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  4. 含TiO2(B)介孔氧化钛材料的制备、特性和应用

催化学报 , 2010, 31(6): 605-614. doi: 10.1016/S1872-2067(09)60073-5

含TiO2(B)介孔氧化钛材料的制备、特性和应用

陈闪山 1, , 朱银华 2, , 李伟 3, , 刘维佳 4, , 李力成 5, , 杨祝红 6, , 刘畅 7, , 姚文俊 8, , 陆小华 9, , 冯新 10,

1.南京工业大学材料化学工程国家重点实验室,江苏,南京,210009

2.南京工业大学材料化学工程国家重点实验室,江苏,南京,210009

3.南京工业大学材料化学工程国家重点实验室,江苏,南京,210009

4.南京工业大学材料化学工程国家重点实验室,江苏,南京,210009

5.南京工业大学材料化学工程国家重点实验室,江苏,南京,210009

6.南京工业大学材料化学工程国家重点实验室,江苏,南京,210009

7.南京工业大学材料化学工程国家重点实验室,江苏,南京,210009

8.南京工业大学材料化学工程国家重点实验室,江苏,南京,210009

9.南京工业大学材料化学工程国家重点实验室,江苏,南京,210009

10.南京工业大学材料化学工程国家重点实验室,江苏,南京,210009

基金项目:   国家重点基础研究发展计划(973计划)前期研究专项(2009CB226103)   长江学者和创新团队发展计划(IRT0732)   江苏省高校自然科学基金(08KJB530003)   江苏省产学研联合创新资金项目(BY2009107)   江苏省高技术研究项目(BG2007051)   国家高技术研究发展计划(863计划)(2006AA03Z455)   国家自然科学基金重点项目(20736002;20976080)   国家自然科学基金委员会与香港研究资助局联合科研基金(20731160614)  

关键词： 介孔 , 氧化钛 , 比表面积 , 热稳定性 , 光催化 , 加氢脱硫 , 药物载体

Synthesis,Features,and Applications of Mesoporous Titania with TiO2(B)

综述了近年来本课题组依据材料化学工程研究思想,对含TiO2(B)(一种比金红石和锐钛矿相结构更松散的氧化钛晶型)介孔氧化钛材料在制各、结构和性能方面所取得的研究进展,该介孔材料由二钛酸钾经水合、离子交换和热处理得到,具有良好原子尺度晶格匹配界面特征的锐钛矿和TiO2(B)核壳结构.研究表明,该介孔材料在兼备高比表面积、高晶化孔壁和高热稳定性的同时,还表现出良好的纳米颗粒担载稳定性,在光催化、油品加氧精制、药物载体、固体酸催化和电化学电容器等方面已凸显出良好的应用潜力和推广价值,目前该新型含TiO2(B)介孔氧化钛材料已经实现低成本、规模化制备.

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