采用批式吸附实验和土柱实验研究KH2PO4、(NH4)H2PO4和 Ca(H2PO4)2对铜和锌在红壤中的吸附和淋溶特性。结果表明:这3种磷酸盐都能极大地提高红壤对铜和锌的吸附能力,其影响大小顺序为 Ca(H2PO4)2> KH2PO4>(NH4)H2PO4。磷酸盐的添加对铜的迁移性影响不大。Ca(H2PO4)2和(NH4)H2PO4能较大地提高锌在红壤中的移动性。3种磷酸盐都能促进铜和锌的形态由非残渣态向残渣态转化,但是同样会增加其可交换态和碳酸盐结合态的含量。
Batch and soil column experiments were conducted to evaluate the influence of KH2PO4, (NH4)H2PO4and Ca(H2PO4)2on the adsorption and leaching characteristics of Cu and Zn in red soil. The results show that all the three phosphates can greatly improve the adsorption capacity of red soil for Cu and Zn, and the effect of different phosphates on Cu and Zn adsorption follows the order of Ca(H2PO4)2>KH2PO4>(NH4)H2PO4. The addition of phosphate has little effect on the mobility of Cu. Ca(H2PO4)2and (NH4)H2PO4 show a strong ability in immobilizing Zn while the immobilization ability of KH2PO4 is much weaker. All the three phosphates are helpful for modifying the partitioning of Cu and Zn from the non-residual phase to the residual phase; however, they could also enhance the contents of Cu and Zn associated with exchangeable and carbonates fractions.
参考文献
[1] | Nanthi Bolan;Anitha Kunhikrishnan;Ramya Thangarajan;Jurate Kumpiene;Jinhee Park;Tomoyuki Makino;Mary Beth Kirkham;Kirk Scheckel.Remediation of heavy metal(loid)s contaminated soils - To mobilize or to immobilize?[J].Journal of hazardous materials,2014Feb.15(Feb.15):141-166. |
[2] | Shuiping Cheng.Heavy Metal Pollution in China: Origin, Pattern and Control/A State-of-the-Art Report with Special Reference to Literature Published in Chinese Journals[J].Environmental Science and Pollution Research,20033(3):192-198. |
[3] | LIAO Guo-li;LIAO Da-xue;LI Quan-ming.Heavy metals contamination characteristics in soil of different mining activity zones[J].中国有色金属学会会刊(英文版),2008(01):207-211. |
[4] | Adriano DC;Wenzel WW;Vangronsveld J;Bolan NS.Role of assisted natural remediation in environmental cleanup[J].Geoderma: An International Journal of Soil Science,20042/4(2/4):121-142. |
[5] | Andrew A. Meharg;M. D. Mazibur Rahman.Arsenic contamination of Bangladesh paddy field soils: implications for rice contribution to arsenic consumption[J].Environmental Science & Technology: ES&T,20032(2):229-234. |
[6] | Rattan R K;Datta S P;Chhonkar P K;Suribabu K;Singh A K.Long-term impact of irrigation with sewage effluents on heavy metal content in soils, crops and groundwater - a case study.[J].Agriculture, Ecosystems & Environment: An International Journal for Scientific Research on the Relationship of Agriculture and Food Production to the Biosphere,20053/4(3/4):310-322. |
[7] | Jianguo Liu;Jared Diamond.China's environment in a globalizing world[J].Nature,20057046(7046):1179-1186. |
[8] | Wei, BG;Yang, LS.A review of heavy metal contaminations in urban soils, urban road dusts and agricultural soils from China[J].Microchemical Journal: Devoted to the Application of Microtechniques in all Branches of Science,20102(2):99-107. |
[9] | Shibao Chen;Minggang Xu;Yibing Ma;Juncheng Yang.Evaluation of different phosphate amendments on availability of metals in contaminated soil[J].Ecotoxicology and Environmental Safety,20072(2):278-285. |
[10] | Xinde Cao;Ammar Wahbi;Lena Ma;Bing Li;Yongliang Yang.Immobilization of Zn, Cu, and Pb in contaminated soils using phosphate rock and phosphoric acid[J].Journal of hazardous materials,20092/3(2/3):555-564. |
[11] | N.T. Basta;S.L. McGowen.Evaluation of chemical immobilization treatments for reducing heavy metal transport in a smelter-contaminated soil[J].Environmental Pollution,20041(1):73-82. |
[12] | Park, J.H.;Bolan, N.;Megharaj, M.;Naidu, R..Comparative value of phosphate sources on the immobilization of lead, and leaching of lead and phosphorus in lead contaminated soils[J].Science of the Total Environment,20114(4):853-860. |
[13] | Fanrong Zeng;Shafaqat Ali;Haitao Zhang;Younan Ouyang;Boyin Qiu;Feibo Wu;Guoping Zhang.The influence of pH and organic matter content in paddy soil on heavy metal availability and their uptake by rice plants[J].Environmental Pollution,20111(1):84-91. |
