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A novel photocatalyst of LaMnO3/graphene thin films with the perovskite-type was synthesized by sol-gel process assisted with spin-coating methods on glass substrates. The prepared samples were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), Brumauer-Emmett-Teller (BET) surface area analyzer, X-ray photoelectron spectroscopy (XPS) and UV-vis diffuse reflectance spectroscopy. Results showed that after the introduction of gra-phene, the perovskite structure was unchanged and the size of LaMnO3 particles was about 22 nm, which uniformed growth in gra-phene sheet. Determination of contact angle indicated that the contact angle of glass substrate decreased and the hydrophilicity im-proved after treating with H2SO4 and APTES. The UV-Vis photocatalytic activity of the photocatalysts was evaluated by the degrada-tion of diamine green B. LaMnO3/graphene thin films had better photocatalytic ability than LaMnO3 and TiO2 films. The obtained k was 0.5627 and 0.3441 h–1 corresponding to LaMnO3/graphene films and TiO2 films, respectively.

参考文献

[1] Lin X;Guan Q F;Zou C J;Liu T T Zhang Y Liu C B Zhai H J .Photocatalytic degradation of an azo dye using Bi3.25M0.75Ti3O12 nanowires(M=La, Sm, Nd, and Eu)[J].Mater Sci Eng B,2013,178:520.
[2] Khanna A;Shetty V K .Solar light induced photocatalytic degradation of Reactive Blue 220(RB-220)dye with highly efficient Ag@TiO2 core-shell nanoparticles:A comparison with UV photocatalysis. Sol[J].Energy,2014,99:67.
[3] Dumrongrojthanath, P.;Thongtem, T.;Phuruangrat, A.;Thongtem, S..Synthesis and characterization of hierarchical multilayered flower-like assemblies of Ag doped Bi_2WO_6 and their photocatalytic activities[J].Superlattices and microstructures,2013:196-203.
[4] Zhong J B;Li J Z;Lu Y;He X Y Zeng J Hu W Shen Y C .Fabrication of Bi3+-doped ZnO with enhanced photocata-lytic performance[J].Appl Surf Sci,2012,258:4929.
[5] Gao K;Li S D .Multi-modal TiO2-LaFeO3 composite films with high photocatalytic activity and hydrophilicity[J].Appl Surf Sci,2012,258:6460.
[6] Tang, P.;Tong, Y.;Chen, H.;Cao, F.;Pan, G. .Microwave-assisted synthesis of nanoparticulate perovskite LaFeO _3 as a high active visible-light photocatalyst[J].Current applied physics: the official journal of the Korean Physical Society,2013(2):340-343.
[7] McEvoy J G;Cui W Q;Zhang Z S .Synthesis and charac-terization of Ag/AgCl-activated carbon composites for enhanced visible light photocatalysis[J].Appl Catal B,2014,144:702.
[8] Fakhouri H;Pulpytel J;Smith W;Zolfaghari A Mortaheb H R Meshkini F Jafari R Sutter E Khonsari F A .Control of the visible and UV light water splitting and photocata-lysisof nitrogen doped TiO2 thin films deposited by reac-tive magnetron sputtering[J].Appl Catal B,2014,144:12.
[9] Fu S S;Niu H L;Tao Z Y;Song J M Mao C J Zhang S Y Chen C L Wang D .Low temperature synthesis and photocatalytic property of perovskitetype LaCoO3 hollow spheres[J].J Alloys Compd,2013,576:5.
[10] Yang H;Zhang J X;Lin G J;Xian T Jiang J L .Prepara-tion, characterization and photocatalytic properties of ter-bium orthoferrite nanopowder[J].Adv Powder Technol,2013,24:242.
[11] Low J X;Yu J G;Li Q;Cheng B .Enhanced visible-light photocatalytic activity of plasmonic Ag and graphene co-modified Bi2WO6 nanosheets, Phys[J].Chem Chem Phys,2014,16:1111.
[12] Yoo, D.-H.;Cuong, T.V.;Pham, V.H.;Chung, J.S.;Khoa, N.T.;Kim, E.J.;Hahn, S.H. .Enhanced photocatalytic activity of graphene oxide decorated on TiO _2 films under UV and visible irradiation[J].Current applied physics: the official journal of the Korean Physical Society,2011(3):805-808.
[13] Perera S D;Mariano R G;Vu K;Nour N Seitz O Chabal Y Balkus K J .Hydrothermal synthesis of graphene-TiO2 nanotube composites with enhanced photocatalytic activity[J].ACS Catal,2012,2:949.
[14] Pan X;Zhao Y;Liu S;Korzeniewski C L Wang S Fan Z Y .Comparing graphene-TiO2 nanowire and graphene-TiO2 nanoparticle composite photocatalysts[J].ACS Appl Mater Interfaces,2012,4:3944.
[15] Xiang Q J;Yu J G;Jaroniec M .Graphene-based semi-conductor photocatalysts[J].Chem Soc Rev,2012,41:782.
[16] Xiang Q J;Yu J G .Graphene-based photocatalysts for hy-drogen generation[J].J Phys Chem Lett,2013,4:753.
[17] Li Y Y;Yao S S;Xue L H;Yan Y W .Sol-gel combustion synthesis of nanocrystalline LaMnO3 powders and photo-catalystic properties[J].J Mater Sci,2009,44:4455.
[18] Shobana M K;Sankar S;Rajendran V .Structural and thermal studies of Ni0.25Mn0.75Fe2O4 composites by sol-gel combustion method[J].J Alloys Compd,2009,472:421.
[19] Mali A;Ataie A .Structural characterization of nano-crystalline BaFe12O19 powders synthesized by sol-gel combustion route[J].Scripta materialia,2005(9):1065-1070.
[20] Zhangpeng Li;Jinqing Wang;Sheng Liu;Xiaohong Liu;Shengrong Yang .Synthesis of hydrothermally reduced graphene/MnO_2 composites and their electrochemical properties as supercapacitors[J].Journal of Power Sources,2011(19):8160-8165.
[21] Souza, N.S.;Rodrigues, A.D.;Cardoso, C.A.;Pardo, H.;Faccio, R.;Mombru, A.W.;Galzerani, J.C.;De Lima, O.F.;Sergeenkov, S.;Araujo-Moreira, F.M. .Physical properties of nanofluid suspension of ferromagnetic graphite with high Zeta potential[J].Physics Letters, A,2012(4):544-546.
[22] Shen M Q;Zhao Z;Chen J H;Su Y G Wang J Wang X Q .Effects of calcium substitute in LaMnO3 perovskites for NO catalytic oxidation[J].J Rare Earths,2013,31(02):119.
[23] Xiang, Q.;Yu, J.;Wong, P.K. .Quantitative characterization of hydroxyl radicals produced by various photocatalysts[J].Journal of Colloid and Interface Science,2011(1):163-167.
[24] Anandan S;Rao T N;Sathish M;Rangappa D Honma I Miyauchi M .Superhydrophilic graphene-loaded TiO2 thin film for self-cleaning applications[J].ACS Appl Mater In-terfaces,2012,5(01):207.
[25] Min Y L;Zhang K;Chen Y C;Zhang Y G .Enhanced photocatalytic performance of Bi2WO6 by graphene sup-porter as charge transfer channel. separation and purifica-tion technology[J].Sep Purif Technol,2012,86:98.
[26] Park C Y;Ghosh T;Meng Z D;Kefayat U Vikram N Oh W C .Preparation of CuS-graphene oxide/TiO2 composites designed for high photonic effect and photocatalytic activ-ity under visible light[J].Chin J Catal (in Chin ),2013,34(04):711.
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