A series of novel photocatalysts,H3PW12O40-Y-TiO2 nanocomposites with different H3PW12O40 loading levels (10%-40%) were prepared by impregnation method.And the Y-TiO2 support,doped with yttrium,was synthesized via sol-gel technique.The prepared catalysts were characterized by Fourier transform infrared spectroscopy (FT-IR),powder X-ray diffraction (XRD),nitrogen adsorption-desorption analysis and scanning electron microscopy (SEM).The processes allowed obtaining Keggin structure and crystallized anatase with large BET surface area as well as uniform distribution.The effects of H3PW12O40 loadings,catalyst dose,initial pH and concentration of dye solution on the degradation kinetics of methyl orange under UV light (λ≥365 nm) were discussed.Kinetics studies showed that the photocatalytic degradation of methyl orange fitted the apparent first-order reaction.Methyl orange was totally degraded in 21 min under optimum conditions:20% loading,0.03 g dose and pH 1.0.The catalyst was stable and easily to be separated from reaction system for recovery.
参考文献
[1] | FENG Changgen,ZHUO Xiaoxi,LIU Xia.Study on photodegradation of Azo dye by polyoxometalates/polyvinyl alcohol[J].稀土学报(英文版),2009(05):717-722. |
[2] | Kamila Bubacz;Julia Choina;Diana Dolat;Antoni W. Morawski .Methylene Blue and Phenol Photocatalytic Degradation on Nanoparticles of Anatase TiO_2[J].Polish Journal of Environmental Studies.,2010(4):685-691. |
[3] | Toshihiro Yamase .Photo- and Electrochromism of Polyoxometalates and Related Materials[J].Chemical Reviews,1998(1):307-325. |
[4] | T. Yamase .Photoredox chemistry of polyoxometalates as a photocatalyst[J].Catalysis Surveys From Japan,2003(4):203-217. |
[5] | Yihang Guo;Yuanhong Wang;Changwen Hu;Yonghui Wang;Enbo Wang;Yongchun Zhou;SHouhua Feng .Microporous Polyoxometalates POMs/SiO_2: Synthesis and Photocatalytic Degradation of Aqueous Organocholorine Pesticides[J].Chemistry of Materials,2000(11):3501-3508. |
[6] | Yang Y.;Guo YH.;Hu CW.;Jiang CJ.;Wang EB. .Synergistic effect of Keggin-type [Xn+W11O39]((12-n)-) and TiO2 in macroporous hybrid materials [Xn+W11O39]((12-n)-)-TiO2 for the photocatalytic degradation of textile dyes[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2003(7):1686-1694. |
[7] | Yang, Y;Wu, QY;Guo, YH;Hu, CW;Wang, E .Efficient degradation of dye pollutants on nanoporous polyoxotungstate-anatase composite under visible-light irradiation[J].Journal of Molecular Catalysis. A, Chemical,2005(2):203-212. |
[8] | Hongxiao Jin;Qingyin Wu;Wenqin Pang .Photocatalytic degradation of textile dye X-3B using polyoxometalate-TiO_2 hybrid materials[J].Journal of hazardous materials,2007(1):123-127. |
[9] | Kexin Li;Yingna Guo;Fengyan Ma .Design of ordered mesoporous H3PW_(12)O_(40)-titania materials and their photocatalytic activity to dye methyl orange degradation[J].Catalysis Communications,2010(9):839-843. |
[10] | Lee, J;Dong, XL;Dong, XW .Ultrasonic synthesis and photocatalytic characterization of H3PW12O40/TiO2 (anatase)[J].Ultrasonics sonochemistry,2010(4):649-653. |
[11] | Ou X Q;Meng J P;Wang Q M;Yu J M .Enhanced photoactivity of layered nanocomposite materials containing rare earths,titanium dioxide and clay[J].Journal of Rare Earths,2006,24(01):251. |
[12] | Fan Caimei,Xue Peng,Sun Yanping.Preparation of Nano-TiO2 Doped with Cerium and Its Photocatalytic Activity[J].稀土学报(英文版),2006(03):309-313. |
[13] | LI Fang-bai,GU Guo-bang,HUANG Guo-feng,GU Yun-li.TiO2-assisted photo-catalysis degradation process of dye chemicals[J].环境科学学报(英文版),2001(01):64-68. |
[14] | Zhu HY.;Orthman JA.;Li JY.;Zhao JC.;Churchman GJ.;Vansant EF. .Novel composites of TiO2 (anatase) and silicate nanoparticles[J].Chemistry of Materials,2002(12):5037-5044. |
[15] | SHI Zhongliang,LIU Fumei,YAO Shuhua.Preparation and photocatalytic activity of B,Y co-doped nanosized TiO2 catalyst[J].稀土学报(英文版),2010(05):737-741. |
[16] | Jose A. Dias;John P. Osegovic;Russell S. Drago .The Solid Acidity of 12-Tungstophosphoric Acid[J].Journal of Catalysis,1999(1):83-90. |
[17] | Noritaka Mizuno .Heterogeneous Catalysis[J].Chemical Reviews,1998(1):199-217. |
[18] | Caliman E;Dias J A;Dias S C L;Garcia F A C de Macedo J L Almeida L S .Preparation and characterization of H3PW12O4o supported on niobia[J].Microporous and Mesoporous Materials,2010,132(1-2):103. |
[19] | CAI Heshan,LIU Guoguang,Lü Wenying,LI Xiaoxia,YU Lin,LI Daguang.Effect of Ho-doping on photocatalytic activity of nanosized TiO2 catalyst[J].稀土学报(英文版),2008(01):71-75. |
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