Phosphors Ca4(PO4)2O:Ce3+/Li+,Eu2+ were prepared by solid state reaction successfully, and characterized by X-ray dif-fraction, UV-Vis spectrometer and photoluminescence spectrometry. The as-prepared phosphors exhibited strong absorption in the UV-visible region and dual-emission bands centered at approximately 460 and 630 nm. Energy transfer from Ce3+ to Eu2+ was also observed. By varying the excitation wavelength, these new phosphors exhibited tunable emissions from blue to white and then to yel-low, making them potential candidates as UV-convertible phosphors for white light emitting diodes.
参考文献
[1] | Yang, WJ;Luo, LY;Chen, TM;Wang, NS.Luminescence and energy transfer of Eu- and Mn-coactivated CaAl2Si2O8 as a potential phosphor for white-light UVLED[J].Chemistry of Materials,200515(15):3883-3888. |
[2] | Xia, Zhiguo;Miao, Shihai;Chen, Mingyue;Molokeev, Maxim S.;Liu, Quanlin.Structure, Crystallographic Sites, and Tunable Luminescence Properties of Eu2+ and Ce3+/Li+-Activated Ca1.65Sr0.35SiO4 Phosphors[J].Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics,201516(16):7684-7691. |
[3] | Xie RJ;Hirosaki N;Mitomo M;Uheda K;Suehiro T;Xu X;Yamamoto Y;Sekiguchi T.Strong green emission from alpha-SiAlON activated by divalent ytterbimn under blue light irradiation[J].The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical,200519(19):9490-9494. |
[4] | Degang Deng;Hua Yu;Yinqun Li.Ca4(PO4)2O:Eu~(2+) red-emitting phosphor for solid-state lighting: structure, luminescent properties and white light emitting diode application[J].Journal of Materials Chemistry, C. materials for optical and electronic devices,201319(19):3194-3199. |
[5] | Chun Che Lin;Zhi Ren Xiao;Guang-Yu Guo;Ting-Shan Chan;Ru-Shi Liu.Versatile Phosphate Phosphors ABPO4 in White Light-Emitting Diodes: Collocated Characteristic Analysis and Theoretical Calculations[J].Journal of the American Chemical Society,20109(9):3020-3028. |
[6] | Y. Q. LI;H. T. HINTZEN.High Efficiency Nitride Based Phosphors for White LEDs[J].Journal of Light & Visual Environment,20082(2):129-134. |
[7] | Paulose PI.;Jose G.;Thomas V.;Unnikrishnan NV.;Warrier MKR..Sensitized fluorescence of Ce3+/Mn2+ system in phosphate glass[J].The journal of physics and chemistry of solids,20035(5):841-846. |
[8] | Guogang Li;Dongling Geng;Mengmeng Shang.Color Tuning Luminescence of Ce /Mn /Tb -Triactivated Mg2Y8(SiO4)6O2 via Energy Transfer: Potential Single-Phase White-Light-Emitting Phosphors[J].The journal of physical chemistry, C. Nanomaterials and interfaces,201144(44):21882-21892. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%