .Preparation of helical mesoporous ethylene-silica nanofibers with lamellar mesopores on the surfaces[J].Chemical communications,2010(15):2680-2682. |
| [19] | Niu D C;Ma Z;Li Y S;Shi J L .[J].Journal of the American Chemical Society,2010,132:15144. |
| [20] | Guo X H;Deng Y H;Tu B;Zhao D Y .[J].Langmuir,2010,26:702. |
| [21] | Chen H M;He J H;Tang H M;Yan C X .[J].Chemistry of Materials,2008,20:5894. |
| [22] | Yu S H;C(o)lfen H .[J].Journal of Materials Chemistry,2004,14:2124. |
| [23] | Pouget E;Dujardin E;Cavalier A;Moreac A Valery C Marchi-Artzner V Weiss T Renault A Paternoster M Artzner F .[J].Nature Materials,2007,6:434. |
| [24] | Liu S Q;Cool P;Collart O;Van Der Voort P Vansant E F Lebedev O I Van Tendeloo G Jiang M H .[J].Journal of Physical Chemistry B,2003,107:10405. |
| [25] | Iler R K.The Chemistry of Silica[M].New York:Wiley-Interscience Publications,1979 |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%