Surface reactive species on MnOx(0.4)-CeO2 catalysts towards soot oxidation assisted with pulse dielectric barrier discharge

稀土学报(英文版), 2014, (2): 153-158. doi: 10.1016/S1002-0721(14)60045-4

付名利 ^1, , 林俊敏 ^2, , 朱文波 ^3, , 吴军良 ^4, , 陈礼敏 ^5, , 黄碧纯 ^6, , 叶代启 ^7,

1.College of Environment and Energy, South China University of Technology, Guangzhou 510006, China

2.College of Environment and Energy, South China University of Technology, Guangzhou 510006, China

3.College of Environment and Energy, South China University of Technology, Guangzhou 510006, China

4.College of Environment and Energy, South China University of Technology, Guangzhou 510006, China

5.College of Environment and Energy, South China University of Technology, Guangzhou 510006, China

6.College of Environment and Energy, South China University of Technology, Guangzhou 510006, China

7.College of Environment and Energy, South China University of Technology, Guangzhou 510006, China

基金项目: National Natural Science Foundation of China(51108187,50978103,21207039) the Fundamental Research Funds for the Central Universities(2012ZM0041) Guangdong High Education Engineering Technology Research Center for Air Pollution Control Program(GCZX-A0903)

Surface reactive species on MnOx(0.4)-CeO2 catalysts towards soot oxidation assisted with pulse dielectric barrier discharge

FU Mingli ^1, , LIN Junmin ^2, , ZHU Wenbo ^3, , WU Junliang ^4, , CHEN Limin ^5, , HUANG Bichun ^6, , YE Daiqi ^7,

1.College of Environment and Energy, South China University of Technology, Guangzhou 510006, China

2.College of Environment and Energy, South China University of Technology, Guangzhou 510006, China

3.College of Environment and Energy, South China University of Technology, Guangzhou 510006, China

4.College of Environment and Energy, South China University of Technology, Guangzhou 510006, China

5.College of Environment and Energy, South China University of Technology, Guangzhou 510006, China

6.College of Environment and Energy, South China University of Technology, Guangzhou 510006, China

7.College of Environment and Energy, South China University of Technology, Guangzhou 510006, China

Keywords： diesel soot

MnOx(0.4)-CeO2 was investigated for soot oxidation assisted with a pulse dielectric barrier discharge (DBD). The catalysts were evaluated and characterized with TPO (temperature programmed oxidation), X-ray diffraction (XRD), Raman and X-ray photo-electron spectroscopy (XPS). The ignition temperature Ti for soot oxidation decreased from 240.8 to 216.4 oC with the increase of the pulse DBD frequencies from 50 to 400 Hz, lower than that of the case without pulse DBD present (253.4 oC). The results of XRD, Raman and XPS agreed well with the TPO activities of MnOx(0.4)-CeO2 towards soot oxidation. More solid solution of ceria and manganese, and surface reactive species including O2-, O-and Mn4+were responsible for the enhancement of soot oxidation due to pulse DBD injection in the present study. For solid solution favors to the activation and transformation of those species, which are be-lieved to be involved in the soot oxidation in a hybrid catalysis-plasma.

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Surface reactive species on MnOx(0.4)-CeO2 catalysts towards soot oxidation assisted with pulse dielectric barrier discharge

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