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A series of Eu3+-Bi3+ co-doped CaMoO4 red phosphors were synthesized via the solid-sate reaction method.The crystal structures of the obtained samples were identified by X-ray powder diffraction (XRD).The photoluminescence property was investigated,and the results showed that the intensity of excitation spectra and emission spectra could be changed with different doping ratios of Bi3+/Eu3+.The proposed explanation of these changes was from the energy transfer between Bi3+ and Eu3+ and the unbalanced charge from the substitution of Eu3+ and Bi3+ for Ca2+ in CaMoO4.The obtained samples are a promising red light emitting phosphor for the needs of different excitation sources with near-UV and blue GaN-based chips.

参考文献

[1] Cao Fabin;Tian Yanwen;Chen Yongjie;Xiao Linjiu Wu Qiar .Luminescence investigation of red phosphors Cao.54Sr0 34-1 5x Eu0 08Smx(MoO4)y(WO4)1-y for UV-white LED device[J].Journal of Luminescence,2009,129:585.
[2] Wang Xiaoxiao;Xian Yulun;Wang Gang;Shi Jianxin Su Qiang Gong Menglian .Luminescence investigation of Eu3+-Sm3+co-doped Gd2-x-yEuxSmy(MoO4)3 phosphors as red phosphors for UV InGaN-based light-emitting diode[J].Optical Materials,2007,30:521.
[3] Yi Linghong;He Xipu;Zhou Liya;Gong Fuzhong Wang Rongfang Sun Jianhua .A potential red phosphor LiGd(MoO4)2:Eu3+ for light-emitting diode application[J].Journal of Luminescence,2010,130:1113.
[4] Guo Chongfeng;Yang Hyun-Kyoung;Jeong Jung-Hyun .Preparation and luminescent properties of phosphor MGd2(MoO4)4:Eu3+ (M=Ca,Sr and Ba)[J].Journal of Luminescence,2010,130:1390.
[5] 郑敏,陈一胜,张继忠,勾阳.红色荧光粉NaBaPO4:Eu3+的制备及其性能研究[J].四川有色金属,2009(3):18-22.
[6] Yi Lihong;Zhou Liya;Wang Zhengliang;Sun Jianghua Gong Fuzhong Wan Weiping Wang Wei .KGd(MoO4)2:Eu3+ as a promising red phosphor for light-emitting diode application[J].Current Applied Physics,2010,10:208.
[7] Zhao Xiaoxia;Wang Xiaojun;Chen Baojiu;Meng Qingyu Di Weihua Ren Guozhong Yang Yanmin .Novel Eu3+-doped red-emitting phosphor Gd2Mo3O9 for white-light-emittingdiodes (WLEDs) application[J].Journal of Alloys and Compounds,2007,433:352.
[8] Hu Yunsheng;Zhuang Weidong;Ye Hongqi;Wang Donghui Zhang Shusheng Huang Xiaowei .A novel red phosphor for white light emitting diodes[J].Journal of Alloys and Compounds,2005,390:226.
[9] Chen Yongjie;Cao Fabin;Tian Yanwen;Xiao Linjiu Li Langkai .Optimized photoluminescence by charge compensation in a novel phosphor system[J].Physica B:Condensed Matter,2010,405:435.
[10] 曹发斌,田彦文,陈永杰,肖林久,刘云义.电荷补偿对红色LED用荧光粉体的荧光性能改进[J].物理化学学报,2009(02):299-303.
[11] Xie An;Yuan Ximing;Shi Yu;Wang Fengxiang Wang Juanjuan .Photoluminescence characteristics of energy transfer between Eu3+ and Bi3+ in LiEu1-xBix(WO4)0.5(MoO4)1 5[J].Journal of the American Ceramic Society,2009,92:2254.
[12] Wang Zhengliang;Liang Honghin;Zhou Liya;Wang Jing Gong Menglian Su Qiang .NaEu0.96Sm0 04(MoO4)2 as a promising red-emitting phosphor for LED solid-state lighting prepared by the Pechini process[J].Journal of Luminescence,2008,128:147.
[13] Biju P R;Jose G;Thomas V;Nampoori V P N Unnikrishnan N V .Energy transfer in Sm3+:Eu3+ system in zinc sodium phosphate glasses[J].Optical Materials,2004,24:671.
[14] Park WJ;Jung MK;Im SJ;Yoon DH .Photoluminescence characteristics of energy transfer between Bi3+ and Eu3+ in LnVO(4): Eu, Bi (Ln = Y, La, Gd)[J].Colloids and Surfaces, A. Physicochemical and Engineering Aspects,2008(0):373-377.
[15] Igor V Zatovsky;Katherina V Terebilenko;Nikolay S Slobodyanik;Vyacheslav N Baumer Oleg V Shishkin .Synthesis,characterization and crystal structure of K2Bi(PO4)(MoO4)[J].Journal of Solid State Chemistry,2006,179:3550.
[16] Wan Jing;Cheng Lihong;Sun Jiashi;Zhong Haiyang Li Xiangping Lu Weili Tian Yue Lin Hai Chen Baojiu .Energy transfer and colorimetric properties of Eu3+/Dy3+ co-doped Gd2(MoO4)3 phosphors[J].Journal of Alloys and Compounds,2010,496:331.
[17] Zhang Zhijun;Chen Haohong;Yang Xinxin;Zhao Jingtai .Preparation and luminescence properties of Eu3+ and Tb3+ ions in the host of CaMoO4[J].Materials Science and Engineering B:Solid-state materials for advanced technology,2007,45:34.
[18] Zhengliang Wang;Hongbin Liang;Menglian Gong;Qiang Su .Novel red phosphor of Bi~(3+), Sm~(3+) co-activated NaEu(MoO_4)_2[J].Optical materials,2007(7):896-900.
[19] Neeraj S.;Kijima N.;Cheetham AK. .Novel red phosphors for solid-state lighting: the system NaM(WO4)(2-x)(MoO4)(x): Eu3+ (M=Gd, Y, Bi)[J].Chemical Physics Letters,2004(1/3):2-6.
[20] Cao Fabin;Tian Yanwen;Chen Yongjie;Xiao Linjiu Wu Qian .Novel red phosphors for solid-state lighting:Ca0.54Sr0 34-1 5x Eu0 08Lax(MoO4)y(WO4)1-y[J].Journal of Alloys and Compounds,2009,475:387.
[21] ZHU Nan-Fei,LI Yong-Xiang,YU Xiao-Feng.Luminescence Spectra of YGG:RE3+,Bi3+ (RE=Eu and Tb) and Energy Transfer from Bi3+ to RE3+[J].中国物理快报(英文版),2008(02):703-706.
[22] Yan Suxia;Zhang Jiahua;Zhang Xia;Lu Shaozhe Ren Xinguang Nie Zhaogang Wang Xiaojun .Enhanced red emission in CaMoO4:Bi3+,Eu3+[J].Journal of Physical Chemistry C,2007,111:13256.
[23] Kang Fengwen;Hu Yihua;Wu Haoyi Mu Zhongfei;Ju Guifang Fu Chujun .Luminescent investigation of NazCa1-x-2y-z BiyMoO4:(x+y)Eu3+ red phosphors[J].Spectroscopy and Spectral Analysis,2011,9:1.
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