The goal of this work is aimed to improve the power conversion efficiency of single crystalline silicon-based photovoltaic (PV) cells by using the solar spectral conversion principle,which employed a down-converting phosphor to convert a high-energy ultraviolet photon to the less energetic red-emitting photons to improve the spectral response of Si solar cells.In this study,the surface of silicon solar cells was coated with a red-emitting KCaGd(PO4)2∶Eu3+ phosphor by using the screen-printing technique.In addition to the investigation on the microstructure using scanning electron microscopy (SEM),we measured the short circuit current (Isc),open circuit voltage (Voc),and power conversion efficiency (η) of spectral-conversion cells and compared with those of bare solar cells as a reference.Preliminary experimental results revealed that in an optimized PV cell,an enhancement of (0.64+0.01)% (from 16.03% to 16.67%) in △η ofa Si-based PV cell was achieved.
参考文献
[1] | T. Trupke;M. A. Green;P. Wurfel .Improving solar cell efficiencies by down-conversion of high-energy photons[J].Journal of Applied Physics,2002(3):1668-1674. |
[2] | Shalav A;Richards BS;Trupke T;Kramer KW;Gudel HU .Application of NaYF4 : Er3+ up-converting phosphors for enhanced near-infrared silicon solar cell response[J].Applied physics letters,2005(1):3505-1-3505-3-0. |
[3] | Trupke T;Shalav A;Richards BS;Wurfel P;Green MA .Efficiency enhancement of solar cells by luminescent up-conversion of sunlight[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2006(18/19):3327-3338. |
[4] | Chung P;Chung H;Holloway P H .Phosphor coatings to enhance Si photovoltaic cell performance[J].Journal of Vacuum Science and Technology A:Vacuum Surfaces and Films,2007,25:61. |
[5] | Shalav A;Richards B S;Green M A .Luminescent layers for enhanced silicon solar cell performance:Up-conversion[J].Solar Energy Materials & Solar Cells,2007,91:829. |
[6] | Shpaisman H;Niitsoo O;Lubomirsky I;Cahen D .Can up- and down-conversion and multi-exciton generation improve photovoltaics?[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2008(12):1541-1546. |
[7] | Li Y;Shan W;Cheng S;Ko M .(Intematix Corp.USA).Wavelength-converting phosphors for enhancing the efficiency of a photovoltaic device[P].Patent:WO 2007/133344 |
[8] | Devriesh A J;Kiliaan S;Blase G .An investigation of energy migration in luminescent diluted Gd3+ systems[J].Journal of Solid State Chemistry,1986,65:190. |
[9] | Blase G .New luminescent materials[J].Chemistry of Materials,1989,1:294. |
[10] | Tabirou M E;Daoudi A .Une nouvelle famille de phosphates triples d'é1éments alealins,alcalinoterreux et de terres rares[J].CR Acad Sci Série C,1980,291:93. |
[11] | Srivastavma A M;Sobierasj T;Ruan K;Banks E .Sensitization of the Gd3+ lattice by Pr3+ in GdBO3 and energy transfer to Ln3+ (Ln3+=Dy3+,Sm3+,and Tb3+)[J].Materials Research Bulletin,1986,21:1455. |
[12] | Srivastava A M;Gieger T S;Banks E .Luminescence and energy transfer in BaGdBgO16[J].Materials Chemistry and Physics,1989,21:327. |
[13] | Hiran H;Blasse G .Energy transfer phenomena in luminescent materials based on GdB3O6[J].Materials Chemistry and Physics,1985,12:257. |
[14] | Zhang ZJ;Yuan JL;Duan CJ;Xiong DB;Chen HH;Zhao JT;Zhang GB;Shi CS .Vacuum ultraviolet spectroscopic properties of rare earth (RE=Ce,Tb,Eu,Tm,Sm)-doped hexagonal KCaGd(PO4)(2) phosphate[J].Journal of Applied Physics,2007(9):93514-1-93514-7-0. |
[15] | Yen-Chi Chen,Teng-Ming Chen.Improvement of conversion efficiency of silicon solar cells using up-conversion molybdate La2Mo2O9:Yb,R (R=Er, Ho) phosphors[J].稀土学报(英文版),2011(08):723-726. |
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