研究两个网状和一个片状氧化涂层阳极在38°C的电解锌溶液中的催化性能,并与通用的Pd?0.7%Al合金的电化学性能进行对比。采用电化学测试方法进行实验,如循环动电位法、恒电流法、动电位法、开路电位法和原位电化学噪音法。经过2 h的开路电位实验,线性极化结果表明:网状Ti/(IrO2?Ta2O5)电极显示出非常好的性能,其腐蚀电流密度在三个氧化涂层阳极中是最低的(3.37μA/cm2)。此外,在50 mA/cm2和38°C的条件下,经过24 h的恒电流极化试验,网状Ti/MnO2阳极有最高的电位(1.799 V),紧随其后的是片状Ti/(IrO2?Ta2O5)(1.775 V)和网状Ti/(IrO2?Ta2O5)阳极(1.705 V)。经过24 h的恒电流极化和16 h时的电位衰退实验后,线性极化方法验证了经过2 h的开路电位实验得出的结果,即网状Ti/(IrO2?Ta2O5)阳极有最低的腐蚀电流。网状Ti/(IrO2?Ta2O5)阳极在24 h极化后显示出更好的性能,并与通用的Pb?0.7%Al合金进行相比,过电位低~245 mV。
The catalytic performance of two oxides coated anodes (OCSs) meshes and one OCA plate was investigated in a zinc electrowinning electrolyte at 38 °C. Their electrochemical behaviors were compared with that of a conventional Pb?0.7%Ag alloy anode. Electrochemical measurements such as cyclic voltammetric, galvanostatic, potentiodynamic, open-circuit potential (OCP) and in situ electrochemical noise measurements were considered. After 2 h of OCP test, the linear polarization shows that the corrosion current density of the Ti/(IrO2?Ta2O5) mesh electrode is the lowest (3.37μA/cm2) among the three OCAs and shows excellent performance. Additionally, after 24 h of galvanostatic polarization at 50 mA/cm2and 38 °C, the Ti/MnO2mesh anode has the highest potential (1.799 V), followed by the Ti/(IrO2?Ta2O5) plate (1.775 V) and Ti/(IrO2?Ta2O5) mesh (1.705 V) anodes. After 24 h of galvanostatic polarization followed by 16 h of decay, the linear polarization method confirms the sequence obtained after 2 h of OCP test, and the Ti/(IrO2?Ta2O5) mesh attains the lowest corrosion current density. The Ti/(IrO2?Ta2O5) mesh anode also shows better performance after 24 h of galvanostatic polarization with the overpotential lower than that of the conventional Pb?Ag anode by about 245 mV.
参考文献
[1] | Brungs A.;Skyllaskazacos M.;Haddadiasl V..PREPARATION AND EVALUATION OF ELECTROCATALYTIC OXIDE COATINGS ON CONDUCTIVE CARBON-POLYMER COMPOSITE SUBSTRATES FOR USE AS DIMENSIONALLY STABLE ANODES[J].Journal of Applied Electrochemistry,199611(11):1117-1123. |
[2] | Msindo, ZS;Sibanda, V;Potgieter, JH.Electrochemical and physical characterisation of lead-based anodes in comparison to Ti-(70%) IrO2/(30%) Ta2O5 dimensionally stable anodes for use in copper electrowinning[J].Journal of Applied Electrochemistry,20103(3):691-699. |
[3] | Morimitsu M.;Matsunaga M.;Otogawa R.;Tamura H..Polarization behaviour and lifetime of IrO2-Ta2O5-SnO2/Ti anodes in p-phenolsulfonic acid solutions for tin plating[J].Journal of Applied Electrochemistry,20004(4):511-514. |
[4] | 肖赛君;Tommy MOKKELBOST;Ove PAULSEN;Arne P RATVIK;Geir M HAARBERG.铝电解中二氧化锡基(氢气)气体阳极[J].中国有色金属学报(英文版),2014(12):3917-3921. |
[5] | Miomir G. Pavlovic;Aleksandar Dekanski.On the use of platinized and activated titanium anodes in some electrodeposition processes[J].Journal of solid state electrochemistry,19973(3):208-214. |
[6] | A. N. Nikoloski;M. J. Nicol.ADDITION OF COBALT TO LEAD ANODES USED FOR OXYGEN EVOLUTION-A LITERATURE REVIEW[J].Mineral Processing and Extractive Metallurgy Review,20101(1):30-57. |
[7] | Palmas S;Polcaro AM;Ferrara F;Ruiz JR;Delogu F;Bonatto-Minella C;Mulas G.Electrochemical performance of mechanically treated SnO2 powders for OER in acid solution[J].Journal of Applied Electrochemistry,20087(7):907-913. |
[8] | Vertova A;Borgese L;Cappelletti G;Locatelli C;Minguzzi A;Pezzoni C;Rondinini S.New electrocatalytic materials based on mixed metal oxides: electrochemical quartz crystal microbalance characterization[J].Journal of Applied Electrochemistry,20087(7):973-978. |
[9] | Sonke Schmachtel;Martina Toiminen;Kyosti Kontturi;Olof Forsen;Michael H. Barker.New oxygen evolution anodes for metal electrowinning: Mn0_2 composite electrodes[J].Journal of Applied Electrochemistry,200910(10):1835-1848. |
[10] | HU Ji-ming;WU Ji-xun;MENG Hui-min;SUN Dong-bai.Degradation characteristics of Ti/(IrO2+Ta2O5) coating anodes in H2SO4 solution[J].中国有色金属学会会刊,2000(04):511. |
[11] | A.-M. Lafront;W. Zhang;S. Jin;R. Tremblay;D. Dube;E. Ghali.Pitting corrosion of AZ91D and AJ62x magnesium alloys in alkaline chloride medium using electrochemical techniques[J].Electrochimica Acta,20053(3):489-501. |
[12] | Ivanov I.;Stefanov Y..Insoluble anodes used in hydrometallurgy Part I. Corrosion resistance of lead and lead alloy anodes[J].Hydrometallurgy,20002(2):109-124. |
[13] | YAN Zhenwei;MENG Huimin.Effect of heat treatment of titanium substrates on the properties of IrO2-Ta2O5 coated anodes[J].稀有金属(英文版),2011(05):439-446. |
- 下载量()
- 访问量()
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%