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研究了辛醇对苯甲羟肟酸(BHA)浮选锡石纯矿物的影响,分析了辛醇和 BHA 在锡石表面的吸附机理。实验室浮选实验结果表明,在广泛 pH 区间内,单一辛醇对锡石没有浮选性,但是作为辅助捕收剂,辛醇可以显著降低捕收剂 BHA 的用量,并且使锡石仍保持较高回收率。红外光谱和吸附量研究表明,单一辛醇在锡石表面没有发生吸附,但是辛醇与 BHA 形成吸附组合体而吸附在锡石表面,增强了锡石表面的疏水性;同时辛醇使 BHA在锡石表面的吸附量增加,从而降低了 BHA 的用量。

The effect of octanol in cassiterite flotation using benzohydroxamic acid (BHA) as a collector was investigated. The adsorption mechanism of octanol and BHA on the surface of cassiterite was analyzed by adsorption experiments and infrared spectra analysis. Micro-flotation results indicated that single octanol exhibited almost no collecting power to cassiterite over a wide pH range. However, as an auxiliary collector, octanol could markedly decrease the consumption of collector BHA and keep the recovery of cassiterite in high level. The results of adsorption experiments and infrared spectra demonstrated that single octanol was not adsorbed on the surface of cassiterite. It formed adsorption connected with BHA on the surface of cassiterite, and enhanced the hydrophobicity of cassiterite. Octanol promoted the adsorption amount of BHA on the cassiterite surface, and decreased the consumption of BHA.

参考文献

[1] Angadi, S. I.;Sreenivas, T.;Jeon, Ho-Seok;Baek, Sang-Ho;Mishra, B. K..A review of cassiterite beneficiation fundamentals and plant practices[J].Minerals Engineering,2015:178-200.
[2] Andrew Falconer.Gravity separation: old technique/new methods[J].Physical Separation in Science and Engineering,20031(1):31-48.
[3] Erik Van Kemenade;Eva Mondt;Toine Hendriks;Paul Verbeek.Liquid-Phase Separation with the Rotational Particle Separator[J].Chemical Engineering & Technology: Industrial Chemistry -Plant Equipment -Process Engineering -Biotechnology,200311(11):1176-1183.
[4] Jean-Sebastien Kroll-Rabotin;Florent Bourgeois;Eric Climent.Physical analysis and modeling of the Falcon concentrator for beneficiation of ultrafine particles[J].International Journal of Mineral Processing,2013:39-50.
[5] 赵跃民;温雪峰;施红霞;焦红光;陶有俊.Study on Metals Recovery from -0.074 mm Printed Circuit Boards by Enhanced Gravity Separation[J].过程工程学报,2006(2):201-204.
[6] X. Wang;N. J. Miles;S. Kingman.Numerical study of centrifugal fluidized bed separation[J].Minerals Engineering,200610(10):1109-1114.
[7] Bulatovic S.;Silvio E..Process development for impurity removal from a tin gravity concentrate[J].Minerals Engineering,20008-9(8-9):871-879.
[8] M.P. Hay;C.M. Rule.SUPASIM: a flotation plant design and analysis methodology[J].Minerals Engineering,200311(11):1103-1109.
[9] 王佩佩;覃文庆;任浏祎;魏茜;刘瑞增;杨聪仁;衷水平.烷基羟肟酸对细粒锡石的浮选及其溶液化学性质[J].中国有色金属学报(英文版),2013(6):1789-1796.
[10] Yongcheng Zhou;Xiong Tong;Shaoxian Song.Beneficiation of Cassiterite Fines from a Tin Tailing Slime by Froth Flotation[J].Separation Science and Technology,20141/5(1/5):458-463.
[11] X.Q. Wu;J.G. Zhu.Selective flotation of cassiterite with Benzohydroxamic acid[J].Minerals Engineering,200614(14):1410-1417.
[12] 孙伟;柯丽芳;孙磊.苯甲羟肟酸在锡石浮选中的应用及作用机理研究[J].中国矿业大学学报,2013(1):62-68.
[13] Wenqing Qin;Yangbao Xu;Hui Liu.Flotation and Surface Behavior of Cassiterite with Salicylhydroxamic Acid[J].Industrial & Engineering Chemistry Research,201118(18):10778-10783.
[14] QIN Wen-qing;REN Liu-yi;XU Yang-bao;WANG Pei-pei;MA Xi-hong.Adsorption mechanism of mixed salicylhydroxamic acid and tributyl phosphate collectors in fine cassiterite electro-flotation system[J].中南大学学报(英文版),2012(06):1711-1717.
[15] 朱海玲;邓海波;陈臣.石油磺酸钠对红柱石和石英浮选分离的影响[J].中国有色金属学报(英文版),2015(4):1279-1285.
[16] 刘瑞增;覃文庆;焦芬;王兴杰;裴斌;杨永军;赖春华.腐殖酸钠和过硫酸铵组合抑制剂浮选分离黄铜矿和方铅矿[J].中国有色金属学报(英文版),2016(1):265-271.
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