Tungstophosphoric Acid Supported on Highly Organosoluble Polyamide (PW12/PA): Highly Efficient Catalysts for the Synthesis of Novel1,3,5-Triaryl-2-pyrazoline Derivatives

催化学报 , 2011, 32(4): 582-588. doi: 10.1016/S1872-2067(10)60203-3

Tungstophosphoric Acid Supported on Highly Organosoluble Polyamide (PW12/PA): Highly Efficient Catalysts for the Synthesis of Novel1,3,5-Triaryl-2-pyrazoline Derivatives

^1, , ^2, , ^3, , ^4, , ^5,

1.Department of Chemistry, Islamic Azad University, Shahreza Branch, 86145-311, Iran

2.Islamic Azad University, Mobarakeh Branch, 84815-119, Iran

3.Organic Polymer Chemistry Research Laboratory, Department of Chemistry, Isfahan University of Technology, Isfahan 84156-83111, Iran;Nanotechnology and Advanced Materials Institute, Isfahan University of Technology, lsfahan 84156-83111, Iran

4.Department of Chemistry, Yasouj University, Yasouj 75914-353, Iran

5.Department of Chemistry, Islamic Azad University, Qom Branch, Qom, Iran

基金项目: This work was supported by the Islamic Azad University,Shahreza Branch and the Research Affairs Division Isfahan University of Technology (IUT)

Tungstophosphoric Acid Supported on Highly Organosoluble Polyamide (PW12/PA): Highly Efficient Catalysts for the Synthesis of Novel 1,3,5-Triaryl-2-pyrazoline Derivatives

Keywords： inorganic-organic hybrid

A novel compound constructed from polyoxometalate (H3PW12O40, PW12) and poly(amidoamine) (PA) was prepared at room temperature in an aqueous solution by an impregnation method. A series of novel 1,3,5-triaryl-2-pyrazoline derivatives was synthesized by the reaction between chalcone and phenylhydrazine in the presence of the title compound, PW12/PA, in high yields. The structures of the compounds obtained were determined by IR and 1H NMR spectra.

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Tungstophosphoric Acid Supported on Highly Organosoluble Polyamide (PW12/PA): Highly Efficient Catalysts for the Synthesis of Novel1,3,5-Triaryl-2-pyrazoline Derivatives

Tungstophosphoric Acid Supported on Highly Organosoluble Polyamide (PW12/PA): Highly Efficient Catalysts for the Synthesis of Novel 1,3,5-Triaryl-2-pyrazoline Derivatives

参考文献