A sol-gel method was used to prepare WO3/MWCNT-TiO2 composites. Their photocatalytic activities were evaluated by the degradation of methylene blue (MB) solution under UV light. The catalysts were characterized by X-ray diffraction, specific surface area measurement, energy-dispersive X-ray analysis, transmission and scanning electron microscopy. Aqueous MB solutions of 100 ml were photodegraded by a small amount of the WO3/MWCNT-TiO2 composite under UV light irradiation. The photocatalytic data showed that the WO3/MWCNT-TiO2 composite achieved a high rate of MB photodegradation. This was attributed to the use of MWCNT which can absorb UV light to create photo-induced electrons, strong adsorption of dye molecules on the photocatalyst, and reduced recombination rate of electron-holes in the WO3/MWCNT-TiO2 composite due to the introduction of the WO3 semiconductor.
参考文献
[1] | Cotton F A;Wilkinson G.Advanced Inorganic Chemistry[M].New York:John Wiley and Sons,Inc,1988:654. |
[2] | Fujishima A;Honda K .[J].Nature,1972,238:37. |
[3] | Kawai T;Sakata T .[J].Nature,1980,286:474. |
[4] | O'Regan B;Gr(a)tzel M .[J].Nature,1991,353:737. |
[5] | Barbe C J;Arendse F;Comte P;Jirousek M Lenzmann F Shklover V Gratzel M .[J].Journal of the American Ceramic Society,1997,80:3157. |
[6] | Mills A;LeHunte S .[J].Journal of Photochemistry and Photobiology A: Chemistry,1997,108:1. |
[7] | Fujishima A.;Tryk DA.;Rao TN. .TiO2 photocatalysts and diamond electrodes[J].Electrochimica Acta,2000(28):4683-4690. |
[8] | Dagan G;Tomkiewicz M .[J].Journal of Physical Chemistry,1993,97:12651. |
[9] | Dagan G;Tomkiewicz M .[J].Journal of Non-Crystalline Solids,1994,175:294. |
[10] | Robert D.;Pulgarin C.;Krzton A.;Weber JV.;Parra S. .Chemisorption of phenols and acids on TiO2 surface[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2000(1/2):51-58. |
[11] | Turchi C S;Ollis D F .[J].Journal of Catalysis,1990,122:178. |
[12] | Minero C;Pelizzetti E;Malato S;Blanco J .[J].Journal of Solar Energy Engineering,1996,56:421. |
[13] | Alfano OM.;Cassano AE.;Cabrera MI. .PHOTOCATALYTIC REACTIONS INVOLVING HYDROXYL RADICAL ATTACK - I - REACTION KINETICS FORMULATION WITH EXPLICIT PHOTON ABSORPTION EFFECTS[J].Journal of Catalysis,1997(2):370-379. |
[14] | Chhor K;Bocquet JF;Colbeau-Justin C .Comparative studies of phenol and salicylic acid photocatalytic degradation: influence of adsorbed oxygen[J].Materials Chemistry and Physics,2004(1):123-131. |
[15] | Rao C N R;Satishkumar B C;Govindaraj A;Nath M .[J].ChemPhysChem:A European Journal of Chemical Physics and Physical Chemistry,2001,2:78. |
[16] | Olek M;Busgen T;Hilgendorff M;Giersig M .[J].Journal of Physical Chemistry B,2006,110:12901. |
[17] | Profumo A;Fagnoni M;Merli D;Quartarone E;Protti S;Dondi D;Albini A .Multiwalled carbon nanotube chemically modified gold electrode for inorganic as speciation and Bi(III) determination[J].Analytical chemistry,2006(12):4194-4199. |
[18] | Chen M L;Zhang F J;Oh W C .[J].New Carbon Materials,2009,24:159. |
[19] | Charlier J C .[J].Accounts of Chemical Research,2002,35:1063. |
[20] | Li X Z;Li F B;Yang C L;Ge W K .[J].Journal of Photochemistry and Photobiology A: Chemistry,2001,141:209. |
[21] | Stankova M;Vilanova X;Calderer J;Llobet E Ivanov P Gracia 1 Cane C Correig X .[J].Sensors and Actuators B: Chemical,2004,102:219. |
[22] | Solis J L;Saukko S;Kish L;Granqvist C G Lantto V .[J].THIN SOLID FILMS,2001,391:255. |
[23] | Li Y;Bando Y;Golberg D .[J].Advanced Materials,2003,15:1294. |
[24] | Fukunga A;Chu S Y;McHenry M E .[J].Journal of Materials Research,1998,13:2465. |
[25] | Keller V;Bernhardt P;Garin F .[J].Journal of Catalysis,2003,215:129. |
[26] | Ke D;Liu H;Peng T;Liu X Dai K .[J].Materials Letters,2008,62:447. |
[27] | Puddu, V;Mokaya, R;Puma, GL .Novel one step hydrothermal synthesis of TiO2/WO3 nanocomposites with enhanced photocatalytic activity[J].Chemical Communications,2007(45):4749-4751. |
[28] | Akurati K;Vital A;Dellemann J Ph;Michalowa K Graule T Ferri D Baiker A .[J].Applied Catalysis B:Environmental,2008,79:53. |
[29] | Zhang Q;Li X J;Li F B .[J].Transactions of Nonferrous Metals Society of China,2002,12:1299. |
[30] | Zhang Y;Kohler N;Zhang M .Surface modification of superparamagnetic magnetite nanoparticles and their intracellular uptake.[J].Biomaterials,2002(7):1553-1561. |
[31] | Pietruszka B;Gregorio F D;Keller N;Keller V .[J].Catalysis Today,2005,102-103:94. |
[32] | Oh W C .[J].Environ Eng Res,2008,13:85. |
[33] | Chen M L;Bae J S;Oh W C .[J].Bulletin of the Korean Chemical Society,2006,27:1423. |
[34] | Oh W C;Jung A R;Ko W B .[J].Journal of Industrial and Engineering Chemistry,2007,13:1208. |
[35] | Oh W C .[J].Journal of the Korean Ceramic Society,2009,46:234. |
[36] | Oh W C;Chen M L .[J].Bulletin of the Korean Chemical Society,2008,29:159. |
[37] | Chen M L;Zhang F J;Oh W C .[J].Journal of the Korean Ceramic Society,2008,45:651. |
[38] | Yu Y;Yu J C;Chan C Y;Che Y K Zhao J C Ding L Ge W K Wong P K .[J].Applied Catalysis B:Environmental,2005,61:1. |
[39] | Ghasemi S;Rahimnejad S;Rahman Setayesh S;Rohani S Gholami M R .[J].Journal of Hazardous Materials B:Environmental Technologies,2009,172:1573. |
[40] | Ghasemi, S;Rahimnejad, S;Setayesh, SR;Hosseini, M;Gholami, MR .KINETICS INVESTIGATION OF THE PHOTOCATALYTIC DEGRADATION OF ACID BLUE 92 IN AQUEOUS SOLUTION USING NANOCRYSTALLINE TiO2 PREPARED IN AN IONIC LIQUID[J].Progress in reaction kinetics and mechanism,2009(1):55-76. |
- 下载量()
- 访问量()
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%