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在 Q235不锈钢板上利用爆炸喷涂工艺制备名义组分为 Fe51.33Cr14.9Mo25.67Y3.4C3.44B1.26(摩尔分数,%)的铁基非晶涂层。采用扫描电镜、X 射线衍射仪、维氏显微硬度计、摩擦磨损试验机和电化学测量方法对涂层的组织结构、相组成、硬度、摩擦磨损特性和耐腐蚀性能进行表征。显微组织结构分析结果表明,涂层组织均匀、结构致密、平均孔隙率低于2.1%。干磨条件下的磨损行为显示,在同一磨损条件下,非晶涂层的相对耐磨性为基体材料的5倍。摩擦过程中,磨损形式为粘着磨损和磨粒磨损的综合作用,在非晶涂层中粘着磨损起主导作用。涂层在质量分数为3.5% NaCl 水溶液中存在明显的钝化现象,有较低的钝化电流密度和较宽的钝化区间,呈现出优异的耐腐蚀性能。

A metallic glass coating with the composition of Fe51.33Cr14.9Mo25.67Y3.4C3.44B1.26 (mole fraction, %) on the Q235 stainless steel was developed by the detonation gun (D-gun) spraying process. The microstructure and the phase aggregate were analyzed by scanning electron microscopy and X-ray diffractometry, respectively. Microhardness, wear resistance and corrosion behavior were assessed using a Vickers microhardness tester, a ball-on-disk wear testing machine and the electrochemical measurement method, respectively. Microstructural studies show that the coatings possess a densely layered structure with the porosity less than 2.1%. The tribological behavior of the coatings examined under dry conditions shows that their relative wear resistance is five times higher than that of the substrate material. Both adhesive wear and abrasive wear contribute to the friction, but the former is the dominant wear mechanism of the metallic glass coatings. The coatings exhibit low passive current density and extremely wide passive region in 3.5% NaCl solution, thus indicating excellent corrosion resistance.

