The crystal structure and phase relations of the Pr2Fe14B-La2Fe14B system were investigated by X-ray powder diffraction (XRD), differential scanning calorimetry (DSC) and scanning electron microscopy (SEM) equipped with energy dispersive X-ray spectroscopy (EDS). The crystal structure parameters were determined by full-profile Rietveld refinements. The results revealed that all alloys of (Pr1–xLax)2Fe14B crystallized the Nd2Fe14B-type structure with the space groupP42/mnm and formed a continuous solid solutions betweenx=0.0 and 1.0. The lattice parametera,c, unit-cell volumeVand c/a ratio increased linearly with the La concentra-tion. Determined by thermogravimetry analysis, the Curie temperature (TC), phase transition temperature and melting temperature of (Pr1–xLax)2Fe14B decreased linearly upon the La content. Based on the results of DSC measurements and X-ray powder diffraction examinations, the phase diagram of the Pr2Fe14B-La2Fe14B system was built up.
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