将K2TiF6和KBF4混合盐与铝合金熔体通过放热反应法制备原位TiB2颗粒增强2014铝合金基复合材料.研究CeO2添加剂对原位TiB2/2014铝基复合材料显微组织和力学性能的影响.结果表明,在高温时添加CeO2与添加Ce的作用相同;当添加0.5% CeO2时,TiB2颗粒在基体中的分散性大幅度提高,颗粒与基体的界面清晰,在复合材料制备过程中颗粒没有明显的沉降现象.解释了TiB2颗粒在2014铝合金基体中的分散机理.加入CeO2的复合材料,其铸态硬度、抗拉强度、屈服强度和伸长率有较大提高.
In-situ TiB2 particles reinforced 2014 aluminum alloy composite was prepared using an exothermic reaction process with K2TiF6 and KBF4 salts.The effects of CeO2 additive on the microstructure and properties of in-situ TiB2/2014 composite were investigated.The results showed that CeO2 at high temperature exhibits the same function as Ce.When 0.5% (mass fraction) CeO2 additive was added,the dispersion of TiB2 particles in the matrix is improved significantly,and particles have no obvious settlement.The dispersing mechanism of TiB2 particles in 2014 Al alloy matrix was explained.Compared with the composite without CeO2,the hardness,tensile strength,yield strength and elongation of the composite with CeO2 addition are greatly increased in as-cast condition.
参考文献
[1] | WALKER J C;RAINFORTH W M;JONE H .Lubricated sliding wear behavior of aluminum alloy composites[J].Wear,2005,259:577-589. |
[2] | KOK M .Production and mechanical properties of Al2O3 particle-reinforced 2024 aluminum alloy composites[J].Journal of Materials Processing Technology,2005,161:381-387. |
[3] | DAVIES P;KELLIE J L F;WOOD J V .Development of cast aluminum MMC'S[J].Key Engineering Materials,1993,77-78:357-362. |
[4] | ONAT A;AKBULUT H;YILMAZ F .Production and characterization of silicon carbide particulate reinforced aluminum-copper alloy matrix composites by direct squeeze casting method[J].Journal of Alloys and Compounds,2007,436:375382. |
[5] | SADEGHIAN Z;LOTFI B;ENAYATI M H;BEISS P .Microstmctural and mechanical evaluation of Al-TiB2 nanostructured composite fabricated by mechanical alloying[J].Journal of Alloys and Compounds,2011,509:7758-7763. |
[6] | Anandkumar, R.;Almeida, A.;Vilar, R. .Wear behavior of Al-12Si/TiB_2 coatings produced by laser cladding[J].Surface & Coatings Technology,2011(13/14):3824-3832. |
[7] | Y. Zhang;N. Ma;H. Wang .Effect of Ti and Mg on the damping behavior of in situ aluminum composites[J].Materials Letters,2005(28):3775-3778. |
[8] | KUMAR S;SUBRAMANYA SARMA V;MURTY B S .The influence of room temperature and cryogenic temperature rolling on the aging and wear behavior of A1-4Cu-5TiB2 in situ composites[J].Journal of Alloys and Compounds,2009,479:268-273. |
[9] | ZHAO D G;LIU X F;PAN Y C .Microstmcture and mechanical properties of in situ synthesized (TiB2+Al2O3)/Al-Cu composites[J].Journal of Materials Processing Technology,2007,189:237-241. |
[10] | MANDAL A;CHAKRABORTY M;MURTY B S .Effect of TiB2 particles on sliding wear behavior of Al-Cu alloy[J].Wear,2007,263:160-166. |
[11] | HERBERT MERVIN A;MAITI R;MITRA R .Wear behaviour of cast and mushy state rolled Al-4.5Cu alloy and in-situ A14.5Cu-5TiB2 composite[J].Wear,2008,265:1606-1618. |
[12] | WOOD J V;DAVIES p;KELLIE J L F .Properties of reactively cast aluminium-TiB2 alloys[J].Materials Science and Technology,1993,9:833-840. |
[13] | LAKSHMI S;LU L;GUPTA M .In situ preparation of TiB2 reinforced Al based composites[J].Journal of Materials Processing Technology,1998,73:160-166. |
[14] | HAN Yan-feng;LI Ke;WANG Jun .Influence of high-intensity ultrasound on grain refining performance of Al-5Ti-1B master alloy on aluminum[J].Materials Science and Engineering A,2005,405:306-312. |
[15] | MOHANTY P S;GRUZLESKI J E .Mechanism of grain refinement in aluminum[J].Acta Metallurgica Et Materialia,1995,43:2001-2012. |
[16] | RAVI K R;SARAVANAN M;PILLAI R M .Equal channel angular pressing of Al-5wt% TiB2 in situ composite[J].Journal of Alloys and Compounds,2008,459:239-243. |
[17] | J. Fjellstedt;A.E.W. Jarfors .On the precipitation of TiB_2 in aluminum melts from the reaction with KBF_4 and K_2TiF_6[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,2005(0):527-532. |
[18] | TSZENG T C .The effects of particle clustering on the mechanical behavior of particle reinforced composites[J].Composites Part B:Engineering,1998,29:299-308. |
[19] | JHA A;DOMETAKIS C .The dispersion mechanism of TiB2 ceramic phase in molten aluminum and its alloys[J].Materials and Designs,1997,18:297-301. |
[20] | YOUSSEF Y M;DASHWOOD R J;LEE P D .Effect of clustering on particle pushing and solidification behaviour in TiB2 reinforced aluminum PMMCs[J].Composites Part A:Applied Science and Manufacturing,2005,36:747-763. |
[21] | TAN M J;ZHANG X .Powder metal matrix composites:Selection and processing[J].Materials Science and Engineering A,1998,244:80-85. |
[22] | XUN Jing;WANG Jun;HAN Yan-feng .Effect of CeO2 additive on the microstructure and mechanical properties of in situ TiB2/Al composite[J].Journal of Alloys and Compounds,2011,509:1573-1578. |
[23] | FENG C F;FROYEN L .Microstructures of in siru Al-TiB2 MMCs prepared by a casting route[J].Journal of Materials Science,2000,35:837850. |
[24] | 罗天骄,姚广春,吴林丽,刘宜汉,韩变华.CeO2在镀镍碳纤维增强铝合金基复合材料中的作用[J].中国有色金属学报,2007(01):80-84. |
[25] | Youming Liu;Bofan Xu;Wenyi Li .The effect of rare earth CeO_2 on microstructure and properties of in situ TiC/Al-Si composite[J].Materials Letters,2004(3/4):432-436. |
- 下载量()
- 访问量()
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%