参考文献

[1] Akihisa Inoue;Akira Takeuchi.Recent progress in bulk glassy alloys[J].Materials transactions,20028(8):1892-1906.
[2] A.Inoue.Stabilization of metallic supercooled liquid and bulk amorphous alloys[J].Acta materialia,20001(1):279-306.
[3] Christopher A. Schuh;Todd C. Hufnagel;Upadrasta Ramamurty.Mechanical behavior of amorphous alloys[J].Acta materialia,200712(12):4067-4109.
[4] S.L. Zhu;X.M. Wang;F.X. Qin.;A. Inoue.A new Ti-based bulk glassy alloy with potential for biomedical application[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,20071/2(1/2):233-237.
[5] Akira Takeuchi;Akihisa Inoue.Classification of Bulk Metallic Glasses by Atomic Size Difference, Heat of Mixing and Period of Constituent Elements and Its Application to Characterization of the Main Alloying Element (Overview)[J].Materials transactions,200512(12):2817-2829.
[6] Dongyan Liu;Wei Gao;Zhengwei Li.Electro-spark deposition of Fe-based amorphous alloy coatings[J].Materials Letters,200726(26):165-167.
[7] Baolong Shen;Akihisa Inoue;Chuntao Chang.Superhigh strength and good soft-magnetic properties of (Fe, Co)-B-Si-Nb bulk glassy alloys with high glass-forming ability[J].Applied physics letters,200421(21):4911-4913.
[8] Kim HJ.;Seong BG.;Park CG.;Lim KM..Amorphous phase formation of Zr-based alloy coating by HVOF spraying process[J].Journal of Materials Science,20011(1):49-54.
[9] Sharma P;Zhang W;Amiya K;Kimura H;Inoue A.Nanoscale patterning of Zr-Al-Cu-Ni metallic glass thin films deposited by magnetron sputtering[J].Journal of nanoscience and nanotechnology,20053(3):416-420.
[10] J. Jayaraj;D. J. Sordelet;D. H. Kim;Y. C. Kim;E. Fleury.Corrosion behaviour of Ni-Zr-Ti-Si-Sn amorphous plasma spray coating[J].Corrosion Science: The Journal on Environmental Degradation of Materials and its Control,20064(4):950-964.
[11] Basu A;Sarnant AN;Harirnkar SP;Majumdar JD;Manna I;Dahotre NB.Laser surface coating of Fe-Cr-Mo-Y-B-C bulk metallic glass composition on AISI 4140 steel[J].Surface & Coatings Technology,200812(12):2623-2631.
[12] Murthy JKN;Bysakh S;Gopinath K;Venkataraman B.Microstructure dependent erosion in Cr3C2-20(NiCr) coating deposited by a detonation gun[J].Surface & Coatings Technology,20071(1):1-12.
[13] Kaur, M.;Singh, H.;Prakash, S..Surface engineering analysis of detonation-gun sprayed Cr_3C_2-NiCr coating under high-temperature oxidation and oxidation-erosion environments[J].Surface & Coatings Technology,20112/3(2/3):530-541.
[14] Subhash Kamal;R. Jayaganthan;S. Prakash.Hot corrosion behavior of detonation gun sprayed Cr_3C_2-NiCr coatings on Ni and Fe-based superalloys in Na_2SO_4-60 percent V_2O_5 environment at 900 deg C[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,20081/2(1/2):358-372.
[15] Rajasekaran B;Raman SGS;Joshi SV;Sundararajan G.Effect of detonation gun sprayed Cu-Ni-In coating on plain fatigue and fretting fatigue behaviour of Al-Mg-Si alloy[J].Surface & Coatings Technology,20063/4(3/4):1548-1558.
[16] Zhou, Z;Wang, L;Wang, FC;Zhang, HF;Liu, YB;Xu, SH.Formation and corrosion behavior of Fe-based amorphous metallic coatings by HVOF thermal spraying[J].Surface & Coatings Technology,20095(5):563-570.
[17] Shtansky DV;Kiryukhantsev-Komeev PV;Sheveyko AN;Kutyrev AE;Levashov EA.Hard tribological Ti-Cr-B-N coatings with enhanced thermal stability, corrosion- and oxidation resistance[J].Surface & Coatings Technology,20074/7(4/7):861-865.
[18] Z. Zhou;L. Wang;D. Y. He;F. C. Wang;Y. B. Liu.Microstructure and Electrochemical Behavior of Fe-Based Amorphous Metallic Coatings Fabricated by Atmospheric Plasma Spraying[J].Journal of Thermal Spray Technology,20111/2(1/2):344-350.
[19] Shaha, K.P.;Pei, Y.T.;Martinez-Martinez, D.;De Hosson, J.T.M..Influence of hardness and roughness on the tribological performance of TiC/a-C nanocomposite coatings[J].Surface & Coatings Technology,20107(7):2624-2632.
[20] Hong Wu;Ian Baker;Yong Liu.Tribological studies of a Zr-based bulk metallic glass[J].Intermetallics,2013:25-32.
[21] Sanghoon Yoon;Junghwan Kim;Gyuyeol Bae.Formation of coating and tribological behavior of kinetic sprayed Fe-based bulk metallic glass[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,20112(2):347-353.
[22] C. -J. Li;A. Ohmori.Relationships between the microstructure and properties of thermally sprayed deposits[J].Journal of Thermal Spray Technology,20023(3):365-374.
[23] H.W.Jin;C.G.Park;M.C.Kim.Friction-induced amorphous phase formation observed in Fe-Cr-B-Ni-Mo alloy thermal spray coatings.[J].Scripta materialia,19996(6):589-595.
[24] Jin HW.;Hong SG.;Park CG.;Rhyim YM..Microstructural evolution of the rapidly quenched Fe-Cr-B alloy thermal spray coatings[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,20010(0):1069-1074.
[25] Dongya Huang;Ran Li;Lu Huang.Fretting wear behavior of bulk amorphous steel[J].Intermetallics,201110(10):1385-1389.
[26] Yoon, S.;Kim, J.;Kim, B.D.;Lee, C..Tribological behavior of B_4C reinforced Fe-base bulk metallic glass composite coating[J].Surface & Coatings Technology,20107(7):1962-1968.
[27] A.L. Greer;K.L. Rutherford;I.M. Hutchings.Wear resistance of amorphous alloys and related materials[J].International Materials Reviews,20022(2):87-112.
[28] S. J. Pang;T. Zhang;K. Asami.Synthesis of Fe-Cr-Mo-C-B-P bulk metallic glasses with high corrosion resistance[J].Acta materialia,20023(3):489-497.
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