[14] | Cao XD;Ma LQ;Singh SP;Zhou QX.Phosphate-induced lead immobilization from different lead minerals in soils under varying pH conditions[J].Environmental Pollution,20081(1):184-192. |
[15] | Kara D;Ozsavasci C;Alkan M.Investigation of suitable digestion methods for the determination of total phosphorus in soils.[J].Talanta: The International Journal of Pure and Applied Analytical Chemistry,199711(11):2027-2032. |
[16] | Arias M;Perez-Novo C;Osorio F;Lopez E;Soto B.Adsorption and desorption of copper and zinc in the surface layer of acid soils[J].Journal of Colloid and Interface Science,20051(1):21-29. |
[17] | Bin Huang;Zhongwu Li;Jinquan Huang;Liang Guo;Xiaodong Nie;Yan Wang;Yan Zhang;Guangming Zeng.Adsorption characteristics of Cu and Zn onto various size fractions of aggregates from red paddy soil[J].Journal of hazardous materials,2014Jan.15(Jan.15):176-183. |
[18] | Sreekrishnaperumal Thanga Ramesh, Rajan Gandhimathi,* Jesuraj Hamoneth Joesun, and Puthiya Veetil Nidheesh.Novel Agricultural Waste Adsorbent, Cyperus rotundus, for Removal of Heavy Metal Mixtures from Aqueous Solutions[J].Environmental engineering science,20132(2):74-81. |
[19] | Agbenin JO.Phosphate-induced zinc retention in a tropical semi-arid soil.[J].European journal of soil science,19984(4):693-700. |
[20] | Perez-Novo, C.;Bermudez-Couso, A.;Lopez-Periago, E.;Fernandez-Calvino, D.;Arias-Estevez, M..The effect of phosphate on the sorption of copper by acid soils[J].Geoderma: An International Journal of Soil Science,20091/2(1/2):166-170. |
[21] | Cristina Perez-Novo;David Fernandez-Calvino;Alipio Bermudez-Couso;Jose E. Lopez-Periago;Manuel Arias-Estevez.Phosphorus effect on Zn adsorption-desorption kinetics in acid soils[J].Chemosphere: Environmental toxicology and risk assessment,20117(7):1028-1034. |
[22] | D.J. Ashworth;B.J. Alloway.Soil mobility of sewage sludge-derived dissolved organic matter, copper, nickel and zinc[J].Environmental Pollution,20041(1):137-144. |
[23] | He, Z L;Zhang, M;Yang, X E;Stoffella, P J.Release behavior of copper and zinc from sandy soils.[J].Soil Science Society of America Journal,20065(5):1699-1707. |
[24] | Helmhart, Martin;O'Day, Peggy A.;Garcia-Guinea, Javier;Serrano, Susana;Garrido, Fernando.Arsenic, Copper, and Zinc Leaching through Preferential Flow in Mining-Impacted Soils[J].Soil Science Society of America Journal,20122(2):449-462. |
[25] | Cao RX.;Ma LQ.;Chen M.;Singh SP.;Harris WG..Phosphate-induced metal immobilization in a contaminated site[J].Environmental Pollution,20031(1):19-28. |
[26] | JOHN C. ZWONITZER;GARY M. PIERZYNSKI;GANGA M. HETT1ARACHCHI.EFFECTS OF PHOSPHORUS ADDITIONS ON LEAD, CADMIUM, AND ZINC BIOAVAILABILITIES IN A METAL-CONTAMINATED SOIL[J].Water, air and soil pollution,20031/4(1/4):193-209. |
[27] | Sun L;Chen S;Chao L;Sun T.Effects of flooding on changes in Eh, pH and speciation of cadmium and lead in contaminated soil.[J].Bulletin of Environmental Contamination and Toxicology,20075(5):514-518. |
[28] | Guiqiu Chen;Guangming Zeng;Chunyan Du;Danlian Huang;Lin Tang;Liang Wang;Guoli Shen.Transfer of heavy metals from compost to red soil and groundwater under simulated rainfall conditions[J].Journal of hazardous materials,20101/3(1/3):211-216. |
[29] | Corwin, D L;Lesch, S M.Apparent soil electrical conductivity measurements in agriculture.[J].Computers and electronics in agriculture,20051/3(1/3):11-43. |
[30] | Kaschl A.;Romheld V.;Chen Y..The influence of soluble organic matter from municipal solid waste compost on trace metal leaching in calcareous soils[J].Science of the Total Environment,20021/3(1/3):45-57. |
[31] | 黄顺红.某铅锌矿区土壤重金属形态分布及污染风险评价[J].中国有色金属学报(英文版),2014(10):3324-3331. |
[32] | 闵小波;谢先德;柴立元;梁彦杰;李密;柯勇.锌浸出渣中重金属的环境活性和生态风险评价[J].中国有色金属学报(英文版),2013(1):208-218. |
[33] | 郭耀广;黄鹏;张武刚;袁学武;范凤霞;王焕丽;柳建设;王兆慧.德兴铜矿尾矿库重金属的浸出[J].中国有色金属学报(英文版),2013(10):3068-3075. |
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